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Cubical Atom
The cubical atom was an early atomic model in which electrons were positioned at the eight corners of a cube in a non-polar atom or molecule. This theory was developed in 1902 by Gilbert N. Lewis and published in 1916 in the article "The Atom and the Molecule" and used to account for the phenomenon of Valency (chemistry), valency. Lewis' theory was based on Abegg's rule. It was further developed in 1919 by Irving Langmuir as the cubical octet atom. The figure below shows structural representations for elements of the second row of the periodic table. Although the cubical model of the atom was soon abandoned in favor of the quantum mechanical model based on the Schrödinger equation, and is therefore now principally of historical interest, it represented an important step towards the understanding of the chemical bond. The 1916 article by Lewis also introduced the concept of the electron pair in the covalent bond, the octet rule, and the now-called Lewis structure. Bonding in t ...
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Atom
Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. Every solid, liquid, gas, and plasma is composed of neutral or ionized atoms. Atoms are extremely small, typically around 100 picometers across. They are so small that accurately predicting their behavior using classical physics, as if they were tennis balls for example, is not possible due to quantum effects. More than 99.94% of an atom's mass is in the nucleus. The protons have a positive electric charge, the electrons have a negative electric charge, and the neutrons have no electric charge. If the number of protons and electrons are equal, then the atom is electrically neutral. If an atom has more or fewer electrons than protons, then it has an overall negative or positive charge, respectively – such atoms are called ions. The electrons of an atom are a ...
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Covalent Bond
A covalent bond is a chemical bond that involves the sharing of electrons to form electron pairs between atoms. These electron pairs are known as shared pairs or bonding pairs. The stable balance of attractive and repulsive forces between atoms, when they share electrons, is known as covalent bonding. For many molecules, the sharing of electrons allows each atom to attain the equivalent of a full valence shell, corresponding to a stable electronic configuration. In organic chemistry, covalent bonding is much more common than ionic bonding. Covalent bonding also includes many kinds of interactions, including σ-bonding, π-bonding, metal-to-metal bonding, agostic interactions, bent bonds, three-center two-electron bonds and three-center four-electron bonds. The term ''covalent bond'' dates from 1939. The prefix ''co-'' means ''jointly, associated in action, partnered to a lesser degree, '' etc.; thus a "co-valent bond", in essence, means that the atoms share " valence", such a ...
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Obsolete Theories In Physics
Obsolescence is the state of being which occurs when an object, service, or practice is no longer maintained or required even though it may still be in good working order. It usually happens when something that is more efficient or less risky replaces it. The international standard IEC 62402:2019 Obsolescence Management defines obsolescence as the "transition from available to unavailable from the manufacturer in accordance with the original specification". Obsolete also refers to something that is already disused or discarded, or antiquated. Typically, obsolescence is preceded by a gradual decline in popularity. Consequences Driven by rapid technological changes, new components are developed and launched on the market with increasing speed. The result is a dramatic change in production methods of all components and their market availability. A growing industry sector is facing issues where life cycles of products no longer fit together with life cycles of required components ...
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History Of The Molecule
In chemistry, the history of molecular theory traces the origins of the concept or idea of the existence of strong chemical bonds between two or more atoms. The modern concept of molecules can be traced back towards pre-scientific and Greek philosophers such as Leucippus and Democritus who argued that all the universe is composed of atoms and voids. Circa 450 BC Empedocles imagined fundamental elements (fire (), earth (), air (), and water () and "forces" of attraction and repulsion allowing the elements to interact. Prior to this, Heraclitus had claimed that fire or change was fundamental to our existence, created through the combination of opposite properties. In the Timaeus, Plato, following Pythagoras, considered mathematical entities such as number, point, line and triangle as the fundamental building blocks or elements of this ephemeral world, and considered the four elements of fire, air, water and earth as states of substances through which the true mathematical princip ...
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Cubical Atom 4
Cubic may refer to: Science and mathematics * Cube (algebra), "cubic" measurement * Cube, a three-dimensional solid object bounded by six square faces, facets or sides, with three meeting at each vertex ** Cubic crystal system, a crystal system where the unit cell is in the shape of a cube * Cubic function, a polynomial function of degree three * Cubic equation, a polynomial equation (reducible to ''ax''3 + ''bx''2 + ''cx'' + ''d'' = 0) * Cubic form, a homogeneous polynomial of degree 3 * Cubic graph (mathematics - graph theory), a graph where all vertices have degree 3 * Cubic plane curve (mathematics), a plane algebraic curve ''C'' defined by a cubic equation * Cubic reciprocity (mathematics - number theory), a theorem analogous to quadratic reciprocity * Cubic surface, an algebraic surface in three-dimensional space * Cubic zirconia, in geology, a mineral that is widely synthesized for use as a diamond simulacra * CUBIC, a histology method Computing * Cubic IDE, a modular de ...
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Cubical Atom 3
Cubic may refer to: Science and mathematics * Cube (algebra), "cubic" measurement * Cube, a three-dimensional solid object bounded by six square faces, facets or sides, with three meeting at each vertex ** Cubic crystal system, a crystal system where the unit cell is in the shape of a cube * Cubic function, a polynomial function of degree three * Cubic equation, a polynomial equation (reducible to ''ax''3 + ''bx''2 + ''cx'' + ''d'' = 0) * Cubic form, a homogeneous polynomial of degree 3 * Cubic graph (mathematics - graph theory), a graph where all vertices have degree 3 * Cubic plane curve (mathematics), a plane algebraic curve ''C'' defined by a cubic equation * Cubic reciprocity (mathematics - number theory), a theorem analogous to quadratic reciprocity * Cubic surface, an algebraic surface in three-dimensional space * Cubic zirconia, in geology, a mineral that is widely synthesized for use as a diamond simulacra * CUBIC, a histology method Computing * Cubic IDE, a modular de ...
