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Conservative Temperature
Conservative temperature (\Theta) is a thermodynamic property of seawater. It is derived from the potential enthalpy and is recommended under the TEOS-10 standard (Thermodynamic Equation of Seawater - 2010) as a replacement for potential temperature as it more accurately represents the heat content in the ocean. Motivation Conservative temperature was initially proposed by Trevor McDougall in 2003. The motivation was to find an oceanic variable representing the heat content that is conserved during both pressure changes and turbulent mixing. In-situ temperature T is not sufficient for this purpose, as the compression of a water parcel with depth causes an increase of the temperature despite the absence of any external heating. Potential temperature \theta can be used to combat this issue, as it is referenced to a specific pressure and so ignores these compressive effects. In fact, potential temperature is a conservative variable in the atmosphere for air parcels in dry adiabat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Seawater
Seawater, or salt water, is water from a sea or ocean. On average, seawater in the world's oceans has a salinity of about 3.5% (35 g/L, 35 ppt, 600 mM). This means that every kilogram (roughly one liter by volume) of seawater has approximately of dissolved salts (predominantly sodium () and chloride () ions). The average density at the surface is 1.025 kg/L. Seawater is denser than both fresh water and pure water (density 1.0 kg/L at ) because the dissolved salts increase the mass by a larger proportion than the volume. The freezing point of seawater decreases as salt concentration increases. At typical salinity, it freezes at about . The coldest seawater still in the liquid state ever recorded was found in 2010, in a stream under an Antarctic glacier: the measured temperature was . Seawater pH is typically limited to a range between 7.5 and 8.4. However, there is no universally accepted reference pH-scale for seawater and the difference between measurement ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Potential
In thermodynamics, the chemical potential of a species is the energy that can be absorbed or released due to a change of the particle number of the given species, e.g. in a chemical reaction or phase transition. The chemical potential of a species in a mixture is defined as the rate of change of free energy of a thermodynamic system with respect to the change in the number of atoms or molecules of the species that are added to the system. Thus, it is the partial derivative of the free energy with respect to the amount of the species, all other species' concentrations in the mixture remaining constant. When both temperature and pressure are held constant, and the number of particles is expressed in moles, the chemical potential is the partial molar Gibbs free energy. At chemical equilibrium or in phase equilibrium, the total sum of the product of chemical potentials and stoichiometric coefficients is zero, as the free energy is at a minimum. In a system in diffusion equilibrium, th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ocean General Circulation Model
Ocean general circulation models (OGCMs) are a particular kind of general circulation model to describe physical and thermodynamical processes in oceans. The oceanic general circulation is defined as the horizontal space scale and time scale larger than mesoscale (of order 100 km and 6 months). They depict oceans using a three-dimensional grid that include active thermodynamics and hence are most directly applicable to climate studies. They are the most advanced tools currently available for simulating the response of the global ocean system to increasing greenhouse gas concentrations. A hierarchy of OGCMs have been developed that include varying degrees of spatial coverage, resolution, geographical realism, process detail, etc. History The first generation of OGCMs assumed “rigid lid” to eliminate high-speed external gravity waves. According to CFL criteria without those fast waves, we can use a bigger time step, which is not so computationally expensive. But it also fil ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gibbs Function
In thermodynamics, the Gibbs free energy (or Gibbs energy; symbol G) is a thermodynamic potential that can be used to calculate the maximum amount of work that may be performed by a thermodynamically closed system at constant temperature and pressure. It also provides a necessary condition for processes such as chemical reactions that may occur under these conditions. The Gibbs free energy change , measured in joules in SI) is the ''maximum'' amount of non-expansion work that can be extracted from a closed system (one that can exchange heat and work with its surroundings, but not matter) at fixed temperature and pressure. This maximum can be attained only in a completely reversible process. When a system transforms reversibly from an initial state to a final state under these conditions, the decrease in Gibbs free energy equals the work done by the system to its surroundings, minus the work of the pressure forces. The Gibbs energy is the thermodynamic potential that is minim ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Biogeochemistry
Biogeochemistry is the scientific discipline that involves the study of the chemical, physical, geological, and biological processes and reactions that govern the composition of the natural environment (including the biosphere, the cryosphere, the hydrosphere, the pedosphere, the atmosphere, and the lithosphere). In particular, biogeochemistry is the study of biogeochemical cycles, the cycles of chemical elements such as carbon and nitrogen, and their interactions with and incorporation into living things transported through earth scale biological systems in space and time. The field focuses on chemical cycles which are either driven by or influence biological activity. Particular emphasis is placed on the study of carbon, nitrogen, sulfur, iron, and phosphorus cycles. Biogeochemistry is a systems science closely related to systems ecology. History Early History Early Greeks established some of the core ideas of biogeochemistry, such as nature consisting of cycles. 17th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Work Done
