High-pressure Steam Locomotives
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High-pressure Steam Locomotives
In science and engineering the study of high pressure examines its effects on materials and the design and construction of devices, such as a diamond anvil cell, which can create high pressure. By ''high pressure'' is usually meant pressures of thousands (kilobars) or millions (megabars) of times atmospheric pressure (about 1 bar or 100,000 Pa). History and overview Percy Williams Bridgman received a Nobel Prize in 1946 for advancing this area of physics by several magnitudes of pressure (400 MPa to 40,000 MPa). The list of founding fathers of this field includes also the names of Harry George Drickamer, Tracy Hall, Francis P. Bundy, Leonid F. Vereschagin, and Sergey M. Stishov. It was by applying high pressure as well as high temperature to carbon that man-made diamonds were first produced as well as many other interesting discoveries. Almost any material when subjected to high pressure will compact itself into a denser form, for example, quartz, also called silica or silicon dio ...
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Science
Science is a systematic endeavor that builds and organizes knowledge in the form of testable explanations and predictions about the universe. Science may be as old as the human species, and some of the earliest archeological evidence for scientific reasoning is tens of thousands of years old. The earliest written records in the history of science come from Ancient Egypt and Mesopotamia in around 3000 to 1200 BCE. Their contributions to mathematics, astronomy, and medicine entered and shaped Greek natural philosophy of classical antiquity, whereby formal attempts were made to provide explanations of events in the physical world based on natural causes. After the fall of the Western Roman Empire, knowledge of Greek conceptions of the world deteriorated in Western Europe during the early centuries (400 to 1000 CE) of the Middle Ages, but was preserved in the Muslim world during the Islamic Golden Age and later by the efforts of Byzantine Greek scholars who brought Greek ...
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Silica
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and most abundant families of materials, existing as a compound of several minerals and as a synthetic product. Notable examples include fused quartz, fumed silica, silica gel, opal and aerogels. It is used in structural materials, microelectronics (as an Insulator (electricity), electrical insulator), and as components in the food and pharmaceutical industries. Structure In the majority of silicates, the silicon atom shows tetrahedral coordination geometry, tetrahedral coordination, with four oxygen atoms surrounding a central Si atomsee 3-D Unit Cell. Thus, SiO2 forms 3-dimensional network solids in which each silicon atom is covalently bonded in a tetrahedral manner to 4 oxygen atoms. In contrast, CO2 is a linear ...
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D-DIA
The D-DIA or deformation-DIA is an apparatus used for high pressure and high temperature deformation experiments. The advantage of this apparatus is the ability to apply pressures up to approximately 15 GPa while independently creating uniaxial strains up to 50%. Theory The D-DIA utilizes the same principle that other high pressure apparatuses (such as the diamond anvil cell) use to create elevated pressure on a specimen. ''Pressure = Force/area'' By generating a force, in the case of the D-DIA through a hydraulic ram, a greater force can then be applied to the sample by decreasing the area of the anvils on the end that are in contact with the sample assembly. Design The D-DIA is based on the similar DIA, which is a cubic-anvil apparatus. The D-DIA is a type of multi-anvil deformation apparatus that uses 6 cubically arranged anvils to provide independent pressurization and deformation of the sample. Four anvils of the cubic arrangement are oriented in the horizontal oppos ...
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Synthetic Diamond
Lab-grown diamond (LGD; also called laboratory-grown, laboratory-created, man-made, artisan-created, artificial, synthetic, or cultured diamond) is diamond that is produced in a controlled technological process (in contrast to naturally formed diamond, which is created through geological processes and obtained by mining). Unlike diamond simulants (imitations of diamond made of superficially-similar non-diamond materials), synthetic diamonds are composed of the same material as naturally formed diamonds – pure carbon crystallized in an isotropic 3D form – and share identical chemical and physical properties. Numerous claims of diamond synthesis were reported between 1879 and 1928; most of these attempts were carefully analyzed but none was confirmed. In the 1940s, systematic research of diamond creation began in the United States, Sweden and the Soviet Union, which culminated in the first reproducible synthesis in 1953. Further research activity yielded the discoveries of HP ...
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Proceedings Of The National Academy Of Sciences
''Proceedings of the National Academy of Sciences of the United States of America'' (often abbreviated ''PNAS'' or ''PNAS USA'') is a peer-reviewed multidisciplinary scientific journal. It is the official journal of the National Academy of Sciences, published since 1915, and publishes original research, scientific reviews, commentaries, and letters. According to ''Journal Citation Reports'', the journal has a 2021 impact factor of 12.779. ''PNAS'' is the second most cited scientific journal, with more than 1.9 million cumulative citations from 2008 to 2018. In the mass media, ''PNAS'' has been described variously as "prestigious", "sedate", "renowned" and "high impact". ''PNAS'' is a delayed open access journal, with an embargo period of six months that can be bypassed for an author fee ( hybrid open access). Since September 2017, open access articles are published under a Creative Commons license. Since January 2019, ''PNAS'' has been online-only, although print issues are a ...
