Cryo-adsorption
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Cryo-adsorption
Cryo-adsorption is a method used for hydrogen storage where gaseous hydrogen at cryogenic temperatures (150—60 K) is physically adsorbed on porous material, mostly activated carbon. The achievable storage density is between liquid-hydrogen (LH2) storage systems and compressed-hydrogen (CGH2) storage systems.Cryo-Adsorption


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Hydrogen economy The hydrogen economy is using hydrogen to decarbonize economic sectors which are hard to electrify, essentially, the "hard-to-abate" sectors such as cement, steel, long-haul transport etc ...
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Hydrogen Storage
Hydrogen storage can be accomplished by several existing methods of holding hydrogen for later use. These include mechanical approaches such as using high pressures and low temperatures, or employing chemical compounds that release H2 upon demand. While large amounts of hydrogen are produced by various industries, it is mostly consumed at the site of production, notably for the synthesis of ammonia. For many years hydrogen has been stored as compressed gas or cryogenic liquid, and transported as such in cylinders, tubes, and cryogenic tanks for use in industry or as propellant in space programs. Interest in using hydrogen for on-board storage of energy in zero-emissions vehicles is motivating the development of new methods of storage, more adapted to this new application. The overarching challenge is the very low boiling point of H2: it boils around 20.268 K (−252.882 °C or −423.188 °F). Achieving such low temperatures requires expending significant energy. Es ...
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Adsorbtion
Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the ''adsorbate'' on the surface of the ''adsorbent''. This process differs from absorption, in which a fluid (the ''absorbate'') is dissolved by or permeates a liquid or solid (the ''absorbent''). Adsorption is a ''surface phenomenon'', while absorption involves the whole volume of the material, although adsorption does often precede absorption. The term ''sorption'' encompasses both processes, while ''desorption'' is the reverse of it. Like surface tension, adsorption is a consequence of surface energy. In a bulk material, all the bonding requirements (be they ionic, covalent or metallic) of the constituent atoms of the material are fulfilled by other atoms in the material. However, atoms on the surface of the adsorbent are not wholly surrounded by other adsorbent atoms and therefore can attract adsorbates. The exact nature of the bondi ...
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Liquid-hydrogen
Liquid hydrogen (LH2 or LH2) is the liquid state of the element hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic, an .... Hydrogen is found naturally in the molecule, molecular H2 form. To exist as a liquid, H2 must be cooled below its critical point (thermodynamics), critical point of 33 Kelvins, K. However, for it to be in a fully liquid state at atmospheric pressure, H2 needs to be cooled to .IPTS-1968
iupac.org, accessed 2020-01-01
A common method of obtaining liquid hydrogen involves a compressor resembling a jet engine in both appearance and principle. Liquid hydrogen is typically used as a concentrated fo ...
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Compressed Hydrogen
Compressed hydrogen (CH2, CGH2 or CGH2) is the gaseous state of the element hydrogen kept under pressure. Compressed hydrogen in hydrogen tanks at 350 bar (5,000 psi) and 700 bar (10,000 psi) is used for mobile hydrogen storage in hydrogen vehicles. It is used as a fuel gas. Infrastructure Compressed hydrogen is used in hydrogen pipeline transport and in compressed hydrogen tube trailer transport. See also *Cryo-adsorption *Gas compressor *Gasoline gallon equivalent *Hydrogen compressor *Hydrogen safety *Liquid hydrogen *Liquefaction of gases *Metallic hydrogen *Slush hydrogen *Standard cubic foot *Timeline of hydrogen technologies This is a timeline of the history of hydrogen technology. Timeline 16th century * c. 1520 – First recorded observation of hydrogen by Paracelsus through dissolution of metals (iron, zinc, and tin) in sulfuric acid. 17th century * 1625 – Fi ... References External links COMPRESSED HYDROGEN INFRASTRUCTURE PROGRAM ("CH2IP") Hydrogen physics ...
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Hydrogen Tank
A hydrogen tank (other names- cartridge or canister) is used for hydrogen storage. The first type IV hydrogen tanks for compressed hydrogen at were demonstrated in 2001, the first fuel cell vehicles on the road with type IV tanks are the Toyota FCHV, Mercedes-Benz F-Cell and the GM HydroGen4. Low-pressure tanks Various applications have allowed the development of different H2 storage scenarios. Recently, the Hy-Can consortium has introduced a small one liter, format. Horizon Fuel Cells is now selling a refillable metal hydride form factor for consumer use called HydroStik. Type I * Metal tank (steel/aluminum) * Approximate maximum pressures: aluminum , steel . Type II * Aluminum tank with filament windings such as glass fiber/aramid or carbon fiber around the metal cylinder. See composite overwrapped pressure vessel. * Approximate maximum pressures: aluminum/glass , steel/carbon or aramide . Type III * Tanks made from composite material, fiberglass/aramid or carbon fiber wi ...