In physics, work is the energy transferred to or from an object via the application of force along a displacement. In its simplest form, for a constant force aligned with the direction of motion, the work equals the product of the force strength and the distance traveled. A force is said to do ''positive work'' if when applied it has a component in the direction of the displacement of the point of application. A force does ''negative work'' if it has a component opposite to the direction of the displacement at the point of application of the force. For example, when a ball is held above the ground and then dropped, the work done by the gravitational force on the ball as it falls is positive, and is equal to the weight of the ball (a force) multiplied by the distance to the ground (a displacement). If the ball is thrown upwards, the work done by its weight is negative, and is equal to the weight multiplied by the displacement in the upwards direction. When the force is const ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Conservation Form
Conservation form or ''Eulerian form'' refers to an arrangement of an equation or system of equations, usually representing a hyperbolic system, that emphasizes that a property represented is conserved, i.e. a type of continuity equation. The term is usually used in the context of continuum mechanics. General form Equations in conservation form take the form \frac + \boldsymbol \nabla \cdot \mathbf f(\xi) = 0 for any conserved quantity \xi, with a suitable function \mathbf f. An equation of this form can be transformed into an integral equation \frac d \int_V \xi ~ dV = -\oint_ \mathbf f(\xi) \cdot \boldsymbol \nu ~ dS using the divergence theorem. The integral equation states that the change rate of the integral of the quantity \xi over an arbitrary control volume V is given by the flux \mathbf f(\xi) through the boundary of the control volume, with \boldsymbol \nu being the outer surface normal through the boundary. \xi is neither produced nor consumed inside of V and is hence co ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Material Derivative
In continuum mechanics, the material derivative describes the time rate of change of some physical quantity (like heat or momentum) of a material element that is subjected to a space-and-time-dependent macroscopic velocity field. The material derivative can serve as a link between Eulerian and Lagrangian descriptions of continuum deformation. For example, in fluid dynamics, the velocity field is the flow velocity, and the quantity of interest might be the temperature of the fluid. In which case, the material derivative then describes the temperature change of a certain fluid parcel with time, as it flows along its pathline (trajectory). Other names There are many other names for the material derivative, including: *advective derivative *convective derivative *derivative following the motion *hydrodynamic derivative *Lagrangian derivative *particle derivative *substantial derivative *substantive derivative *Stokes derivative *total derivative, although the material derivative ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Internal Energy
The internal energy of a thermodynamic system is the total energy contained within it. It is the energy necessary to create or prepare the system in its given internal state, and includes the contributions of potential energy and internal kinetic energy. It keeps account of the gains and losses of energy of the system that are due to changes in its internal state. It does not include the kinetic energy of motion of the system as a whole, or any external energies from surrounding force fields. The internal energy of an isolated system is constant, which is expressed as the law of conservation of energy, a foundation of the first law of thermodynamics. The internal energy is an extensive property. The internal energy cannot be measured directly and knowledge of all its components is rarely interesting, such as the static rest mass energy of its constituent matter. Thermodynamics is chiefly concerned only with ''changes'' in the internal energy, not with its absolute value. Instea ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
First Law Of Thermodynamics
The first law of thermodynamics is a formulation of the law of conservation of energy, adapted for thermodynamic processes. It distinguishes in principle two forms of energy transfer, heat and thermodynamic work for a system of a constant amount of matter. The law also defines the internal energy of a system, an extensive property for taking account of the balance of energies in the system. The law of conservation of energy states that the total energy of any isolated system, which cannot exchange energy or matter, is constant. Energy can be transformed from one form to another, but can be neither created nor destroyed. The first law for a thermodynamic process is often formulated asThe sign convention (Q is heat supplied ''to'' the system but W is work done ''by'' the system) is that of Rudolf Clausius (Equation IIa on page 384 of Clausius, R. (1850)), and it is followed below. :\Delta U = Q - W, where \Delta U denotes the change in the internal energy of a closed system (f ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Specific Heat Capacity
In thermodynamics, the specific heat capacity (symbol ) of a substance is the heat capacity of a sample of the substance divided by the mass of the sample, also sometimes referred to as massic heat capacity. Informally, it is the amount of heat that must be added to one unit of mass of the substance in order to cause an increase of one unit in temperature. The SI unit of specific heat capacity is joule per kelvin per kilogram, J⋅kg−1⋅K−1. For example, the heat required to raise the temperature of of water by is , so the specific heat capacity of water is . Specific heat capacity often varies with temperature, and is different for each state of matter. Liquid water has one of the highest specific heat capacities among common substances, about at 20 °C; but that of ice, just below 0 °C, is only . The specific heat capacities of iron, granite, and hydrogen gas are about 449 J⋅kg−1⋅K−1, 790 J⋅kg−1⋅K−1, and 14300 J⋅kg−1⋅K−1 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Kelvin
The kelvin, symbol K, is the primary unit of temperature in the International System of Units (SI), used alongside its prefixed forms and the degree Celsius. It is named after the Belfast-born and University of Glasgow-based engineer and physicist William Thomson, 1st Baron Kelvin (1824–1907). The Kelvin scale is an absolute thermodynamic temperature scale, meaning it uses absolute zero as its null (zero) point. Historically, the Kelvin scale was developed by shifting the starting point of the much-older Celsius scale down from the melting point of water to absolute zero, and its increments still closely approximate the historic definition of a degree Celsius, but since 2019 the scale has been defined by fixing the Boltzmann constant to be exactly . Hence, one kelvin is equal to a change in the thermodynamic temperature that results in a change of thermal energy by . The temperature in degree Celsius is now defined as the temperature in kelvins minus 273.15, meaning t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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