Clay–water Interaction
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Clay–water Interaction
Clay-water interaction is an all-inclusive term to describe various progressive interactions between clay minerals and water. In the dry state, clay packets exist in face-to-face stacks like a deck of playing cards, but clay packets begin to change when exposed to water. Five descriptive terms describe the progressive interactions that can occur in a clay-water system, such as a water mud. (1) Hydration occurs as clay packets absorb water and swell. (2) Dispersion (or disaggregation) causes clay platelets to break apart and disperse into the water due to loss of attractive forces as water forces the platelets farther apart. (3) Flocculation begins when mechanical shearing stops and platelets previously dispersed come together due to the attractive force of surface charges on the platelets. (4) Deflocculation, or peptization, the opposite effect, occurs by addition of chemical deflocculant to flocculated mud; the positive edge charges are covered and attraction forces are gr ...
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Clay Mineral
Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay minerals form in the presence of water and have been important to life, and many theories of abiogenesis involve them. They are important constituents of soils, and have been useful to humans since ancient times in agriculture and manufacturing. Properties Clay is a very fine-grained geologic material that develops plasticity when wet, but becomes hard, brittle and non–plastic upon drying or firing. It is a very common material, and is the oldest known ceramic. Prehistoric humans discovered the useful properties of clay and used it for making pottery. The chemistry of clay, including its capacity to retain nutrient cations such as potassium and ammonium, is important to soil fertility. Because the individual particles in clay are less than ...
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Water
Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a solvent). It is vital for all known forms of life, despite not providing food, energy or organic micronutrients. Its chemical formula, H2O, indicates that each of its molecules contains one oxygen and two hydrogen atoms, connected by covalent bonds. The hydrogen atoms are attached to the oxygen atom at an angle of 104.45°. "Water" is also the name of the liquid state of H2O at standard temperature and pressure. A number of natural states of water exist. It forms precipitation in the form of rain and aerosols in the form of fog. Clouds consist of suspended droplets of water and ice, its solid state. When finely divided, crystalline ice may precipitate in the form of snow. The gaseous state of water is steam or water vapor. Water co ...
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Mineral Hydration
In chemistry, mineral hydration is an inorganic chemical reaction which adds water to the crystal structure of a mineral, usually creating a new mineral, usually called a ''hydrate''. In geological terms, the process of mineral hydration is known as ''retrograde alteration'' and is a process occurring in retrograde metamorphism. It commonly accompanies metasomatism and is often a feature of wall rock alteration around ore bodies. Hydration of minerals occurs generally in concert with hydrothermal circulation which may be driven by tectonic or igneous activity. Processes There are two main ways in which minerals hydrate. One is conversion of an oxide to a double hydroxide, as with the hydration of calcium oxide—CaO—to calcium hydroxide—Ca(OH)2, the other is with the incorporation of water molecules directly into the crystalline structure of a new mineral. The later process is exhibited in the hydration of feldspars to clay minerals, garnet to chlorite, or kyanite to m ...
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Dispersion (chemistry)
A dispersion is a system in which distributed particles of one material are dispersed in a continuous phase of another material. The two phases may be in the same or different states of matter. Dispersions are classified in a number of different ways, including how large the particles are in relation to the particles of the continuous phase, whether or not precipitation occurs, and the presence of Brownian motion. In general, dispersions of particles sufficiently large for sedimentation are called suspensions, while those of smaller particles are called colloids and solutions. Structure and properties Dispersions do not display any structure; i.e., the particles (or in case of emulsions: droplets) dispersed in the liquid or solid matrix (the "dispersion medium") are assumed to be statistically distributed. Therefore, for dispersions, usually percolation theory is assumed to appropriately describe their properties. However, percolation theory can be applied only if the sys ...
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Flocculation
Flocculation, in the field of chemistry, is a process by which colloidal particles come out of suspension to sediment under the form of floc or flake, either spontaneously or due to the addition of a clarifying agent. The action differs from precipitation in that, prior to flocculation, colloids are merely suspended, under the form of a stable dispersion (where the internal phase (solid) is dispersed throughout the external phase (fluid) through mechanical agitation) and are not truly dissolved in solution. Coagulation and flocculation are important processes in water treatment with coagulation aimed to destabilize and aggregate particles through chemical interactions between the coagulant and colloids, and flocculation to sediment the destabilized particles by causing their aggregation into floc. Term definition According to the IUPAC definition, flocculation is "a process of contact and adhesion whereby the particles of a dispersion form larger-size clusters". Flocculation ...
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Peptization
Peptization or deflocculation is the process of converting precipitate into colloid by shaking it with a suitable electrolyte called peptizing agent. This is particularly important in colloid chemistry or for precipitation reactions in an aqueous solution. When colloidal particles bear a same sign electric charge, they mutually repel each other and cannot aggregate together. Freshly precipitated aluminium or iron hydroxide is extremely difficult to filter because the very fine colloidal particles directly pass through a paper filter. To facilitate the filtration, the colloidal suspension must be first flocculated by adding a concentrated solution of salt to the system. Multivalent cations are more efficient flocculants than monovalent cations: AlCl3 > CaCl2 > NaCl. The electrical charges present at the surface of the particles are so "''neutralised''" and disappear. More correctly speaking, the electrical double layer existing at the surface of the particles is compressed by the ...
