Carl S. Marvel
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Carl S. Marvel
Carl Shipp "Speed" Marvel (September 11, 1894 – January 4, 1988) was an American chemist who specialized in polymer chemistry. He made important contributions to U.S. synthetic rubber program during World War II, and later worked at developing polybenzimidazoles, temperature-resistant polymers that are used in the aerospace industry, in fire-fighting equipment, and as a replacement for asbestos. He has been described as "one of the world's outstanding organic chemists" and received numerous awards, including the 1956 Priestley Medal and the 1986 National Medal of Science, presented by President Ronald Reagan. Early life and education Carl Shipp Marvel was born on September 11, 1894, in Waynesville, Illinois, U.S., to farmers John Thomas Marvel and Mary Lucy Wasson Marvel. An uncle urged him to study chemistry. Marvel attended Illinois Wesleyan University from 1911 to 1915. He graduated with an A.B. and M.S. in chemistry. On the recommendation of his advisor, Alfred W. Homb ...
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Waynesville, Illinois
Waynesville is a village in DeWitt County, Illinois, United States. The population was 381 at the 2020 census. History Waynesville is one of the oldest settlements in central Illinois. The area was first settled around 1825, by Prettyman Marvel and his wife, Rebecca (Barr) Marvel. They cleared an area of land near the present location of the village and were followed shortly thereafter by several other settlers. As a result, a small settlement sprung up about a mile south of Kickapoo Creek. In 1832, the first plats for the village were filed, and the name "Waynesville" (after the hero of the Revolutionary War, General Anthony Wayne) was selected. Town lots were auctioned off, and the sale announced in newspapers. However, economic circumstances meant that few lots were ever built upon. Within two or three decades, the village had reached a population of about 500, a figure where it would remain almost until the present. Sadly, Waynesville, although one of the first villages i ...
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University Of Illinois At Urbana-Champaign
The University of Illinois Urbana-Champaign (U of I, Illinois, University of Illinois, or UIUC) is a public land-grant research university in Illinois in the twin cities of Champaign and Urbana. It is the flagship institution of the University of Illinois system and was founded in 1867. Enrolling over 56,000 undergraduate and graduate students, the University of Illinois is one of the largest public universities by enrollment in the country. The University of Illinois Urbana-Champaign is a member of the Association of American Universities and is classified among "R1: Doctoral Universities – Very high research activity". In fiscal year 2019, research expenditures at Illinois totaled $652 million. The campus library system possesses the second-largest university library in the United States by holdings after Harvard University. The university also hosts the National Center for Supercomputing Applications and is home to the fastest supercomputer on a university campus ...
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Mass Spectrometry
Mass spectrometry (MS) is an analytical technique that is used to measure the mass-to-charge ratio of ions. The results are presented as a ''mass spectrum'', a plot of intensity as a function of the mass-to-charge ratio. Mass spectrometry is used in many different fields and is applied to pure samples as well as complex mixtures. A mass spectrum is a type of plot of the ion signal as a function of the mass-to-charge ratio. These spectra are used to determine the elemental or isotopic signature of a sample, the masses of particles and of molecules, and to elucidate the chemical identity or structure of molecules and other chemical compounds. In a typical MS procedure, a sample, which may be solid, liquid, or gaseous, is ionized, for example by bombarding it with a beam of electrons. This may cause some of the sample's molecules to break up into positively charged fragments or simply become positively charged without fragmenting. These ions (fragments) are then separated accordin ...
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Infrared Spectroscopy
Infrared spectroscopy (IR spectroscopy or vibrational spectroscopy) is the measurement of the interaction of infrared radiation with matter by absorption, emission, or reflection. It is used to study and identify chemical substances or functional groups in solid, liquid, or gaseous forms. It can be used to characterize new materials or identify and verify known and unknown samples. The method or technique of infrared spectroscopy is conducted with an instrument called an infrared spectrometer (or spectrophotometer) which produces an infrared spectrum. An IR spectrum can be visualized in a graph of infrared light absorbance (or transmittance) on the vertical axis vs. frequency, wavenumber or wavelength on the horizontal axis. Typical units of wavenumber used in IR spectra are reciprocal centimeters, with the symbol cm−1. Units of IR wavelength are commonly given in micrometers (formerly called "microns"), symbol μm, which are related to the wavenumber in a reciprocal way. A com ...
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Ammonium
The ammonium cation is a positively-charged polyatomic ion with the chemical formula or . It is formed by the protonation of ammonia (). Ammonium is also a general name for positively charged or protonated substituted amines and quaternary ammonium cations (), where one or more hydrogen atoms are replaced by organic groups (indicated by R). Acid–base properties The ammonium ion is generated when ammonia, a weak base, reacts with Brønsted acids (proton donors): :H+ + NH3 -> H4 The ammonium ion is mildly acidic, reacting with Brønsted bases to return to the uncharged ammonia molecule: : H4 + B- -> HB + NH3 Thus, treatment of concentrated solutions of ammonium salts with strong base gives ammonia. When ammonia is dissolved in water, a tiny amount of it converts to ammonium ions: :H2O + NH3 OH- + H4 The degree to which ammonia forms the ammonium ion depends on the pH of the solution. If the pH is low, the equilibrium shifts to the right: more ammonia molecules are co ...
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Phosphonium
In polyatomic cations with the chemical formula (where R is a hydrogen or an alkyl, aryl, or halide group). These cations have tetrahedral structures. The salts are generally colorless or take the color of the anions. Types of phosphonium cations Protonated phosphines The parent phosphonium is as found in the iodide salt, phosphonium iodide. Salts of the parent are rarely encountered, but this ion is an intermediate in the preparation of the industrially useful tetrakis(hydroxymethyl)phosphonium chloride: :PH3 + HCl + 4 CH2O → Many organophosphonium salts are produced by protonation of primary, secondary, and tertiary phosphines: :PR3 + H+ → The basicity of phosphines follows the usual trends, with R = alkyl being more basic than R = aryl. Tetraorganophosphonium cations The most common phosphonium compounds have four organic substituents attached to phosphorus. The quaternary phosphonium cations include tetraphenylphosphonium, (C6H5)4P+ and tetramethylphosphoni ...
