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Component (thermodynamics)
In thermodynamics, a component is one of a collection of chemically independent constituents of a system. The number of components represents the minimum number of independent chemical species necessary to define the composition of all phases of the system. Calculating the number of components in a system is necessary when applying Gibbs' phase rule in determination of the number of degrees of freedom of a system. The number of components is equal to the number of distinct chemical species (constituents), minus the number of chemical reactions between them, minus the number of any constraints (like charge neutrality or balance of molar quantities). Calculation Suppose that a chemical system has elements and chemical species (elements or compounds). The latter are combinations of the former, and each species can be represented as a sum of elements: : A_i = \sum_j a_E_j, where are the integers denoting number of atoms of element in molecule . Each species is determined by a v ...
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Thermodynamics
Thermodynamics is a branch of physics that deals with heat, Work (thermodynamics), work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics, which convey a quantitative description using measurable macroscopic physical quantity, physical quantities but may be explained in terms of microscopic constituents by statistical mechanics. Thermodynamics applies to various topics in science and engineering, especially physical chemistry, biochemistry, chemical engineering, and mechanical engineering, as well as other complex fields such as meteorology. Historically, thermodynamics developed out of a desire to increase the thermodynamic efficiency, efficiency of early steam engines, particularly through the work of French physicist Nicolas Léonard Sadi Carnot, Sadi Carnot (1824) who believed that engine efficiency was the key that could help France win ...
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Central Michigan University
Central Michigan University (CMU) is a Public university, public research university in Mount Pleasant, Michigan, United States. It was established in 1892 as a private normal school and became a state institution in 1895. CMU is one of the eight research universities in Michigan and is Carnegie Classification of Institutions of Higher Education, classified among "R2: Doctoral Universities – High research activity". It has more than 15,000 students on its Mount Pleasant campus. CMU offers 200 academic programs at the undergraduate, master's, specialist, and doctoral levels. The Central Michigan Chippewas compete in the NCAA Division I Mid-American Conference in six men's and ten women's sports. History CMU opened in 1892 as the Central Michigan Normal School and Business Institute. Prof. Charles F. R. Bellows, a University of Michigan graduate, became the founding principal of the school in June 1892. For the first year, 31 students attended classes in the Carpenter Buildi ...
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Thermodynamic System
A thermodynamic system is a body of matter and/or radiation separate from its surroundings that can be studied using the laws of thermodynamics. Thermodynamic systems can be passive and active according to internal processes. According to internal processes, passive systems and active systems are distinguished: passive, in which there is a redistribution of available energy, active, in which one type of energy is converted into another. Depending on its interaction with the environment, a thermodynamic system may be an isolated system, a Closed system#In thermodynamics, closed system, or an Open system (systems theory), open system. An isolated system does not exchange matter or energy with its surroundings. A closed system may exchange heat, experience forces, and exert forces, but does not exchange matter. An open system can interact with its surroundings by exchanging both matter and energy. The physical condition of a thermodynamic system at a given time is described by its ...
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Chemical Species
Chemical species are a specific form of chemical substance or chemically identical molecular entities that have the same molecular energy level at a specified timescale. These entities are classified through bonding types and relative abundance of isotopes. Types of chemical species can be classified based on the type of molecular entity and can be either an atomic, molecular, ionic or radical species. Classification Generally, a chemical species is defined as a chemical identity that has the same set of molecular energy levels in a defined timescale (i.e. an experiment). These energy levels determine the way the chemical species will interact with others through properties such as bonding or isotopic compositions. The chemical species can be an atom, molecule, ion, or radical, with a specific chemical name and chemical formula. In supramolecular chemistry, chemical species are structures created by forming or breaking bonds between molecules, such as hydrogen bonding, dipole ...
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Chemical Composition
A chemical composition specifies the identity, arrangement, and ratio of the chemical elements making up a compound by way of chemical and atomic bonds. Chemical formulas can be used to describe the relative amounts of elements present in a compound. For example, the chemical formula for water is H2O: this means that each molecule of water is constituted by 2 atoms of hydrogen (H) and 1 atom of oxygen (O). The chemical composition of water may be interpreted as a 2:1 ratio of hydrogen atoms to oxygen atoms. Different types of chemical formulas are used to convey composition information, such as an empirical or molecular formula. Nomenclature can be used to express not only the elements present in a compound but their arrangement within the molecules of the compound. In this way, compounds will have unique names which can describe their elemental composition. Composite mixture The chemical composition of a mixture can be defined as the distribution of the individual substance ...
