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DDT In New Zealand
The use of DDT in New Zealand was banned in 1989 due to negative environmental impacts. DDT DDT is an organochlorine insecticide that does not occur naturally. It is a persistent organic pollutant (POP) with a half life of 2–15 years. Concerns were raised about its use in the 1940s but the publication of Rachael Carson's book ''Silent Spring'' was the catalyst leading to DDT being banned. DDT was first banned in Hungary in 1968 then in Norway and Sweden in 1970, the US in 1972 and the United Kingdom in 1984. Usage DDT was used extensively for agricultural use in the 1950s and 1960s to control grass grub and porina moth. It was also used on lawns and for market gardens. Some 500 tons was being applied annually by 1959. By the 1970s its use was restricted and was banned in 1989. Residues There was increasing evidence, especially in the 1970s, that there were DDT residues in aquatic organisms including trout and eels. Being bioaccumulative DDT passes up the food chain and organ ...
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New Zealand
New Zealand ( mi, Aotearoa ) is an island country in the southwestern Pacific Ocean. It consists of two main landmasses—the North Island () and the South Island ()—and over 700 smaller islands. It is the sixth-largest island country by area, covering . New Zealand is about east of Australia across the Tasman Sea and south of the islands of New Caledonia, Fiji, and Tonga. The country's varied topography and sharp mountain peaks, including the Southern Alps, owe much to tectonic uplift and volcanic eruptions. New Zealand's capital city is Wellington, and its most populous city is Auckland. The islands of New Zealand were the last large habitable land to be settled by humans. Between about 1280 and 1350, Polynesians began to settle in the islands and then developed a distinctive Māori culture. In 1642, the Dutch explorer Abel Tasman became the first European to sight and record New Zealand. In 1840, representatives of the United Kingdom and Māori chiefs ...
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Dieldrin
Dieldrin is an organochloride originally produced in 1948 by J. Hyman & Co, Denver, as an insecticide. Dieldrin is closely related to aldrin, which reacts further to form dieldrin. Aldrin is not toxic to insects; it is oxidized in the insect to form dieldrin which is the active compound. Both dieldrin and aldrin are named after the Diels-Alder reaction which is used to form aldrin from a mixture of norbornadiene and hexachlorocyclopentadiene. Originally developed in the 1940s as an alternative to DDT, dieldrin proved to be a highly effective insecticide and was very widely used during the 1950s to early 1970s. Endrin is a stereoisomer of dieldrin. However, it is an extremely persistent organic pollutant; it does not easily break down. Furthermore, it tends to biomagnify as it is passed along the food chain. Long-term exposure has proven toxic to a very wide range of animals including humans, far greater than to the original insect targets. For this reason, it is now banned in ...
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Pesticides In New Zealand
There is a high use of pesticides in New Zealand due predominantly to the large agricultural industry. Pesticides 1080 Sodium fluoroacetate, commonly known as 1080, is used in New Zealand to control animal pests, specifically the possum which threatens biodiversity and carries tuberculosus. Hunters fear that 1080 impacts on game animals, and some environmentalists have concerns about 1080 killing the very native fauna it is meant to save, and pollution of drinking water reservoirs with 1080 baits and poisoned animals. 2,4,5-T Manufacture of 2,4,5-Trichlorophenoxyacetic acid (2,4,5-T) ceased in New Zealand in 1987 and it is no longer sold in New Zealand. 2,4-D 2,4-Dichlorophenoxyacetic acid (2,4-D) is used in New Zealand and the Pesticides Board has decided not to prohibit the use of the chemical. DDT DDT was used extensively for agricultural use in the 1950s and 1960s to control grass grub and porina moth. It was also used on lawns and for market gardens. Some 500 t ...
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Stockholm Convention
Stockholm Convention on Persistent Organic Pollutants is an international environmental treaty, signed on 22 May 2001 in Stockholm and effective from 17 May 2004, that aims to eliminate or restrict the production and use of persistent organic pollutants (POPs). History In 1995, the Governing Council of the United Nations Environment Programme (UNEP) called for global action to be taken on POPs, which it defined as "chemical substances that persist in the environment, bio-accumulate through the food web, and pose a risk of causing adverse effects to human health and the environment". Following this, the Intergovernmental Forum on Chemical Safety (IFCS) and the International Programme on Chemical Safety (IPCS) prepared an assessment of the 12 worst offenders, known as the ''dirty dozen''. The INC met five times between June 1998 and December 2000 to elaborate the convention, and delegates adopted the Stockholm Convention on POPs at the Conference of the Plenipotentiaries co ...
