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A limnic eruption, also known as a lake overturn, is a very rare type of
natural disaster A natural disaster is "the negative impact following an actual occurrence of natural hazard in the event that it significantly harms a community". A natural disaster can cause loss of life or damage property, and typically leaves some econ ...
in which dissolved
carbon dioxide Carbon dioxide (chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is transpar ...
() suddenly erupts from deep lake waters, forming a gas cloud capable of suffocating wildlife, livestock, and humans. A limnic eruption may also cause
tsunami A tsunami ( ; from ja, 津波, lit=harbour wave, ) is a series of waves in a water body caused by the displacement of a large volume of water, generally in an ocean or a large lake. Earthquakes, volcanic eruptions and other underwater explo ...
or
seiche A seiche ( ) is a standing wave in an enclosed or partially enclosed body of water. Seiches and seiche-related phenomena have been observed on lakes, reservoirs, swimming pools, bays, harbors, caves and seas. The key requirement for formation o ...
as the rising displaces water. Scientists believe
earthquake An earthquake (also known as a quake, tremor or temblor) is the shaking of the surface of the Earth resulting from a sudden release of energy in the Earth's lithosphere that creates seismic waves. Earthquakes can range in intensity, from ...
s,
volcanic activity Volcanism, vulcanism or volcanicity is the phenomenon of eruption of molten rock (magma) onto the surface of the Earth or a solid-surface planet or moon, where lava, pyroclastics, and volcanic gases erupt through a break in the surface called a ...
, and other explosive events can serve as triggers for limnic eruptions. Lakes in which such activity occurs are referred to as limnically active lakes or exploding lakes. Some features of limnically active lakes include: * -saturated incoming water * A cool lake bottom indicating an absence of direct volcanic interaction with lake waters * An upper and lower thermal layer with differing saturations * Proximity to areas with volcanic activity Investigations of the
Lake Monoun Lake Monoun is a crater lake ( maar) in West Province, Cameroon, that lies in the Oku Volcanic Field. On August 15, 1984, a limnic eruption occurred at the lake, which resulted in the release of a large amount of carbon dioxide () that killed 37 ...
and
Lake Nyos Lake Nyos ( ) is a crater lake in the Region of Cameroon, located about northwest of Yaoundé, the capital. Nyos is a deep lake high on the flank of an inactive volcano in the Oku volcanic plain along the Cameroon line of volcanic activity ...
casualties led scientists to classify limnic eruptions as a distinct type of disaster event, even though they can be indirectly linked to volcanic eruptions.Volcanic Lakes and Gas Releases
USG
Cascades Volcano Observatory
Vancouver, Washington.