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Hydrogen Technologies
Hydrogen technologies are technologies that relate to the production and use of hydrogen as a part hydrogen economy. Hydrogen technologies are applicable for many uses. Some hydrogen technologies are carbon neutral and could have a role in preventing climate change and a possible future hydrogen economy. Hydrogen is a chemical widely used in various applications including ammonia production, oil refining and energy. The most common methods for producing hydrogen on an industrial scale are: Steam reforming, oil reforming, coal gasification, water electrolysis. Hydrogen is not a primary energy source, because it is not naturally occurring as a fuel. It is, however, widely regarded as an ideal energy storage medium, due to the ease with which electricity can convert water into hydrogen and oxygen through electrolysis and can be converted back to electrical power using a fuel cell. There are a wide number of different types of fuel and electrolysis cells. The potential envir ...
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Hydrogen
Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic, and highly combustible. Hydrogen is the most abundant chemical substance in the universe, constituting roughly 75% of all normal matter.However, most of the universe's mass is not in the form of baryons or chemical elements. See dark matter and dark energy. Stars such as the Sun are mainly composed of hydrogen in the plasma state. Most of the hydrogen on Earth exists in molecular forms such as water and organic compounds. For the most common isotope of hydrogen (symbol 1H) each atom has one proton, one electron, and no neutrons. In the early universe, the formation of protons, the nuclei of hydrogen, occurred during the first second after the Big Bang. The emergence of neutral hydrogen atoms throughout the universe occurred about 370,000 ...
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Cryogenic
In physics, cryogenics is the production and behaviour of materials at very low temperatures. The 13th IIR International Congress of Refrigeration (held in Washington DC in 1971) endorsed a universal definition of “cryogenics” and “cryogenic” by accepting a threshold of 120 K (or –153 °C) to distinguish these terms from the conventional refrigeration. This is a logical dividing line, since the normal boiling points of the so-called permanent gases (such as helium, hydrogen, neon, nitrogen, oxygen, and normal air) lie below 120K while the Freon refrigerants, hydrocarbons, and other common refrigerants have boiling points above 120K. The U.S. National Institute of Standards and Technology considers the field of cryogenics as that involving temperatures below -153 Celsius (120K; -243.4 Fahrenheit) Discovery of superconducting materials with critical temperatures significantly above the boiling point of nitrogen has provided new interest in reliable, low cost methods ...
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Activated Carbon
Activated carbon, also called activated charcoal, is a form of carbon commonly used to filter contaminants from water and air, among many other uses. It is processed (activated) to have small, low-volume pores that increase the surface area available for adsorption (which is not the same as absorption) or chemical reactions. Activation is analogous to making popcorn from dried corn kernels: popcorn is light, fluffy, and has a surface area that is much larger than the kernels. ''Activated'' is sometimes replaced by ''active''. Due to its high degree of microporosity, one gram of activated carbon has a surface area in excess of as determined by gas adsorption. Charcoal, before activation, has a specific surface area in the range of . An activation level sufficient for useful application may be obtained solely from high surface area. Further chemical treatment often enhances adsorption properties. Activated carbon is usually derived from waste products such as coconut husks; waste ...
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Density
Density (volumetric mass density or specific mass) is the substance's mass per unit of volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' can also be used. Mathematically, density is defined as mass divided by volume: : \rho = \frac where ''ρ'' is the density, ''m'' is the mass, and ''V'' is the volume. In some cases (for instance, in the United States oil and gas industry), density is loosely defined as its weight per unit volume, although this is scientifically inaccurate – this quantity is more specifically called specific weight. For a pure substance the density has the same numerical value as its mass concentration. Different materials usually have different densities, and density may be relevant to buoyancy, purity and packaging. Osmium and iridium are the densest known elements at standard conditions for temperature and pressure. To simplify comparisons of density across different s ...
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Hydrogen Economy
The hydrogen economy is using hydrogen to decarbonize economic sectors which are hard to electrify, essentially, the "hard-to-abate" sectors such as cement, steel, long-haul transport etc. In order to phase out fossil fuels and limit climate change, hydrogen can be created from water using renewable sources such as wind and solar, and its combustion only releases water vapor to the atmosphere. Hydrogen is an energetic fuel, frequently used as rocket fuel, but numerous technical challenges prevent the creation of a large-scale hydrogen economy. These include the difficulty of developing long-term storage, pipelines and engine equipment; a relative lack of off-the-shelf engine technology that can currently run safely on hydrogen; safety concerns regarding the high reactivity of hydrogen fuel with oxygen in ambient air; the expense of producing it by electrolysis; and a lack of efficient photochemical water splitting technology. Hydrogen can also react in a fuel cell, which effic ...
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Separation Processes
A separation process is a method that converts a mixture or a solution of chemical substances into two or more distinct product mixtures, a scientific process of separating two or more substance in order to obtain purity. At least one product mixture from the separation is enriched in one or more of the source mixture's constituents. In some cases, a separation may fully divide the mixture into pure constituents. Separations exploit differences in chemical properties or physical properties (such as size, shape, mass, density, or chemical affinity) between the constituents of a mixture. Processes are often classified according to the particular properties they exploit to achieve separation. If no single difference can be used to accomplish the desired separation, multiple operations can often be combined to achieve the desired end. With a few exceptions, elements or compounds exist in nature in an impure state. Often these raw materials must go through a separation before th ...
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