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Peptization
Peptization or deflocculation is the process of converting precipitate into colloid by shaking it with a suitable electrolyte called peptizing agent. This is particularly important in colloid chemistry or for precipitation reactions in an aqueous solution. When colloidal particles bear a same sign electric charge, they mutually repel each other and cannot aggregate together. Freshly precipitated aluminium or iron hydroxide is extremely difficult to filter because the very fine colloidal particles directly pass through a paper filter. To facilitate the filtration, the colloidal suspension must be first flocculated by adding a concentrated solution of salt to the system. Multivalent cations are more efficient flocculants than monovalent cations: AlCl3 > CaCl2 > NaCl. The electrical charges present at the surface of the particles are so "''neutralised''" and disappear. More correctly speaking, the electrical double layer existing at the surface of the particles is compressed by the ...
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Particle Aggregation
Particle agglomeration refers to formation of assemblages in a suspension and represents a mechanism leading to the functional destabilization of colloidal systems. During this process, particles dispersed in the liquid phase stick to each other, and spontaneously form irregular particle assemblages, flocs, or agglomerates. This phenomenon is also referred to as coagulation or flocculation and such a suspension is also called ''unstable''. Particle agglomeration can be induced by adding salts or other chemicals referred to as coagulant or flocculant.M. Elimelech, J. Gregory, X. Jia, R. Williams, ''Particle Deposition and Aggregation: Measurement, Modelling and Simulation'', Butterworth-Heinemann, 1998. Particle agglomeration can be a reversible or irreversible process. Particle agglomerates defined as "hard agglomerates" are more difficult to redisperse to the initial single particles. In the course of agglomeration, the agglomerates will grow in size, and as a consequence they ma ...
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Dispersity
In chemistry, the dispersity is a measure of the heterogeneity of sizes of molecules or particles in a mixture. A collection of objects is called uniform if the objects have the same size, shape, or mass. A sample of objects that have an inconsistent size, shape and mass distribution is called non-uniform. The objects can be in any form of chemical dispersion, such as particles in a colloid, droplets in a cloud, crystals in a rock, or polymer macromolecules in a solution or a solid polymer mass. Polymers can be described by molecular mass distribution; a population of particles can be described by size, surface area, and/or mass distribution; and thin films can be described by film thickness distribution. IUPAC has deprecated the use of the term ''polydispersity index'', having replaced it with the term ''dispersity'', represented by the symbol Đ (pronounced D-strokeStepto, R. F. T.; Gilbert, R. G.; Hess, M.; Jenkins, A. D.; Jones, R. G.; Kratochvíl P. (2009).Dispersity in Po ...
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Quick Clay
Quick clay, also known as Leda clay and Champlain Sea clay in Canada, is any of several distinctively sensitive glaciomarine clays found in Canada, Norway, Russia, Sweden, Finland, the United States and other locations around the world. The clay is so unstable that when a mass of quick clay is subjected to sufficient stress, the material behavior may drastically change from that of a particulate material to that of a watery fluid. Landslides occur because of the sudden soil liquefaction caused by external sollicitations such as vibrations induced by an earthquake, or massive rainfalls. Quick clay main deposits Quick clay is found only in countries close to the north pole, such as Russia; Canada; Norway; Sweden; and Finland; and in Alaska, United States; since they were glaciated during the Pleistocene epoch. In Canada, the clay is associated primarily with the Pleistocene-era Champlain Sea, in the modern Ottawa Valley, the St. Lawrence Valley, and the Saguenay River regions. Qu ...
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Water
Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a solvent). It is vital for all known forms of life, despite not providing food, energy or organic micronutrients. Its chemical formula, H2O, indicates that each of its molecules contains one oxygen and two hydrogen atoms, connected by covalent bonds. The hydrogen atoms are attached to the oxygen atom at an angle of 104.45°. "Water" is also the name of the liquid state of H2O at standard temperature and pressure. A number of natural states of water exist. It forms precipitation in the form of rain and aerosols in the form of fog. Clouds consist of suspended droplets of water and ice, its solid state. When finely divided, crystalline ice may precipitate in the form of snow. The gaseous state of water is steam or water vapor. Water co ...
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Clay
Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4). Clays develop plasticity when wet, due to a molecular film of water surrounding the clay particles, but become hard, brittle and non–plastic upon drying or firing. Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impurities, such as a reddish or brownish colour from small amounts of iron oxide. Clay is the oldest known ceramic material. Prehistoric humans discovered the useful properties of clay and used it for making pottery. Some of the earliest pottery shards have been dated to around 14,000 BC, and clay tablets were the first known writing medium. Clay is used in many modern industrial processes, such as paper making, cement production, and chemical filtering. Between one-half and two-thirds of the world's population live or work in buildings made with clay, often ...
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