Historical occurrences

Due to the largely invisible nature of the underlying cause ( gas) behind limnic eruptions, it is difficult to determine to what extent eruptions have occurred in the past. The
Roman Roman or Romans most often refers to: *Rome, the capital city of Italy *Ancient Rome, Roman civilization from 8th century BC to 5th century AD *Roman people, the people of ancient Rome *''Epistle to the Romans'', shortened to ''Romans'', a letter ...
historian
Plutarch Plutarch (; grc-gre, Πλούταρχος, ''Ploútarchos''; ; – after AD 119) was a Greek Middle Platonist philosopher, historian, biographer, essayist, and priest at the Temple of Apollo in Delphi. He is known primarily for his ''P ...
reports that in 406BC,
Lake Albano Lake Albano (Italian: ''Lago Albano'' or ''Lago di Castel Gandolfo'') is a small volcanic crater lake in the Alban Hills of Lazio, at the foot of Monte Cavo, southeast of Rome. Castel Gandolfo, overlooking the lake, is the site of the Papal Pa ...
surged over the surrounding hills, despite there being no rain nor tributaries flowing into the lake to account for the rise in water level. The ensuing flood destroyed fields and vineyards before eventually pouring into the sea. This event is thought to have been caused by volcanic gases, trapped in sediment at the bottom of the lake and gradually building up until suddenly releasing, causing the water to overflow. In recent history, this phenomenon has been observed twice. The first recorded limnic eruption occurred in
Cameroon Cameroon (; french: Cameroun, ff, Kamerun), officially the Republic of Cameroon (french: République du Cameroun, links=no), is a country in west-central Africa. It is bordered by Nigeria to the west and north; Chad to the northeast; the C ...
at
Lake Monoun Lake Monoun is a crater lake ( maar) in West Province, Cameroon, that lies in the Oku Volcanic Field. On August 15, 1984, a limnic eruption occurred at the lake, which resulted in the release of a large amount of carbon dioxide () that killed 37 ...
in 1984, causing
asphyxia Asphyxia or asphyxiation is a condition of deficient supply of oxygen to the body which arises from abnormal breathing. Asphyxia causes generalized hypoxia, which affects primarily the tissues and organs. There are many circumstances that can i ...
tion and death of 37 people living nearby. A second, deadlier eruption happened at neighboring
Lake Nyos Lake Nyos ( ) is a crater lake in the Region of Cameroon, located about northwest of Yaoundé, the capital. Nyos is a deep lake high on the flank of an inactive volcano in the Oku volcanic plain along the Cameroon line of volcanic activity ...
in 1986, releasing over 80 million m3 of , killing around 1,700 people and 3,000 livestock, again by asphyxiation. A third lake, the much larger
Lake Kivu Lake Kivu is one of the African Great Lakes. It lies on the border between the Democratic Republic of the Congo and Rwanda, and is in the Albertine Rift, the western branch of the East African Rift. Lake Kivu empties into the Ruzizi River, whic ...
, rests on the border between the
Democratic Republic of the Congo The Democratic Republic of the Congo (french: République démocratique du Congo (RDC), colloquially "La RDC" ), informally Congo-Kinshasa, DR Congo, the DRC, the DROC, or the Congo, and formerly and also colloquially Zaire, is a country in ...
and
Rwanda Rwanda (; rw, u Rwanda ), officially the Republic of Rwanda, is a landlocked country in the Great Rift Valley of Central Africa, where the African Great Lakes region and Southeast Africa converge. Located a few degrees south of the Equator ...
, and contains massive amounts of dissolved . Sediment samples taken from the lake showed an event caused living creatures in the lake to go extinct around every 1,000 years, and caused nearby vegetation to be swept back into the lake. Limnic eruptions can be detected and quantified on a concentration scale by taking air samples of the affected region. The
Messel pit The Messel pit (german: Grube Messel) is a disused quarry near the village of Messel (Landkreis Darmstadt-Dieburg, Hesse) about southeast of Frankfurt am Main, Germany. Bituminous shale was mined there. Because of its abundance of well-preserved ...
fossil A fossil (from Classical Latin , ) is any preserved remains, impression, or trace of any once-living thing from a past geological age. Examples include bones, shells, exoskeletons, stone imprints of animals or microbes, objects preserved ...
deposits of
Messel Messel is a municipality in the district of Darmstadt-Dieburg in Hesse near Frankfurt am Main in Germany. The village is first mentioned, as ''Masilla'', in the Lorsch codex. Messel was the property of the lords of Groschlag from ca. 1400 to 1799 ...
,
Germany Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated betwe ...
, show evidence of a limnic eruption there in the early
Eocene The Eocene ( ) Epoch is a geological epoch (geology), epoch that lasted from about 56 to 33.9 million years ago (mya). It is the second epoch of the Paleogene Period (geology), Period in the modern Cenozoic Era (geology), Era. The name ''Eocene' ...
. Among the victims are perfectly preserved
insect Insects (from Latin ') are pancrustacean hexapod invertebrates of the class Insecta. They are the largest group within the arthropod phylum. Insects have a chitinous exoskeleton, a three-part body ( head, thorax and abdomen), three pairs ...
s,
frog A frog is any member of a diverse and largely Carnivore, carnivorous group of short-bodied, tailless amphibians composing the order (biology), order Anura (ανοὐρά, literally ''without tail'' in Ancient Greek). The oldest fossil "proto-f ...
s,
turtle Turtles are an order of reptiles known as Testudines, characterized by a special shell developed mainly from their ribs. Modern turtles are divided into two major groups, the Pleurodira (side necked turtles) and Cryptodira (hidden necked tu ...
s,
crocodile Crocodiles (family (biology), family Crocodylidae) or true crocodiles are large semiaquatic reptiles that live throughout the tropics in Africa, Asia, the Americas and Australia. The term crocodile is sometimes used even more loosely to inclu ...
s,
bird Birds are a group of warm-blooded vertebrates constituting the class Aves (), characterised by feathers, toothless beaked jaws, the laying of hard-shelled eggs, a high metabolic rate, a four-chambered heart, and a strong yet lightweigh ...
s, anteaters,
insectivore A robber fly eating a hoverfly An insectivore is a carnivorous animal or plant that eats insects. An alternative term is entomophage, which can also refer to the human practice of eating insects. The first vertebrate insectivores wer ...
s, early
primate Primates are a diverse order of mammals. They are divided into the strepsirrhines, which include the lemurs, galagos, and lorisids, and the haplorhines, which include the tarsiers and the simians (monkeys and apes, the latter including huma ...
s, and paleotheres.


