Coning And Quartering
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Coning And Quartering
In analytical chemistry, sub-sampling is a procedure by which a small, representative sample is taken from a larger sample. Good sub-sampling technique becomes important when the large sample is not homogeneous. Techniques Coning and quartering Coning and quartering is a method used by analytical chemists to reduce the sample size of a powder without creating a systematic bias. The technique involves pouring the sample so that it takes on a conical shape, and then flattening it out into a cake. The cake is then divided into quarters; the two quarters which sit opposite one another are discarded, while the other two are combined and constitute the reduced sample. The same process is continued until an appropriate sample size remains. Analyses are made with respect to the sample left behind. Riffle box splitting A riffle box is a box containing a number (between 3 and 12) of "chutes" - slotted paths through which particles of the sample may slide. The sample is dropped into ...
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Analytical Chemistry
Analytical chemistry studies and uses instruments and methods to separate, identify, and quantify matter. In practice, separation, identification or quantification may constitute the entire analysis or be combined with another method. Separation isolates analytes. Qualitative analysis identifies analytes, while quantitative analysis determines the numerical amount or concentration. Analytical chemistry consists of classical, wet chemical methods and modern, instrumental methods. Classical qualitative methods use separations such as precipitation, extraction, and distillation. Identification may be based on differences in color, odor, melting point, boiling point, solubility, radioactivity or reactivity. Classical quantitative analysis uses mass or volume changes to quantify amount. Instrumental methods may be used to separate samples using chromatography, electrophoresis or field flow fractionation. Then qualitative and quantitative analysis can be performed, often with ...
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Representative Sample
In statistics, quality assurance, and survey methodology, sampling is the selection of a subset (a statistical sample) of individuals from within a statistical population to estimate characteristics of the whole population. Statisticians attempt to collect samples that are representative of the population in question. Sampling has lower costs and faster data collection than measuring the entire population and can provide insights in cases where it is infeasible to measure an entire population. Each observation measures one or more properties (such as weight, location, colour or mass) of independent objects or individuals. In survey sampling, weights can be applied to the data to adjust for the sample design, particularly in stratified sampling. Results from probability theory and statistical theory are employed to guide the practice. In business and medical research, sampling is widely used for gathering information about a population. Acceptance sampling is used to determi ...
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Homogeneous (chemistry)
In chemistry, a mixture is a material made up of two or more different chemical substances which are not chemically bonded. A mixture is the physical combination of two or more substances in which the identities are retained and are mixed in the form of solutions, suspensions and colloids. Mixtures are one product of mechanically blending or mixing chemical substances such as elements and compounds, without chemical bonding or other chemical change, so that each ingredient substance retains its own chemical properties and makeup. Despite the fact that there are no chemical changes to its constituents, the physical properties of a mixture, such as its melting point, may differ from those of the components. Some mixtures can be separated into their components by using physical (mechanical or thermal) means. Azeotropes are one kind of mixture that usually poses considerable difficulties regarding the separation processes required to obtain their constituents (physical or chemical ...
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Sample (material)
In general, a sample is a limited quantity of something which is intended to be similar to and represent a larger amount of that thing(s). The things could be countable objects such as individual items available as units for sale, or an uncountable material. Even though the word "sample" implies a smaller quantity taken from a larger amount, sometimes full biological or mineralogical specimens are called samples if they are taken for analysis, testing, or investigation like other samples. They are also considered samples in the sense that even whole specimens are "samples" of the full population of many individual organisms. The act of obtaining a sample is called "sampling" and can be performed manually by a person or by automatic process. Samples of material can be taken or provided for testing, analysis, investigation, quality control, demonstration, or trial use. Sometimes, sampling may be performed continuously. Aliquot part In science, a representative liquid sample t ...
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