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Coring
Coring happens when a heated alloy, such as a Cu-Ni system, cools in non-equilibrium conditions. The center of each grain, which is the first part to freeze, is rich in the high-melting element (e.g., nickel for this Cu–Ni system), whereas the concentration of the low-melting element increases with position from this region to the grain boundary. This is termed a 'cored structure', which gives rise to less than the optimal properties. The distribution of the two elements within the grains is nonuniform, a phenomenon termed 'segregation'; that is, concentration gradients are established across the grains. As a casting having a cored structure is reheated, grain boundary regions will melt first in as much as they are richer in the low-melting component. This produces a sudden loss in mechanical integrity due to the thin liquid film that separates the grains. Furthermore, this melting may begin at a temperature below the equilibrium solidus temperature of the alloy. Coring may be e ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Copper-Nickel
Cupronickel or copper-nickel (CuNi) is an alloy of copper that contains nickel and strengthening elements, such as iron and manganese. The copper content typically varies from 60 to 90 percent. (Monel is a nickel-copper alloy that contains a minimum of 52 percent nickel.) Despite its high copper content, cupronickel is silver in colour. Cupronickel is highly resistant to corrosion by salt water, and is therefore used for piping, heat exchangers and condensers in seawater systems, as well as for marine hardware. It is sometimes used for the propellers, propeller shafts, and hulls of high-quality boats. Other uses include military equipment and chemical, petrochemical, and electrical industries. Another common 20th-century use of cupronickel was silver-coloured coins. For this use, the typical alloy has 3:1 copper to nickel ratio, with very small amounts of manganese. In the past, true silver coins were debased with cupronickel, such as coins of the pound sterling from 1947 onward ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Liquidus
The liquidus temperature, TL or Tliq, specifies the temperature above which a material is completely liquid, and the maximum temperature at which crystals can co-exist with the melt in thermodynamic equilibrium. It is mostly used for impure substances (mixtures) such as glasses, alloys and rocks. Above the liquidus temperature the material is homogeneous and liquid at equilibrium. Below the liquidus temperature, more and more crystals will form in the melt if one waits a sufficiently long time, depending on the material. Alternately, homogeneous glasses can be obtained through sufficiently fast cooling, i.e., through kinetic inhibition of the crystallization process. The crystal phase that crystallizes first on cooling a substance to its liquidus temperature is termed primary crystalline phase or primary phase. The composition range within which the primary phase remains constant is known as primary crystalline phase field. The liquidus temperature is important in the glass ind ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Solidus (chemistry)
In chemistry, materials science, and physics, the solidus is the locus of temperatures (a curve on a phase diagram) below which a given substance is completely solid (crystallized). The solidus temperature, TS or Tsol, specifies the temperature below which a material is completely solid, and the minimum temperature at which a melt can co-exist with crystals in thermodynamic equilibrium. The solidus is applied, among other materials, to metal alloys, ceramics, and natural rocks and minerals. The solidus quantifies the temperature at which melting of a substance ''begins'', but the substance is not necessarily melted ''completely'', i.e., the solidus is not necessarily a melting point. For this distinction, the solidus may be contrasted to the liquidus. The solidus is always less than or equal to the liquidus, but they need not coincide. If a gap exists between the solidus and liquidus it is called the freezing range, and within that gap, the substance consists of a mixture of so ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Annealing (metallurgy)
In metallurgy and materials science, annealing is a heat treatment that alters the physical and sometimes chemical properties of a material to increase its ductility and reduce its hardness, making it more workable. It involves heating a material above its recrystallization temperature, maintaining a suitable temperature for an appropriate amount of time and then cooling. In annealing, atoms migrate in the crystal lattice and the number of dislocations decreases, leading to a change in ductility and hardness. As the material cools it recrystallizes. For many alloys, including carbon steel, the crystal grain size and phase composition, which ultimately determine the material properties, are dependent on the heating rate and cooling rate. Hot working or cold working after the annealing process alters the metal structure, so further heat treatments may be used to achieve the properties required. With knowledge of the composition and phase diagram, heat treatment can be used to ad ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hot-working
In metallurgy, hot working refers to processes where metals are plastically deformed above their recrystallization temperature. Being above the recrystallization temperature allows the material to recrystallize during deformation. This is important because recrystallization keeps the materials from strain hardening, which ultimately keeps the yield strength and hardness low and ductility high.Degarmo, p. 373. This contrasts with cold working. Many kinds of working, including rolling, forging, extrusion, and drawing, can be done with hot metal. Temperature The lower limit of the hot working temperature is determined by its recrystallization temperature. As a guideline, the lower limit of the hot working temperature of a material is 60% its melting temperature (on an absolute temperature scale). The upper limit for hot working is determined by various factors, such as: excessive oxidation, grain growth, or an undesirable phase transformation. In practice materials are usuall ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Zone Refining
Zone melting (or zone refining, or floating-zone method, or floating-zone technique) is a group of similar methods of purifying crystals, in which a narrow region of a crystal is melted, and this molten zone is moved along the crystal. The molten region melts impure solid at its forward edge and leaves a wake of purer material solidified behind it as it moves through the ingot. The impurities concentrate in the melt, and are moved to one end of the ingot. Zone refining was invented by John Desmond Bernal and further developed by William G. Pfann William G. Pfann (1966) ''Zone Melting'', 2nd edition, John Wiley & Sons in Bell Labs as a method to prepare high purity materials, mainly semiconductors, for manufacturing transistors. Its first commercial use was in germanium, refined to one atom of impurity per ten billion,”Zone melting”, entry in ''The World Book Encyclopedia'', Volume 21, W-X-Y-Z, 1973, page 501. but the process can be extended to virtually any solute–solvent ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