Causes

For a lake to undergo a limnic eruption, the water must be nearly
saturated Saturation, saturated, unsaturation or unsaturated may refer to: Chemistry * Saturation, a property of organic compounds referring to carbon-carbon bonds ** Saturated and unsaturated compounds **Degree of unsaturation ** Saturated fat or fatty ac ...
with gas. was the primary component in the two observed cases (Lake Nyos and Lake Monoun). In Lake Kivu, scientists are concerned about the concentrations of
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on Eart ...
gas as well. may originate from
volcanic gas Volcanic gases are gases given off by active (or, at times, by dormant) volcanoes. These include gases trapped in cavities (vesicles) in volcanic rocks, dissolved or dissociated gases in magma and lava, or gases emanating from lava, from volcanic ...
emitted from under the lake or from decomposition of organic material. Before a lake is saturated, it behaves like an unopened
carbonated beverage A soft drink (see § Terminology for other names) is a drink that usually contains water (often carbonated), a sweetener, and a natural and/or artificial flavoring. The sweetener may be a sugar, high-fructose corn syrup, fruit juice, a sugar ...
(e.g., a
soft drink A soft drink (see § Terminology for other names) is a drink that usually contains water (often carbonated), a sweetener, and a natural and/or artificial flavoring. The sweetener may be a sugar, high-fructose corn syrup, fruit juice, a su ...
): the is dissolved in the water. In both the lake and the soft drink, dissolves much more readily at higher
pressure Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and e ...
(
Henry's law In physical chemistry, Henry's law is a gas law that states that the amount of dissolved gas in a liquid is directly proportional to its partial pressure above the liquid. The proportionality factor is called Henry's law constant. It was formulat ...
). This is why bubbles in a can of soda form only after the can is opened; when the pressure is released, the comes out of
solution Solution may refer to: * Solution (chemistry), a mixture where one substance is dissolved in another * Solution (equation), in mathematics ** Numerical solution, in numerical analysis, approximate solutions within specified error bounds * Soluti ...
. In the case of lakes, the bottom is at a much higher pressure; the deeper it is, the higher the pressure is at the bottom. Therefore, huge amounts of can be dissolved in large, deep lakes. also dissolves more readily in cooler water, such as that found at a lake bottom. A small rise in water
temperature Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measured with a thermometer. Thermometers are calibrated in various temperature scales that historically have relied o ...
can lead to the release of a large amount of . Once a lake is saturated with , it is very unstable and it gives off a smell of rotten eggs and gun powder, but a trigger is needed to set off an eruption. In the case of the 1986 Lake Nyos eruption,
landslide Landslides, also known as landslips, are several forms of mass wasting that may include a wide range of ground movements, such as rockfalls, deep-seated grade (slope), slope failures, mudflows, and debris flows. Landslides occur in a variety of ...
s were the suspected triggers, but a volcanic eruption, an
earthquake An earthquake (also known as a quake, tremor or temblor) is the shaking of the surface of the Earth resulting from a sudden release of energy in the Earth's lithosphere that creates seismic waves. Earthquakes can range in intensity, from ...
, or even
wind Wind is the natural movement of air or other gases relative to a planet's surface. Winds occur on a range of scales, from thunderstorm flows lasting tens of minutes, to local breezes generated by heating of land surfaces and lasting a few hou ...
