Chamaecydin
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Chamaecydin
Chamaecydin is a chemical compound with the molecular formula C30H40O3. It is made up of three six-membered rings and two five-membered rings and has one polar hydroxyl functional group. It is well preserved in the rock record and is only found in a specific family of conifers, the swamp cypress subfamily. The presence and abundance of chamaecydin in the rock record can reveal environmental changes in ancient biomes. Background Notable properties The molecule has a mass of 448.298 Daltons, and consists of two carbonyl groups and three double bonds. It is a hexacarboxylic triterpene. The 2d structure is shown in Figure 1. The physical properties are not well known; the melting point of chamaecydin is 197-198 C. Its crystal structure is orthorhombic. Chamaecydin shows significant antifeedant activity against the larvae of '' Spodoptera Iitura'' and has an antifeedant index (AFI) of 0.44. The index ranges from 1 to -1, with one being the most powerful antifeedant. It is calcula ...
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Chamaecyparis Obtusa
''Chamaecyparis obtusa'' (Japanese cypress, hinoki cypress or hinoki; ja, 檜 or , ) is a species of cypress native to central Japan in East Asia, and widely cultivated in the temperate northern hemisphere for its high-quality timber and ornamental qualities, with many cultivars commercially available. Description It is a slow-growing tree which may reach tall with a trunk up to in diameter. The bark is dark red-brown. The leaves are scale-like, long, blunt tipped (obtuse), green above, and green below with a white stomatal band at the base of each scale-leaf. The cones are globose, in diameter, with 8–12 scales arranged in opposite pairs. Related species The plant is widespread in Japan. The related '' Chamaecyparis pisifera'' (sawara cypress) can be readily distinguished in its having pointed tips to the leaves and smaller cones. A similar cypress found on Taiwan is treated by different botanists as either a variety of this species (as ''Chamaecyparis obtusa'' va ...
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Triterpene
Triterpenes are a class of chemical compounds composed of three terpene units with the molecular formula C30H48; they may also be thought of as consisting of six isoprene units. Animals, plants and fungi all produce triterpenes, including squalene, the precursor to all steroids. Structures Triterpenes exist in a great variety of structures. Nearly 200 different skeletons have been identified. These skeletons may be broadly divided according to the number of rings present. In general pentacyclic structures (5 rings) tend to dominate. Squalene is biosynthesized through the head-to-head condensation of two farnesyl pyrophosphate units. This coupling converts a pair of C15 components into a C30 product. Squalene serves as precursor for the formation of many triterpenoids, including bacterial hopanoids and eukaryotic sterols. Triterpenoids By definition triterpenoids are triterpenes that possess heteroatoms, usually oxygen. The terms ''triterpene'' and ''triterpenoid'' oft ...
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Hydroxy Group
In chemistry, a hydroxy or hydroxyl group is a functional group with the chemical formula and composed of one oxygen atom covalently bonded to one hydrogen atom. In organic chemistry, alcohols and carboxylic acids contain one or more hydroxy groups. Both the negatively charged anion , called hydroxide, and the neutral radical , known as the hydroxyl radical, consist of an unbonded hydroxy group. According to IUPAC definitions, the term ''hydroxyl'' refers to the hydroxyl radical () only, while the functional group is called a ''hydroxy group''. Properties Water, alcohols, carboxylic acids, and many other hydroxy-containing compounds can be readily deprotonated due to a large difference between the electronegativity of oxygen (3.5) and that of hydrogen (2.1). Hydroxy-containing compounds engage in intermolecular hydrogen bonding increasing the electrostatic attraction between molecules and thus to higher boiling and melting points than found for compounds that lack this ...
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Glyptostrobus Pensilis
''Glyptostrobus pensilis'', known in Chinese as 水松 (Shuǐ sōng), and also Chinese swamp cypress, is an endangered conifer, and the sole living species in the genus ''Glyptostrobus''. Description It is a medium-sized to large tree, reaching tall and with a trunk diameter of up to , possibly more. The leaves are deciduous, spirally arranged but twisted at the base to lie in two horizontal ranks, long and broad, but long and scale-like on shoots in the upper crown. The cones are green maturing yellow-brown, pear-shaped, long and diameter, broadest near the apex. They open when mature to release the small, long, winged seeds. Like the related genus ''Taxodium'', it produces 'cypress knees', or pneumatophores, when growing in water, thought to help transport oxygen to the roots. Distribution and habitat ''G. pensilis'' is native to subtropical southeastern China, from Fujian west to southeast Yunnan, and also very locally in northern Vietnam and Laos. It typically gro ...
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Pliocene
The Pliocene ( ; also Pleiocene) is the epoch in the geologic time scale that extends from 5.333 million to 2.58See the 2014 version of the ICS geologic time scale
million years ago. It is the second and most recent epoch of the Neogene Period in the . The Pliocene follows the Epoch and is followed by the Epoch. Prior to the 2009 ...
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Oligocene
The Oligocene ( ) is a geologic epoch of the Paleogene Period and extends from about 33.9 million to 23 million years before the present ( to ). As with other older geologic periods, the rock beds that define the epoch are well identified but the exact dates of the start and end of the epoch are slightly uncertain. The name Oligocene was coined in 1854 by the German paleontologist Heinrich Ernst Beyrich from his studies of marine beds in Belgium and Germany. The name comes from the Ancient Greek (''olígos'', "few") and (''kainós'', "new"), and refers to the sparsity of extant forms of molluscs. The Oligocene is preceded by the Eocene Epoch and is followed by the Miocene Epoch. The Oligocene is the third and final epoch of the Paleogene Period. The Oligocene is often considered an important time of transition, a link between the archaic world of the tropical Eocene and the more modern ecosystems of the Miocene. Major changes during the Oligocene included a global expansion o ...
