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Carbene Radical
Carbene radicals are a special class of transition metal carbene complex, organometallic carbenes. The carbene radical (chemistry), radical can be formed by one-electron reduction of Fischer-type carbenes using an external reducing agent, or directly upon carbene formation at an open shell, open-shell transition metal complex (in particular low-spin cobalt(II) complexes) using diazo compounds and related carbene precursors. Cobalt(III)-carbene radicals have found catalytic applications in cyclopropanation reactions, as well as in a variety of other catalytic radical-type ring-closing reactions. Theoretical calculations and EPR studies confirmed their radical-type behaviour and explained the bonding interactions underlying the stability of the carbene radical. Stable carbene radicals of other metals are known, but the catalytically relevant cobalt(III)-carbene radicals have thus far only been synthesized as long-lived reactive intermediates. Bonding interacti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bonding Scheme Carbene Radical
Bonding may refer to: Arts and entertainment * Bonding (TV series), ''Bonding'' (TV series), a 2019 Netflix Original TV series * Bonding (Kim Possible), "Bonding" (''Kim Possible''), a 2004 episode of the television series ''Kim Possible'' * "The Bonding", a 1989 episode of the television series ''Star Trek: The Next Generation'' * The Bonding (album), ''The Bonding'' (album), a 2013 album by Austrian symphonic metal band Edenbridge Other uses * Bonding (dental), a dental procedure in which a dentist applies a resin material to the tooth See also * Human bonding * Female bonding * Male bonding * Channel bonding (or modem bonding), an arrangement in which two or more network interfaces on a host computer are combined ** NIC bonding, an alternate name for link aggregation * Electrical bonding, practice of connecting all metal objects in a room to protect from electric shock * Bonding, a method for creating electric interconnects: ** Ball bonding, a method very similar to wire bon ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