and rain storms are potential triggers. Another possible cause of a limnic eruption is gradual gas saturation at specific depths which can trigger spontaneous gas development. For any of these cases, the trigger pushes some of the gas-saturated water higher in the lake, where pressure is insufficient to keep in solution. As bubbles start forming the water is lifted even higher in the lake (
buoyancy Buoyancy (), or upthrust, is an upward force exerted by a fluid that opposes the weight of a partially or fully immersed object. In a column of fluid, pressure increases with depth as a result of the weight of the overlying fluid. Thus the p ...
), where yet more comes out of solution. This process forms a column of gas, at which point the water at the bottom of this column is pulled up by suction, and it, too, loses in a runaway process. This eruption discharges into the air and can displace enough water to form a tsunami. Limnic eruptions are exceptionally rare for several reasons. First, a source must exist (regions with volcanic activity are most at risk). Second, the vast majority of lakes are
holomictic Holomictic lakes are lakes that have a uniform temperature and density from surface to bottom at a specific time during the year, which allows the lake waters to mix in the absence of stratification. Details Holomictic lakes mix at least occasi ...
(i.e., their layers mix regularly), preventing a buildup of dissolved gases. Only
meromictic lake A meromictic lake is a lake which has layers of water that do not intermix. In ordinary, holomictic lakes, at least once each year, there is a physical mixing of the surface and the deep waters. The term ''meromictic'' was coined by the Austr ...
s do not mix and remain stratified, allowing to remain dissolved. It is estimated only one meromictic lake exists for every 1,000 holomictic lakes. Finally, a lake must be deep enough to have sufficient pressure to dissolve large amounts of .


Consequences

Once an eruption occurs, a large cloud forms above the lake and expands to the surrounding region. Because is
denser Density (volumetric mass density or specific mass) is the substance's mass per unit of volume. The symbol most often used for density is ''ρ'' (the lower case Greek language, Greek letter Rho (letter), rho), although the Latin letter ''D'' ca ...
than air, it has a tendency to sink to the ground, simultaneously displacing breathable air, resulting in
asphyxia Asphyxia or asphyxiation is a condition of deficient supply of oxygen to the body which arises from abnormal breathing. Asphyxia causes generalized hypoxia, which affects primarily the tissues and organs. There are many circumstances that can i ...
. can make human bodily fluids highly acidic and potentially cause poisoning. As victims gasp for air, they actually accelerate asphyxia by inhaling . At Lake Nyos, the gas cloud descended into a nearby village where it settled, killing nearly everyone; casualties as far as were reported. A change in skin color on some bodies led scientists to hypothesize the gas cloud may have contained dissolved acid such as
hydrogen chloride The compound hydrogen chloride has the chemical formula and as such is a hydrogen halide. At room temperature, it is a colourless gas, which forms white fumes of hydrochloric acid upon contact with atmospheric water vapor. Hydrogen chloride ga ...
, though this hypothesis is disputed. Many victims were found with blisters on their skin, thought to have been caused by
pressure ulcer Pressure ulcers, also known as pressure sores, bed sores or pressure injuries, are localised damage to the skin and/or underlying tissue that usually occur over a bony prominence as a result of usually long-term pressure, or pressure in combi ...
s, which were likely caused by low blood oxygen levels in those asphyxiated by carbon dioxide.BBC Horizon programme "Killer Lakes"
/ref> Nearby vegetation was largely unaffected, except any growing immediately adjacent to the lake. There, vegetation was damaged or destroyed by a high tsunami caused by the violent eruption.


