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Copper Coulometer
The copper coulometer is a one application for the copper-copper(II) sulfate electrode. Such a coulometer consists of two identical copper electrodes immersed in slightly acidic pH-buffered solution of copper(II) sulfate. Passing of current through the element leads to the anodic dissolution of the metal on anode and simultaneous deposition of copper ions on the cathode. These reactions have 100% efficiency over a wide range of current density. Calculation The amount of electric charge (quantity of electricity) passed through the cell can easily be determined by measuring the change in mass of either electrode and calculating: :Q = \frac, where: *Q is the quantity of electricity (coulombs) *\Delta m is the mass transported (gm) *z_ is the charge of the copper ions, equal to +2 *F is the Faraday constant (96485.3383 coulombs per mole) *M_ is the atomic weight of copper, equal to 63.546 grams per mole. Although this apparatus is interesting from a theoretical and historical point ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electric Charge
Electric charge is the physical property of matter that causes charged matter to experience a force when placed in an electromagnetic field. Electric charge can be ''positive'' or ''negative'' (commonly carried by protons and electrons respectively). Like charges repel each other and unlike charges attract each other. An object with an absence of net charge is referred to as neutral. Early knowledge of how charged substances interact is now called classical electrodynamics, and is still accurate for problems that do not require consideration of quantum effects. Electric charge is a conserved property; the net charge of an isolated system, the amount of positive charge minus the amount of negative charge, cannot change. Electric charge is carried by subatomic particles. In ordinary matter, negative charge is carried by electrons, and positive charge is carried by the protons in the nuclei of atoms. If there are more electrons than protons in a piece of matter, it will have ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Physical Chemistry
Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistical mechanics, analytical dynamics and chemical equilibria. Physical chemistry, in contrast to chemical physics, is predominantly (but not always) a supra-molecular science, as the majority of the principles on which it was founded relate to the bulk rather than the molecular or atomic structure alone (for example, chemical equilibrium and colloids). Some of the relationships that physical chemistry strives to resolve include the effects of: # Intermolecular forces that act upon the physical properties of materials ( plasticity, tensile strength, surface tension in liquids). # Reaction kinetics on the rate of a reaction. # The identity of ions and the electrical conductivity of materials. # Surface science and electrochemistry of cell membrane ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Coulometry
Coulometry determines the amount of matter transformed during an electrolysis reaction by measuring the amount of electricity (in coulombs) consumed or produced. It can be used for precision measurements of charge, and the amperes even used to have a coulometric definition. However, today coulometry is mainly used for analytical applications. Coulometry is a group of techniques in analytical chemistry. It is named after Charles-Augustin de Coulomb. There are two basic categories of coulometric techniques. ''Potentiostatic coulometry'' involves holding the electric potential constant during the reaction using a potentiostat. The other, called ''coulometric titration'' or ''amperostatic coulometry'', keeps the current (measured in amperes) constant using an amperostat. Potentiostatic coulometry Potentiostatic coulometry is a technique most commonly referred to as "bulk electrolysis". The working electrode is kept at a constant potential and the current that flows through the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mercury Coulometer
A mercury coulometer is an electroanalytical chemistry device using mercury to determine the amount of matter transformed (in coulombs) during the following reaction:Although the indication of the zero charge of the metal is not needed, in discussing situations with charged AND uncharged particles, it clearly indicates the charge is not "forgotten". :Hg^2+ + 2e^- Hg^\circ These oxidation/reduction processes have 100% efficiency with the wide range of the current densities. Measuring of the quantity of electricity (coulombs) is based on the changes of the mass of the mercury electrode. Mass of the electrode can be increased during cathodic deposition of the mercury ions or decreased during the anodic dissolution of the metal. :Q = \frac, where :Q, quantity of electricity; :\Delta\ m, mass changes; :F, Faraday constant :M_\ce, the molar mass of mercury Construction This coulometer has different constructions but all of them are based on mass measurements. The device consists of t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Coulomb