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Marine Regression
A marine regression is a geological process occurring when areas of submerged seafloor are exposed above the sea level. The opposite event, marine transgression, occurs when flooding from the sea covers previously-exposed land. Evidence of marine regressions and transgressions occurs throughout the fossil record, and the fluctuations are thought to have caused or contributed to several mass extinctions, such as the Permian-Triassic extinction event (250 million years ago) and Cretaceous–Paleogene extinction event (66 Ma). During the Permian-Triassic extinction, the largest extinction event in the Earth's history, the global sea level fell 250 m (820 ft). A major regression could itself cause marine organisms in shallow seas to go extinct, but mass extinctions tend to involve both terrestrial and aquatic species, and it is harder to see how a marine regression could cause widespread extinctions of land animals. Regressions are, therefore, seen as correlates or symptoms of major ...
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Limnic Eruption
A limnic eruption, also known as a lake overturn, is a very rare type of natural disaster in which dissolved carbon dioxide () suddenly erupts from deep lake waters, forming a gas cloud capable of suffocating wildlife, livestock, and humans. A limnic eruption may also cause tsunami or seiche as the rising displaces water. Scientists believe earthquakes, volcanic activity, and other explosive events can serve as triggers for limnic eruptions. Lakes in which such activity occurs are referred to as limnically active lakes or exploding lakes. Some features of limnically active lakes include: * -saturated incoming water * A cool lake bottom indicating an absence of direct volcanic interaction with lake waters * An upper and lower thermal layer with differing saturations * Proximity to areas with volcanic activity Investigations of the Lake Monoun and Lake Nyos casualties led scientists to classify limnic eruptions as a distinct type of disaster event, even though they can be indirect ...
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Conifer
Conifers are a group of conifer cone, cone-bearing Spermatophyte, seed plants, a subset of gymnosperms. Scientifically, they make up the phylum, division Pinophyta (), also known as Coniferophyta () or Coniferae. The division contains a single extant class (biology), class, Pinopsida. All Neontology, extant conifers are perennial plant, perennial woody plants with secondary growth. The great majority are trees, though a few are shrubs. Examples include Cedrus, cedars, Pseudotsuga, Douglas-firs, Cupressaceae, cypresses, firs, junipers, Agathis, kauri, larches, pines, Tsuga, hemlocks, Sequoioideae, redwoods, spruces, and Taxaceae, yews.Campbell, Reece, "Phylum Coniferophyta". Biology. 7th. 2005. Print. P. 595 As of 1998, the division Pinophyta was estimated to contain eight families, 68 genera, and 629 living species. Although the total number of species is relatively small, conifers are ecology, ecologically important. They are the dominant plants over large areas of land, most ...
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Ferruginol
Ferruginol is a natural phenol with a terpenoid substructure. Specifically, it is a diterpene of the abietane chemical class, meaning it is characterized by three fused six-membered rings and alkyl functional groups. Ferruginol was first identified in 1939 by Brandt and Neubauer as the main component in the resin of the Prumnopitys ferruginea, Miro tree (''Podocarpus ferrugneus)'' and has since been isolated from other conifer species in the families ''Cupressaceae'' and ''Podocarpaceae''. As a biomarker, the presence of ferruginol in fossils, mainly resin, is used to describe the density of these conifers in that particular biosphere throughout time. Background Ferruginol is a phenolic abietene, a type of tricyclic diterpenoid derived from terrestrial plants. It has a molecular composition of C20H30O with a molecular weight of 286 g/mole. Along with its presence in the ''Verbenaceae'' family, it has been found in a variety of conifer families including ''Podocarpaceae,'' the anc ...
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Biomarker
In biomedical contexts, a biomarker, or biological marker, is a measurable indicator of some biological state or condition. Biomarkers are often measured and evaluated using blood, urine, or soft tissues to examine normal biological processes, pathogenic processes, or pharmacologic responses to a therapeutic intervention. as cited in Biomarkers are used in many scientific fields. Medicine Biomarkers used in the medical field, are a part of a relatively new clinical toolset categorized by their clinical applications. The three main classes are molecular biomarkers, cellular biomarkers or imaging biomarkers. All three types of biomarkers have a clinical role in narrowing or guiding treatment decisions and follow a sub-categorization of being either predictive, prognostic, or diagnostic. Predictive Predictive molecular, cellular, or imaging biomarkers that pass validation can serve as a method of predicting clinical outcomes. Predictive biomarkers are used to help optimize id ...
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Cretaceous
The Cretaceous ( ) is a geological period that lasted from about 145 to 66 million years ago (Mya). It is the third and final period of the Mesozoic Era, as well as the longest. At around 79 million years, it is the longest geological period of the entire Phanerozoic. The name is derived from the Latin ''creta'', "chalk", which is abundant in the latter half of the period. It is usually abbreviated K, for its German translation ''Kreide''. The Cretaceous was a period with a relatively warm climate, resulting in high eustatic sea levels that created numerous shallow inland seas. These oceans and seas were populated with now- extinct marine reptiles, ammonites, and rudists, while dinosaurs continued to dominate on land. The world was ice free, and forests extended to the poles. During this time, new groups of mammals and birds appeared. During the Early Cretaceous, flowering plants appeared and began to rapidly diversify, becoming the dominant group of plants across the Earth b ...
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