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Complete Set Of Commuting Operators
In quantum mechanics, a complete set of commuting observables (CSCO) is a set of commuting operators whose common eigenvectors can be used as a basis to express any quantum state. In the case of operators with discrete spectra, a CSCO is a set of commuting observables whose simultaneous eigenspaces span the Hilbert space, so that the eigenvectors are uniquely specified by the corresponding sets of eigenvalues. Since each pair of observables in the set commutes, the observables are all compatible so that the measurement of one observable has no effect on the result of measuring another observable in the set. It is therefore ''not'' necessary to specify the order in which the different observables are measured. Measurement of the complete set of observables constitutes a complete measurement, in the sense that it projects the quantum state of the system onto a unique and known vector in the basis defined by the set of operators. That is, to prepare the completely specified state, we h ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Quantum Mechanics
Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, quantum field theory, quantum technology, and quantum information science. Classical physics, the collection of theories that existed before the advent of quantum mechanics, describes many aspects of nature at an ordinary (macroscopic) scale, but is not sufficient for describing them at small (atomic and subatomic) scales. Most theories in classical physics can be derived from quantum mechanics as an approximation valid at large (macroscopic) scale. Quantum mechanics differs from classical physics in that energy, momentum, angular momentum, and other quantities of a bound system are restricted to discrete values ( quantization); objects have characteristics of both particles and waves (wave–particle duality); and there are limits to ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Good Quantum Number
In quantum mechanics, given a particular Hamiltonian H and an operator O with corresponding eigenvalues and eigenvectors given by O, q_j\rangle=q_j, q_j\rangle, the q_j are said to be good quantum numbers if every eigenvector , q_j\rangle remains an eigenvector of O ''with the same eigenvalue'' as time evolves. In other words, the eigenvalues q_j are good quantum numbers if the corresponding operator O is a constant of motion. Good quantum numbers are often used to label initial and final states in experiments. For example, in particle colliders: 1. Particles are initially prepared in approximate momentum eigenstates; the particle momentum being a good quantum number for non-interacting particles. 2. The particles are made to collide. At this point, the momentum of each particle is undergoing change and thus the particles’ momenta are not a good quantum number for the interacting particles during the collision. 3. A significant time after the collision, particles are measure ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
The Principles Of Quantum Mechanics
''The Principles of Quantum Mechanics'' is an influential monograph on quantum mechanics written by Paul Dirac and first published by Oxford University Press in 1930. Dirac gives an account of quantum mechanics by "demonstrating how to construct a completely new theoretical framework from scratch"; "problems were tackled top-down, by working on the great principles, with the details left to look after themselves". It leaves classical physics behind after the first chapter, presenting the subject with a logical structure. Its 82 sections contain 785 equations with no diagrams. Dirac is credited with developing the subject "particularly in Cambridge and Göttingen between 1925–1927" (Farmelo). History The first and second editions of the book were published in 1930 and 1935. In 1947 the third edition of the book was published, in which the chapter on quantum electrodynamics was rewritten particularly with the inclusion of electron-positron creation. In the fourth edition ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
John Wiley & Sons
John Wiley & Sons, Inc., commonly known as Wiley (), is an American multinational publishing company founded in 1807 that focuses on academic publishing and instructional materials. The company produces books, journals, and encyclopedias, in print and electronically, as well as online products and services, training materials, and educational materials for undergraduate, graduate, and continuing education students. History The company was established in 1807 when Charles Wiley opened a print shop in Manhattan. The company was the publisher of 19th century American literary figures like James Fenimore Cooper, Washington Irving, Herman Melville, and Edgar Allan Poe, as well as of legal, religious, and other non-fiction titles. The firm took its current name in 1865. Wiley later shifted its focus to scientific, technical, and engineering subject areas, abandoning its literary interests. Wiley's son John (born in Flatbush, New York, October 4, 1808; died in East Orange, New Je ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Angular Momentum
In physics, angular momentum (rarely, moment of momentum or rotational momentum) is the rotational analog of linear momentum. It is an important physical quantity because it is a conserved quantity—the total angular momentum of a closed system remains constant. Angular momentum has both a direction and a magnitude, and both are conserved. Bicycles and motorcycles, frisbees, rifled bullets, and gyroscopes owe their useful properties to conservation of angular momentum. Conservation of angular momentum is also why hurricanes form spirals and neutron stars have high rotational rates. In general, conservation limits the possible motion of a system, but it does not uniquely determine it. The three-dimensional angular momentum for a point particle is classically represented as a pseudovector , the cross product of the particle's position vector (relative to some origin) and its momentum vector; the latter is in Newtonian mechanics. Unlike linear momentum, angular m ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Collapse Of The Wavefunction
In quantum mechanics, wave function collapse occurs when a wave function—initially in a superposition of several eigenstates—reduces to a single eigenstate due to interaction with the external world. This interaction is called an ''observation'', and is the essence of a measurement in quantum mechanics, which connects the wave function with classical observables such as position and momentum. Collapse is one of the two processes by which quantum systems evolve in time; the other is the continuous evolution governed by the Schrödinger equation. : Collapse is a black box for a thermodynamically irreversible interaction with a classical environment. Calculations of quantum decoherence show that when a quantum system interacts with the environment, the superpositions ''apparently'' reduce to mixtures of classical alternatives. Significantly, the combined wave function of the system and environment continue to obey the Schrödinger equation throughout this ''apparent'' coll ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Measurement In Quantum Mechanics