The coulomb (symbol: C) is the unit of electric charge in the International System of Units (SI). In the present version of the SI it is equal to the electric charge delivered by a 1 ampere constant current in 1 second and to elementary charges, , (about ). Name and history By 1878, the British Association for the Advancement of Science had defined the volt, ohm, and farad, but not the coulomb. In 1881, the International Electrical Congress, now the International Electrotechnical Commission (IEC), approved the volt as the unit for electromotive force, the ampere as the unit for electric current, and the coulomb as the unit of electric charge. At that time, the volt was defined as the potential difference .e., what is nowadays called the "voltage (difference)"across a conductor when a current of one ampere dissipates one watt of power. The coulomb (later "absolute coulomb" or "abcoulomb" for disambiguation) was part of the EMU system of units. The "international coulo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Atomic Weight
Relative atomic mass (symbol: ''A''; sometimes abbreviated RAM or r.a.m.), also known by the deprecated synonym atomic weight, is a dimensionless physical quantity defined as the ratio of the average mass of atoms of a chemical element in a given sample to the atomic mass constant. The atomic mass constant (symbol: ''m'') is defined as being of the mass of a carbon-12 atom. Since both quantities in the ratio are masses, the resulting value is dimensionless; hence the value is said to be ''relative''. For a single given sample, the relative atomic mass of a given element is the weighted arithmetic mean of the masses of the individual atoms (including their isotopes) that are present in the sample. This quantity can vary substantially between samples because the sample's origin (and therefore its radioactive history or diffusion history) may have produced unique combinations of isotopic abundances. For example, due to a different mixture of stable carbon-12 and carbon-13 isoto ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Faraday Constant
In physical chemistry, the Faraday constant, denoted by the symbol and sometimes stylized as ℱ, is the electric charge per mole of elementary charges. It is named after the English scientist Michael Faraday. Since the 2019 redefinition of SI base units, which took effect on 20 May 2019, the Faraday constant has the exactly defined value given by the product of the elementary charge ''e'' and Avogadro constant ''N''A: : : :. Derivation The Faraday constant can be thought of as the conversion factor between the mole (used in chemistry) and the coulomb (used in physics and in practical electrical measurements), and is therefore of particular use in electrochemistry. Because 1 mole contains exactly entities, and 1 coulomb contains exactly elementary charges, the Faraday constant is given by the quotient of these two quantities: :. One common use of the Faraday constant is in electrolysis calculations. One can divide the amount of charge (the current integrated over time) ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cathode
A cathode is the electrode from which a conventional current leaves a polarized electrical device. This definition can be recalled by using the mnemonic ''CCD'' for ''Cathode Current Departs''. A conventional current describes the direction in which positive charges move. Electrons have a negative electrical charge, so the movement of electrons is opposite to that of the conventional current flow. Consequently, the mnemonic ''cathode current departs'' also means that electrons flow ''into'' the device's cathode from the external circuit. For example, the end of a household battery marked with a + (plus) is the cathode. The electrode through which conventional current flows the other way, into the device, is termed an anode. Charge flow Conventional current flows from cathode to anode outside of the cell or device (with electrons moving in the opposite direction), regardless of the cell or device type and operating mode. Cathode polarity with respect to the anode can be positive ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Copper
Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orange color. Copper is used as a conductor of heat and electricity, as a building material, and as a constituent of various metal alloys, such as sterling silver used in jewelry, cupronickel used to make marine hardware and coins, and constantan used in strain gauges and thermocouples for temperature measurement. Copper is one of the few metals that can occur in nature in a directly usable metallic form ( native metals). This led to very early human use in several regions, from circa 8000 BC. Thousands of years later, it was the first metal to be smelted from sulfide ores, circa 5000 BC; the first metal to be cast into a shape in a mold, c. 4000 BC; and the first metal to be purposely alloyed with another metal, tin, to create ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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