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Phase (matter)
In the physical sciences, a phase is a region of material that is chemically uniform, physically distinct, and (often) mechanically separable. In a system consisting of ice and water in a glass jar, the ice cubes are one phase, the water is a second phase, and the humid air is a third phase over the ice and water. The glass of the jar is a different material, in its own separate phase. (See .) More precisely, a phase is a region of space (a thermodynamic system), throughout which all physical properties of a material are essentially uniform. Examples of physical properties include density, index of refraction, magnetization and chemical composition. The term ''phase'' is sometimes used as a synonym for state of matter, but there can be several immiscible phases of the same state of matter (as where oil and water separate into distinct phases, both in the liquid state). Types of phases Distinct phases may be described as different states of matter such as gas, liquid ...
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Degrees Of Freedom (physics And Chemistry)
In physics and chemistry, a degree of freedom is an independent physical parameter in the chosen parameterization of a physical system. More formally, given a parameterization of a physical system, the number of degrees of freedom is the smallest number n of parameters whose values need to be known in order to always be possible to determine the values of ''all'' parameters in the chosen parameterization. In this case, any set of n such parameters are called degrees of freedom. The location of a particle in three-dimensional space requires three Coordinate system, position coordinates. Similarly, the direction and speed at which a particle moves can be described in terms of three velocity components, each in reference to the three dimensions of space. So, if the time evolution of the system is Deterministic system, deterministic (where the state at one instant uniquely determines its past and future position and velocity as a function of time), such a system has six degrees of f ...
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Linear Independence
In the theory of vector spaces, a set (mathematics), set of vector (mathematics), vectors is said to be if there exists no nontrivial linear combination of the vectors that equals the zero vector. If such a linear combination exists, then the vectors are said to be . These concepts are central to the definition of Dimension (vector space), dimension. A vector space can be of finite dimension or infinite dimension depending on the maximum number of linearly independent vectors. The definition of linear dependence and the ability to determine whether a subset of vectors in a vector space is linearly dependent are central to determining the dimension of a vector space. Definition A sequence of vectors \mathbf_1, \mathbf_2, \dots, \mathbf_k from a vector space is said to be ''linearly dependent'', if there exist Scalar (mathematics), scalars a_1, a_2, \dots, a_k, not all zero, such that :a_1\mathbf_1 + a_2\mathbf_2 + \cdots + a_k\mathbf_k = \mathbf, where \mathbf denotes ...
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Rank (linear Algebra)
In linear algebra, the rank of a matrix is the dimension of the vector space generated (or spanned) by its columns. p. 48, § 1.16 This corresponds to the maximal number of linearly independent columns of . This, in turn, is identical to the dimension of the vector space spanned by its rows. Rank is thus a measure of the " nondegenerateness" of the system of linear equations and linear transformation encoded by . There are multiple equivalent definitions of rank. A matrix's rank is one of its most fundamental characteristics. The rank is commonly denoted by or ; sometimes the parentheses are not written, as in .Alternative notation includes \rho (\Phi) from and . Main definitions In this section, we give some definitions of the rank of a matrix. Many definitions are possible; see Alternative definitions for several of these. The column rank of is the dimension of the column space of , while the row rank of is the dimension of the row space of . A fundamental resul ...
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Graphite
Graphite () is a Crystallinity, crystalline allotrope (form) of the element carbon. It consists of many stacked Layered materials, layers of graphene, typically in excess of hundreds of layers. Graphite occurs naturally and is the most stable form of carbon under standard conditions. Synthetic and natural graphite are consumed on a large scale (1.3million metric tons per year in 2022) for uses in many critical industries including refractories (50%), lithium-ion batteries (18%), foundries (10%), and lubricants (5%), among others (17%). Graphite converts to diamond under extremely high pressure and temperature. Graphite's low cost, thermal and chemical inertness and characteristic conductivity of heat and electricity finds numerous applications in high energy and high temperature processes. Types and varieties Graphite can occur naturally or be produced synthetically. Natural graphite is obtained from naturally occurring geologic deposits and synthetic graphite is produced t ...
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Polymer
A polymer () is a chemical substance, substance or material that consists of very large molecules, or macromolecules, that are constituted by many repeat unit, repeating subunits derived from one or more species of monomers. Due to their broad spectrum of properties, both synthetic and natural polymers play essential and ubiquitous roles in everyday life. Polymers range from familiar synthetic plastics such as polystyrene to natural biopolymers such as DNA and proteins that are fundamental to biological structure and function. Polymers, both natural and synthetic, are created via polymerization of many small molecules, known as monomers. Their consequently large molecular mass, relative to small molecule compound (chemistry), compounds, produces unique physical property, physical properties including toughness, high rubber elasticity, elasticity, viscoelasticity, and a tendency to form Amorphous solid, amorphous and crystallization of polymers, semicrystalline structures rath ...
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