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Parliamentary Commissioner For The Environment
__NOTOC__ The Parliamentary Commissioner for the Environment (''Te Kaitiaki Taiao a Te Whare Pāremata'' in Māori) is an independent Officer of the New Zealand Parliament appointed by the Governor-General on the recommendation of the House of Representatives for a five-year term under the Environment Act 1986. The Parliamentary Commissioner for the Environment replaced the Commission for the Environment, a Government agency which was formed in 1972. Role The Commissioner is one of three officers of Parliament (the Ombudsmen and the controller and auditor general) who are independent of the executive and who may review activities of the executive government and report directly to Parliament. The Commissioner's role is to review and provide advice on environmental issues and the system of agencies and processes established by the Government to manage the environment. The primary objective of the office is to contribute to maintaining and improving the quality of the environment i ...
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Paraquat
Paraquat (trivial name; ), or ''N'',''N''′-dimethyl-4,4′-bipyridinium dichloride (systematic name), also known as methyl viologen, is an organic compound with the chemical formula C6H7N)2l2. It is classified as a viologen, a family of redox-active heterocycles of similar structure. This salt is one of the most widely used herbicides. It is quick-acting and non-selective, killing green plant tissue on contact. It is also toxic (lethal) to human beings and animals due to its redox Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate (chemistry), substrate change. Oxidation is the loss of Electron, electrons or an increase in the oxidation state, while reduction ... activity, which produces superoxide anions. It has been linked to the development of Parkinson's disease and is banned in several countries. Paraquat may be in the form of salt (chemistry), salt with chloride or other anions; quantities of the substan ...
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Dichlorodiphenyldichloroethane
Dichlorodiphenyldichloroethane (DDD) is an organochlorine insecticide that is slightly irritating to the skin.Merck Index, 11th ed, p482 DDD is a metabolite of DDT.“p,p'-Dichlorodiphenyl dichloroethane (DDD) (CASRN 72-54-8).” ''Integrated Risk Information System''. 25 Jan. 2007. United States Environmental Protection Agency. 23 Apr. 2007 . DDD is colorless and crystalline;Mish, Frederick C., Editor in Chief. “DDD.” ''Webster’s Ninth New Collegiate Dictionary''. 9th ed. Springfield, MA: Merriam-Webster Inc., 1985. it is closely related chemically and is similar in properties to DDT, but it is considered to be less toxic to animals than DDT.Guralnik, David B., Editor in Chief. “DDD.” ''Webster’s New World Dictionary of the American Language''. Second College Edition. New York, NY: Prentice Hall Press, 1986. The molecular formula for DDD is (ClC6H4)2CHCHCl2 or C14H10Cl4, whereas the formula for DDT is (ClC6H4)2CHCCl3 or C14H9Cl5. DDD is in the “ Group B2” classif ...
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Persistent Organic Pollutant
Persistent organic pollutants (POPs), sometimes known as "forever chemicals", are organic compounds that are resistant to environmental degradation through chemical, biological, and photolytic processes. They are toxic chemicals that adversely affect human health and the environment around the world. Because they can be transported by wind and water, most POPs generated in one country can and do affect people and wildlife far from where they are used and released. The effect of POPs on human and environmental health was discussed, with intention to eliminate or severely restrict their production, by the international community at the Stockholm Convention on Persistent Organic Pollutants in 2001. Most POPs are pesticides or insecticides, and some are also solvents, pharmaceuticals, and industrial chemicals. Although some POPs arise naturally (e.g. from volcanoes), most are man-made. The "dirty dozen" POPs identified by the Stockholm Convention include aldrin, chlordane, dield ...
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Organochlorine
An organochloride, organochlorine compound, chlorocarbon, or chlorinated hydrocarbon is an organic compound containing at least one covalent bond, covalently bonded atom of chlorine. The chloroalkane class (alkanes with one or more hydrogens substituted by chlorine) provides common examples. The wide structural variety and divergent chemical properties of organochlorides lead to a broad range of names, applications, and properties. Organochlorine compounds have wide use in many applications, though some are of profound environmental concern, with 2,3,7,8-Tetrachlorodibenzodioxin, TCDD being one of the most notorious. Physical and chemical properties Chlorination reaction, Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular dam ...
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Organomercury
Organomercury refers to the group of organometallic compounds that contain mercury. Typically the Hg–C bond is stable toward air and moisture but sensitive to light. Important organomercury compounds are the methylmercury(II) cation, CH3Hg+; ethylmercury(II) cation, C2H5Hg+; dimethylmercury, (CH3)2Hg, diethylmercury and merbromin ("Mercurochrome"). Thiomersal is used as a preservative for vaccines and intravenous drugs. The toxicity of organomercury compounds presents both dangers and benefits. Dimethylmercury in particular, is notoriously toxic, but found use as an antifungal agent and insecticide. Merbromin and phenylmercuric borate are used as topical antiseptics, while nitromersol is used as a preservative for vaccines and antitoxins. Synthesis Organomercury compounds are generated by many methods, including the direct reaction of hydrocarbons and mercury(II) salts. In this regard, organomercury chemistry more closely resembles organopalladium chemistry and contrasts ...
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