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Cubical Atom 2
Cubic may refer to: Science and mathematics * Cube (algebra), "cubic" measurement * Cube, a three-dimensional solid object bounded by six square faces, facets or sides, with three meeting at each vertex ** Cubic crystal system, a crystal system where the unit cell is in the shape of a cube * Cubic function, a polynomial function of degree three * Cubic equation, a polynomial equation (reducible to ''ax''3 + ''bx''2 + ''cx'' + ''d'' = 0) * Cubic form, a homogeneous polynomial of degree 3 * Cubic graph (mathematics - graph theory), a graph where all vertices have degree 3 * Cubic plane curve (mathematics), a plane algebraic curve ''C'' defined by a cubic equation * Cubic reciprocity (mathematics - number theory), a theorem analogous to quadratic reciprocity * Cubic surface, an algebraic surface in three-dimensional space * Cubic zirconia, in geology, a mineral that is widely synthesized for use as a diamond simulacra * CUBIC, a histology method Computing * Cubic IDE, a modular de ...
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Lewis Structure
Lewis structures, also known as Lewis dot formulas, Lewis dot structures, electron dot structures, or Lewis electron dot structures (LEDS), are diagrams that show the chemical bonding, bonding between atoms of a molecule, as well as the lone pairs of electrons that may exist in the molecule. A Lewis structure can be drawn for any covalently bonded molecule, as well as complex (chemistry), coordination compounds. The Lewis structure was named after Gilbert N. Lewis, who introduced it in his 1916 article ''The Atom and the Molecule.'' Lewis structures extend the concept of the electron dot diagram by adding lines between atoms to represent shared pairs in a chemical bond. Lewis structures show each atom and its position in the structure of the molecule using its chemical symbol. Lines are drawn between atoms that are bonded to one another (pairs of dots can be used instead of lines). Excess electrons that form lone pairs are represented as pairs of dots, and are placed next to the at ...
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Octet Rule
The octet rule is a chemical rule of thumb that reflects the theory that main-group elements tend to bond in such a way that each atom has eight electrons in its valence shell, giving it the same electronic configuration as a noble gas. The rule is especially applicable to carbon, nitrogen, oxygen, and the halogens; although more generally the rule is applicable for the s-block and p-block of the periodic table. Other rules exist for other elements, such as the duplet rule for hydrogen and helium, or the 18-electron rule for transition metals. The valence electrons can be counted using a Lewis electron dot diagram as shown at the right for carbon dioxide. The electrons shared by the two atoms in a covalent bond are counted twice, once for each atom. In carbon dioxide each oxygen shares four electrons with the central carbon, two (shown in red) from the oxygen itself and two (shown in black) from the carbon. All four of these electrons are counted in both the carbon octet and the ...
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Electron Pair
In chemistry, an electron pair or Lewis pair consists of two electrons that occupy the same molecular orbital but have opposite spins. Gilbert N. Lewis introduced the concepts of both the electron pair and the covalent bond in a landmark paper he published in 1916. Because electrons are fermions, the Pauli exclusion principle forbids these particles from having the same quantum numbers. Therefore, for two electrons to occupy the same orbital, and thereby have the same orbital quantum number, they must have different spin quantum number. This also limits the number of electrons in the same orbital to two. The pairing of spins is often energetically favorable, and electron pairs therefore play a large role in chemistry. They can form a chemical bond between two atoms, or they can occur as a lone pair of valence electrons. They also fill the core levels of an atom. Because the spins are paired, the magnetic moment of the electrons cancel one another, and the pair's contri ...
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Electron
The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no known components or substructure. The electron's mass is approximately 1/1836 that of the proton. Quantum mechanical properties of the electron include an intrinsic angular momentum ( spin) of a half-integer value, expressed in units of the reduced Planck constant, . Being fermions, no two electrons can occupy the same quantum state, in accordance with the Pauli exclusion principle. Like all elementary particles, electrons exhibit properties of both particles and waves: They can collide with other particles and can be diffracted like light. The wave properties of electrons are easier to observe with experiments than those of other particles like neutrons and protons because electrons have a lower mass and hence a longer de Broglie wavele ...
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Schrödinger Equation
The Schrödinger equation is a linear partial differential equation that governs the wave function of a quantum-mechanical system. It is a key result in quantum mechanics, and its discovery was a significant landmark in the development of the subject. The equation is named after Erwin Schrödinger, who postulated the equation in 1925, and published it in 1926, forming the basis for the work that resulted in his Nobel Prize in Physics in 1933. Conceptually, the Schrödinger equation is the quantum counterpart of Newton's second law in classical mechanics. Given a set of known initial conditions, Newton's second law makes a mathematical prediction as to what path a given physical system will take over time. The Schrödinger equation gives the evolution over time of a wave function, the quantum-mechanical characterization of an isolated physical system. The equation can be derived from the fact that the time-evolution operator must be unitary, and must therefore be generated by t ...
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