Degassing

Efforts are under way to develop a solution for removing the gas from these lakes and to prevent a build-up which could lead to another catastrophe. A team led by French scientist Michel Halbwachs began experimenting at
Lake Monoun Lake Monoun is a crater lake ( maar) in West Province, Cameroon, that lies in the Oku Volcanic Field. On August 15, 1984, a limnic eruption occurred at the lake, which resulted in the release of a large amount of carbon dioxide () that killed 37 ...
and
Lake Nyos Lake Nyos ( ) is a crater lake in the Region of Cameroon, located about northwest of Yaoundé, the capital. Nyos is a deep lake high on the flank of an inactive volcano in the Oku volcanic plain along the Cameroon line of volcanic activity ...
in 1990 using
siphon A siphon (from grc, σίφων, síphōn, "pipe, tube", also spelled nonetymologically syphon) is any of a wide variety of devices that involve the flow of liquids through tubes. In a narrower sense, the word refers particularly to a tube in a ...
s to degas the waters of these lakes in a controlled manner. The team positioned a pipe vertically in the lake with its upper end above the water surface. Water saturated with enters the bottom of the pipe and rises to the top. The lower pressure at the surface allows the gas to come out of solution. Only a small amount of water must be mechanically pumped initially through the pipe to start the flow. As saturated water rises, the comes out of solution and forms bubbles. The natural buoyancy of the bubbles draws the water up the pipe at high velocity resulting in a fountain at the surface. The degassifying water acts like a pump, drawing more water into the bottom of the pipe, and creating a self-sustaining flow. This is the same process which leads to a natural eruption, but in this case it is controlled by the size of the pipe. Each pipe has a limited pumping capacity and several would be required for both Lake Monoun and Lake Nyos to degas a significant fraction of the deep lake water and render the lakes safe. The deep lake waters are slightly acidic due to the dissolved which causes corrosion to the pipes and electronics, necessitating ongoing maintenance. There is some concern that from the pipes could settle on the surface of the lake forming a thin layer of unbreathable air and thus potentially causing problems for wildlife. In January 2001, a single pipe was installed by the French-Cameroonian team on Lake Nyos, and two more pipes were installed in 2011 with funding support from the
United Nations Development Programme The United Nations Development Programme (UNDP)french: Programme des Nations unies pour le développement, PNUD is a United Nations agency tasked with helping countries eliminate poverty and achieve sustainable economic growth and human dev ...
. A pipe was installed at Lake Monoun in 2003 and two more were added in 2006. These three pipes are thought to be sufficient to prevent an increase in levels, removing approximately the same amount of gas that naturally enters at the lake bed. In January 2003, an 18-month project was approved to fully degas Lake Monoun, and the lake has since been rendered safe. There is some evidence that
Lake Michigan Lake Michigan is one of the five Great Lakes of North America. It is the second-largest of the Great Lakes by volume () and the third-largest by surface area (), after Lake Superior and Lake Huron. To the east, its basin is conjoined with that o ...
in the United States spontaneously degasses (the colloquial term used is "burps") on a much smaller scale each fall.