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Post-perovskite
Post-perovskite (pPv) is a high-pressure phase of magnesium silicate (MgSiO3). It is composed of the prime oxide constituents of the Earth's rocky mantle (MgO and SiO2), and its pressure and temperature for stability imply that it is likely to occur in portions of the lowermost few hundred km of Earth's mantle. The post-perovskite phase has implications for the ''D''′′ layer, which influences the convective mixing in the mantle responsible for plate tectonics. Post-perovskite has the same crystal structure as the synthetic solid compound CaIrO3, and is often referred to as the "CaIrO3-type phase of MgSiO3" in the literature. The crystal system of post-perovskite is orthorhombic, its space group is ''Cmcm'', and its structure is a stacked SiO6-octahedral sheet along the ''b'' axis. The name "post-perovskite" derives from silicate perovskite, the stable phase of MgSiO3 throughout most of Earth's mantle, which has the perovskite structure. The prefix "post-" refers to the fact t ...
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Silicate Perovskite
Silicate perovskite is either (the magnesium end-member is called bridgmanite) or (calcium silicate known as davemaoite) when arranged in a perovskite structure. Silicate perovskites are not stable at Earth's surface, and mainly exist in the lower part of Earth's mantle, between about depth. They are thought to form the main mineral phases, together with ferropericlase. Discovery The existence of silicate perovskite in the mantle was first suggested in 1962, and both and had been synthesized experimentally before 1975. By the late 1970s, it had been proposed that the seismic discontinuity at about 660 km in the mantle represented a change from spinel structure minerals with an olivine composition to silicate perovskite with ferropericlase. Natural silicate perovskite was discovered in the heavily shocked Tenham meteorite. In 2014, the Commission on New Minerals, Nomenclature and Classification (CNMNC) of the International Mineralogical Association (IMA) approved the na ...
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Angewandte Chemie International Edition
''Angewandte Chemie'' (, meaning "Applied Chemistry") is a weekly peer-reviewed scientific journal that is published by Wiley-VCH on behalf of the German Chemical Society (Gesellschaft Deutscher Chemiker). Publishing formats include feature-length reviews, short highlights, research communications, minireviews, essays, book reviews, meeting reviews, correspondences, corrections, and obituaries. This journal contains review articles covering all aspects of chemistry. According to the ''Journal Citation Reports'', the journal had a 2021 impact factor of 16.823. Editions The journal appears in two editions with separate volume and page numbering: a German edition, ''Angewandte Chemie'' ( (print), (online)), and a fully English-language edition, ''Angewandte Chemie International Edition'' ( (print), (online)). The editions are identical in content with the exception of occasional reviews of German-language books or German translations of IUPAC recommendations. Business model ''A ...
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Metallization Pressure
Metallization pressure is the pressure required for a non-metallic chemical element to become a metal. Every material is predicted to turn into a metal if the pressure is high enough, and temperature low enough. The value for arsenic refers to pressurizing metastable black arsenic; grey arsenic, the standard state, is already a metallic conductor at standard conditions. The metallization pressures for fluorine and radon have never been experimentally measured. For fluorine, 2020 calculations predict metallization at 25000 Mbar. See also *Metallic hydrogen Metallic hydrogen is a phase of hydrogen in which it behaves like an electrical conductor. This phase was predicted in 1935 on theoretical grounds by Eugene Wigner and Hillard Bell Huntington. At high pressure and temperatures, metallic hydroge ... References {{Reflist Physical chemistry Allotropes ...
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Sodium
Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable isotope is 23Na. The free metal does not occur in nature, and must be prepared from compounds. Sodium is the sixth most abundant element in the Earth's crust and exists in numerous minerals such as feldspars, sodalite, and halite (NaCl). Many salts of sodium are highly water-soluble: sodium ions have been leached by the action of water from the Earth's minerals over eons, and thus sodium and chlorine are the most common dissolved elements by weight in the oceans. Sodium was first isolated by Humphry Davy in 1807 by the electrolysis of sodium hydroxide. Among many other useful sodium compounds, sodium hydroxide (lye) is used in soap manufacture, and sodium chloride (edible salt) is a de-icing agent and a nutrient for animals including h ...
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Oxygen
Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as well as with other compounds. Oxygen is Earth's most abundant element, and after hydrogen and helium, it is the third-most abundant element in the universe. At standard temperature and pressure, two atoms of the element bind to form dioxygen, a colorless and odorless diatomic gas with the formula . Diatomic oxygen gas currently constitutes 20.95% of the Earth's atmosphere, though this has changed considerably over long periods of time. Oxygen makes up almost half of the Earth's crust in the form of oxides.Atkins, P.; Jones, L.; Laverman, L. (2016).''Chemical Principles'', 7th edition. Freeman. Many major classes of organic molecules in living organisms contain oxygen atoms, such as proteins, nucleic acids, carbohydrates, and fats, as ...
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Stishovite
Stishovite is an extremely hard, dense tetragonal form (Polymorphism (materials science), polymorph) of silicon dioxide. It is very rare on the Earth's surface; however, it may be a predominant form of silicon dioxide in the Earth, especially in the Lower mantle (Earth), lower mantle. Stishovite was named after Sergey M. Stishov, a Russian high-pressure physicist who first synthesized the mineral in 1961. It was discovered in Meteor Crater in 1962 by Edward C. T. Chao. Unlike other silica polymorphs, the crystal structure of stishovite resembles that of rutile (TiO2). The silicon in stishovite adopts an octahedral coordination geometry, being bound to six oxides. Similarly, the oxides are three-connected, unlike low-pressure forms of SiO2. In most silicates, silicon is tetrahedral, being bound to four oxides. It was long considered the hardest known oxide (~30 GPa Vickers); however, boron suboxide has been discovered in 2002 to be much harder. At normal temperature and pressur ...
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