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Ethane
Ethane ( , ) is an organic chemical compound with chemical formula . At standard temperature and pressure, ethane is a colorless, odorless gas. Like many hydrocarbons, ethane is isolated on an industrial scale from natural gas and as a petrochemical by-product of petroleum refining. Its chief use is as feedstock for ethylene production. Related compounds may be formed by replacing a hydrogen atom with another functional group; the ethane moiety is called an ethyl group. For example, an ethyl group linked to a hydroxyl group yields ethanol, the alcohol in beverages. History Ethane was first synthesised in 1834 by Michael Faraday, applying electrolysis of a potassium acetate solution. He mistook the hydrocarbon product of this reaction for methane and did not investigate it further. During the period 1847–1849, in an effort to vindicate the radical theory of organic chemistry, Hermann Kolbe and Edward Frankland produced ethane by the reductions of propionitrile (ethyl ...
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Organic Syntheses
''Organic Syntheses'' is a peer-reviewed scientific journal that was established in 1921. It publishes detailed and checked procedures for the synthesis of organic compounds. A unique feature of the review process is that all of the data and experiments reported in an article must be successfully repeated in the laboratory of a member of the editorial board as a check for reproducibility prior to publication. The journal is published by Organic Syntheses, Inc., a non-profit corporation. An annual print version is published by John Wiley & Sons on behalf of Organic Syntheses, Inc. History Prior to World War I, work on synthetic organic chemistry in the United States had been quite limited, and most of the reagents used in laboratories had to be imported from Europe. When export stoppages and trade embargoes cut off this source, Clarence Derick, a professor of chemistry at University of Illinois at Urbana-Champaign, began an effort to synthesize these needed chemicals in industr ...
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William Albert Noyes
William Albert Noyes (November 6, 1857 – October 24, 1941) was an American analytical and organic chemist. He made pioneering determinations of atomic weights, chaired the Chemistry Department at the University of Illinois at Urbana-Champaign from 1907 to 1926, was the founder and editor of several important chemical journals, and received the American Chemical Society's highest award, the Priestley Medal, in 1935. Early life and education Noyes was born on November 6, 1857, near Independence, Iowa. He earned A.B. and B.S. degrees from Grinnell College in 1879 (having originally enrolled in 1875 in classical studies, with chemistry as a side subject). As an undergraduate, in the winter quarters Noyes taught school full-time in the countryside. On graduating he studied and taught analytical chemistry at Grinnell, until he began graduate school at Johns Hopkins University in January 1881. There, working with Ira Remsen, Noyes earned his Ph.D. in 1882. His doctoral disserta ...
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DuPont
DuPont de Nemours, Inc., commonly shortened to DuPont, is an American multinational chemical company first formed in 1802 by French-American chemist and industrialist Éleuthère Irénée du Pont de Nemours. The company played a major role in the development of Delaware and first arose as a major supplier of gunpowder. DuPont developed many polymers such as Vespel, neoprene, nylon, Corian, Teflon, Mylar, Kapton, Kevlar, Zemdrain, M5 fiber, Nomex, Tyvek, Sorona, Corfam and Lycra in the 20th century, and its scientists developed many chemicals, most notably Freon (chlorofluorocarbons), for the refrigerant industry. It also developed synthetic pigments and paints including ChromaFlair. In 2015, DuPont and the Dow Chemical Company agreed to a reorganization plan in which the two companies would merge and split into three. As a merged entity, DuPont simultaneously acquired Dow and renamed itself to DowDuPont on August 31, 2017, and after 18 months spin off the merged entity' ...
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Alpha Chi Sigma
Alpha Chi Sigma () is a professional fraternity specializing in the fields of the chemical sciences. It has both collegiate and professional chapters throughout the United States consisting of both men and women and numbering more than 70,000 members. The fraternity aims to bring together students and professionals pursuing a wide variety of chemistry-related careers. History Founding The Alpha Chi Sigma fraternity was organized at the University of Wisconsin–Madison by a group of undergraduates who were fellow students in chemistry at that time. Later documents set the date of founding as December 11, 1902. The original founders were: * Raymond Tracy Conger * Harold Everett Eggers * Joseph Gerard Holty * Alfred Emil Kundert * Joseph Howard Mathews * Edward Gustav Mattke * Bart Eldred McCormick * Frank Joseph Petura * James Chisholm Silverthorn Coat of arms The seven symbols that stretch the length of the coat of arms are the "seven metals of the Ancients": gold, silver, ...
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Tau Kappa Epsilon
Tau Kappa Epsilon (), commonly known as or Teke, is a social college fraternity founded on January 10, 1899, at Illinois Wesleyan University. The organization has chapters throughout the United States and Canada, making the Fraternity an international organization. Since its founding in 1899, Tau Kappa Epsilon Fraternity has never had an exclusionary or discriminatory clause to prevent individuals from joining and has instead admitted members based on their "personal worth and character". As of fall 2022, there are 222 active chapters and colonies with over 296,000 lifetime members. While Tau Kappa Epsilon is primarily mentioned as a collegiate fraternity, the organization emphasizes that it is a "Fraternity for Life". Many chapters have active alumni associations that support philanthropic causes, mentor collegiate members, and host social events. Famous Teke alumni that continued their involvement with the Fraternity include NFL quarterback Terry Bradshaw, country music singer ...
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