Lake Kivu risks

Lake Kivu Lake Kivu is one of the African Great Lakes. It lies on the border between the Democratic Republic of the Congo and Rwanda, and is in the Albertine Rift, the western branch of the East African Rift. Lake Kivu empties into the Ruzizi River, whic ...
is not only about 1,700 times larger than
Lake Nyos Lake Nyos ( ) is a crater lake in the Region of Cameroon, located about northwest of Yaoundé, the capital. Nyos is a deep lake high on the flank of an inactive volcano in the Oku volcanic plain along the Cameroon line of volcanic activity ...
, but is also located in a far more densely populated area, with over two million people living along its shores, and the part within the
Democratic Republic of the Congo The Democratic Republic of the Congo (french: République démocratique du Congo (RDC), colloquially "La RDC" ), informally Congo-Kinshasa, DR Congo, the DRC, the DROC, or the Congo, and formerly and also colloquially Zaire, is a country in ...
is a site of active armed conflict and low
state capacity State capacity is the ability of a government to accomplish policy goals, either generally or in reference to specific aims. A state that lacks capacity is defined as a fragile state or, in a more extreme case, a failed state. Higher state capacity ...
for the DRC government. Lake Kivu has not reached a high level of
saturation Saturation, saturated, unsaturation or unsaturated may refer to: Chemistry * Saturation, a property of organic compounds referring to carbon-carbon bonds **Saturated and unsaturated compounds ** Degree of unsaturation **Saturated fat or fatty aci ...
yet; if the water were to become heavily saturated, a limnic eruption would pose a great risk to human and animal life, potentially killing millions. Two significant changes in Lake Kivu's physical state have brought attention to a possible limnic eruption: the high rates of
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on Eart ...
dissociation and a rising surface temperature. Research investigating historical and present-day temperatures show Lake Kivu's surface temperature is increasing by about 0.12 °C per decade. Lake Kivu is in close proximity to potential triggers:
Mount Nyiragongo Mount Nyiragongo ( ) is an active stratovolcano with an elevation of in the Virunga Mountains associated with the Albertine Rift. It is located inside Virunga National Park, in the Democratic Republic of the Congo, about north of the town of ...
(an active volcano which erupted in January 2002 and May 2021), an active earthquake zone, and other active volcanoes. While the lake could be degassed in a manner similar to Lake Monoun and Lake Nyos, due to the size of Lake Kivu and the volume of gas it contains, such an operation would be expensive, running into the millions of dollars. A scheme initiated in 2010 to use methane trapped in the lake as a fuel source to generate electricity in
Rwanda Rwanda (; rw, u Rwanda ), officially the Republic of Rwanda, is a landlocked country in the Great Rift Valley of Central Africa, where the African Great Lakes region and Southeast Africa converge. Located a few degrees south of the Equator ...
has led to a degree of degassing. During the procedure for extracting the flammable methane gas used to fuel power stations on the shore, some is removed in a process known as catalyst scrubbing. It is unclear whether enough gas will be removed to eliminate the danger of a limnic eruption at Lake Kivu.


See also

*
Cold-water geyser Cold-water geysers have eruptions similar to those of hot-water geysers, except that -bubbles drive the eruption instead of steam from the proximity to magma. In cold-water geysers, -laden water lies in a confined aquifer, in which water and are ...
*
Mazuku In geology, a mazuku ( Swahili for "evil wind") is a pocket of carbon dioxide-rich air that can be lethal to any human or animal life inside. Mazuku are created when carbon dioxide accumulates in pockets low to the ground. CO2 is denser than air, w ...
*
Natural disaster A natural disaster is "the negative impact following an actual occurrence of natural hazard in the event that it significantly harms a community". A natural disaster can cause loss of life or damage property, and typically leaves some econ ...
*
Tsunamis in lakes A tsunami is a series of water waves caused by the displacement of a large volume within a body of water, often caused by earthquakes, or similar events. This may occur in lakes as well as oceans, presenting threats to both fishermen and shoreside ...


References


External links


Page of the team degassing Lake Nyos

Lake's silent killer to be disarmed





Cracking the Killer Lakes of Cameroon
* *


BBC Cameroons "killer lake" degassed


{{Types of volcanic eruptions Volcanic eruption types Geological hazards Natural disasters