In quantum physics, a measurement is the testing or manipulation of a physical system to yield a numerical result. The predictions that quantum physics makes are in general probabilistic. The mathematical tools for making predictions about what measurement outcomes may occur were developed during the 20th century and make use of linear algebra and functional analysis. Quantum physics has proven to be an empirical success and to have wide-ranging applicability. However, on a more philosophical level, debates continue about the meaning of the measurement concept. Mathematical formalism "Observables" as self-adjoint operators In quantum mechanics, each physical system is associated with a Hilbert space, each element of which represents a possible state of the physical system. The approach codified by John von Neumann represents a measurement upon a physical system by a self-adjoint operator on that Hilbert space termed an "observable". These observables play the role of measurable ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Canonical Commutation Relation
In quantum mechanics, the canonical commutation relation is the fundamental relation between canonical conjugate quantities (quantities which are related by definition such that one is the Fourier transform of another). For example, hat x,\hat p_x= i\hbar \mathbb between the position operator and momentum operator in the direction of a point particle in one dimension, where is the commutator of and , is the imaginary unit, and is the reduced Planck's constant , and \mathbb is the unit operator. In general, position and momentum are vectors of operators and their commutation relation between different components of position and momentum can be expressed as hat r_i,\hat p_j= i\hbar \delta_ \mathbb. where \delta_ is the Kronecker delta. This relation is attributed to Werner Heisenberg, Max Born and Pascual Jordan (1925), who called it a "quantum condition" serving as a postulate of the theory; it was noted by E. Kennard (1927) to imply the Heisenberg uncertainty principl ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mathematical Formulation Of Quantum Mechanics
The mathematical formulations of quantum mechanics are those mathematical formalisms that permit a rigorous description of quantum mechanics. This mathematical formalism uses mainly a part of functional analysis, especially Hilbert spaces, which are a kind of linear space. Such are distinguished from mathematical formalisms for physics theories developed prior to the early 1900s by the use of abstract mathematical structures, such as infinite-dimensional Hilbert spaces ( ''L''2 space mainly), and operators on these spaces. In brief, values of physical observables such as energy and momentum were no longer considered as values of functions on phase space, but as eigenvalues; more precisely as spectral values of linear operators in Hilbert space. These formulations of quantum mechanics continue to be used today. At the heart of the description are ideas of ''quantum state'' and ''quantum observables'', which are radically different from those used in previous models of physical r ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Degenerate Energy Levels
In quantum mechanics, an energy level is degenerate if it corresponds to two or more different measurable states of a quantum system. Conversely, two or more different states of a quantum mechanical system are said to be degenerate if they give the same value of energy upon measurement. The number of different states corresponding to a particular energy level is known as the degree of degeneracy of the level. It is represented mathematically by the Hamiltonian for the system having more than one linearly independent eigenstate with the same energy eigenvalue. When this is the case, energy alone is not enough to characterize what state the system is in, and other quantum numbers are needed to characterize the exact state when distinction is desired. In classical mechanics, this can be understood in terms of different possible trajectories corresponding to the same energy. Degeneracy plays a fundamental role in quantum statistical mechanics. For an -particle system in three dimens ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Quantum Number
In quantum physics and chemistry, quantum numbers describe values of conserved quantities in the dynamics of a quantum system. Quantum numbers correspond to eigenvalues of operators that commute with the Hamiltonian—quantities that can be known with precision at the same time as the system's energyspecifically, observables \widehat that commute with the Hamiltonian are simultaneously diagonalizable with it and so the eigenvalues a and the energy (eigenvalues of the Hamiltonian) are not limited by an uncertainty relation arising from non-commutativity.—and their corresponding eigenspaces. Together, a specification of all of the quantum numbers of a quantum system fully characterize a basis state of the system, and can in principle be measured together. An important aspect of quantum mechanics is the quantization of many observable quantities of interest.Many observables have discrete spectra (sets of eigenvalues) in quantum mechanics, so the quantities can only be measure ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Commutative
In mathematics, a binary operation is commutative if changing the order of the operands does not change the result. It is a fundamental property of many binary operations, and many mathematical proofs depend on it. Most familiar as the name of the property that says something like or , the property can also be used in more advanced settings. The name is needed because there are operations, such as division and subtraction, that do not have it (for example, ); such operations are ''not'' commutative, and so are referred to as ''noncommutative operations''. The idea that simple operations, such as the multiplication and addition of numbers, are commutative was for many years implicitly assumed. Thus, this property was not named until the 19th century, when mathematics started to become formalized. A similar property exists for binary relations; a binary relation is said to be symmetric if the relation applies regardless of the order of its operands; for example, equality is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
