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Compressibility Equation
In statistical mechanics and thermodynamics the compressibility equation refers to an equation which relates the isothermal compressibility (and indirectly the pressure) to the structure of the liquid. It reads:kT\left(\frac\right)=1+\rho \int_V \mathrm \mathbf (r)-1where \rho is the number density, g(r) is the radial distribution function and kT\left(\frac\right) is the isothermal compressibility. Using the Fourier representation of the Ornstein-Zernike equation the compressibility equation can be rewritten in the form: \frac\left(\frac\right) = \frac=\frac=1-\rho\hat(0)=1-\rho \int c(r) \mathrm \mathbf where h(r) and c(r) are the indirect and direct correlation functions respectively. The compressibility equation is one of the many integral equations in statistical mechanics In physics, statistical mechanics is a mathematical framework that applies statistical methods and probability theory to large assemblies of microscopic entities. It does not assume or postulate an ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Statistical Mechanics
In physics, statistical mechanics is a mathematical framework that applies statistical methods and probability theory to large assemblies of microscopic entities. It does not assume or postulate any natural laws, but explains the macroscopic behavior of nature from the behavior of such ensembles. Statistical mechanics arose out of the development of classical thermodynamics, a field for which it was successful in explaining macroscopic physical properties—such as temperature, pressure, and heat capacity—in terms of microscopic parameters that fluctuate about average values and are characterized by probability distributions. This established the fields of statistical thermodynamics and statistical physics. The founding of the field of statistical mechanics is generally credited to three physicists: *Ludwig Boltzmann, who developed the fundamental interpretation of entropy in terms of a collection of microstates *James Clerk Maxwell, who developed models of probability distr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamics
Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics which convey a quantitative description using measurable macroscopic physical quantities, but may be explained in terms of microscopic constituents by statistical mechanics. Thermodynamics applies to a wide variety of topics in science and engineering, especially physical chemistry, biochemistry, chemical engineering and mechanical engineering, but also in other complex fields such as meteorology. Historically, thermodynamics developed out of a desire to increase the efficiency of early steam engines, particularly through the work of French physicist Sadi Carnot (1824) who believed that engine efficiency was the key that could help France win the Napoleonic Wars. Scots-Irish physicist Lord Kelvin was the first to formulate a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Compressibility
In thermodynamics and fluid mechanics, the compressibility (also known as the coefficient of compressibility or, if the temperature is held constant, the isothermal compressibility) is a measure of the instantaneous relative volume change of a fluid or solid as a response to a pressure (or mean stress) change. In its simple form, the compressibility \kappa (denoted in some fields) may be expressed as :\beta =-\frac\frac, where is volume and is pressure. The choice to define compressibility as the negative of the fraction makes compressibility positive in the (usual) case that an increase in pressure induces a reduction in volume. The reciprocal of compressibility at fixed temperature is called the isothermal bulk modulus. Definition The specification above is incomplete, because for any object or system the magnitude of the compressibility depends strongly on whether the process is isentropic or isothermal. Accordingly, isothermal compressibility is defined: :\beta_T=-\frac ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Radial Distribution Function
In statistical mechanics, the radial distribution function, (or pair correlation function) g(r) in a system of particles (atoms, molecules, colloids, etc.), describes how density varies as a function of distance from a reference particle. If a given particle is taken to be at the origin O, and if \rho =N/V is the average number density of particles, then the local time-averaged density at a distance r from O is \rho g(r). This simplified definition holds for a homogeneous and isotropic system. A more general case will be considered below. In simplest terms it is a measure of the probability of finding a particle at a distance of r away from a given reference particle, relative to that for an ideal gas. The general algorithm involves determining how many particles are within a distance of r and r+dr away from a particle. This general theme is depicted to the right, where the red particle is our reference particle, and blue particles are those whose centers are within the circul ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Integral Equations
In mathematics, integral equations are equations in which an unknown function appears under an integral sign. In mathematical notation, integral equations may thus be expressed as being of the form: f(x_1,x_2,x_3,...,x_n ; u(x_1,x_2,x_3,...,x_n) ; I^1 (u), I^2(u), I^3(u), ..., I^m(u)) = 0where I^i(u) is an integral operator acting on ''u.'' Hence, integral equations may be viewed as the analog to differential equations where instead of the equation involving derivatives, the equation contains integrals. A direct comparison can be seen with the mathematical form of the general integral equation above with the general form of a differential equation which may be expressed as follows:f(x_1,x_2,x_3,...,x_n ; u(x_1,x_2,x_3,...,x_n) ; D^1 (u), D^2(u), D^3(u), ..., D^m(u)) = 0where D^i(u) may be viewed as a differential operator of order ''i''. Due to this close connection between differential and integral equations, one can often convert between the two. For example, one method of solvi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Statistical Mechanics
In physics, statistical mechanics is a mathematical framework that applies statistical methods and probability theory to large assemblies of microscopic entities. It does not assume or postulate any natural laws, but explains the macroscopic behavior of nature from the behavior of such ensembles. Statistical mechanics arose out of the development of classical thermodynamics, a field for which it was successful in explaining macroscopic physical properties—such as temperature, pressure, and heat capacity—in terms of microscopic parameters that fluctuate about average values and are characterized by probability distributions. This established the fields of statistical thermodynamics and statistical physics. The founding of the field of statistical mechanics is generally credited to three physicists: *Ludwig Boltzmann, who developed the fundamental interpretation of entropy in terms of a collection of microstates *James Clerk Maxwell, who developed models of probability distr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
