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Collisional Excitation
Collisional excitation is a process in which the kinetic energy of a collision partner is converted into the internal energy of a reactant species. Astronomy In astronomy, collisional excitation gives rise to spectral lines in the spectra of astronomical objects such as planetary nebulae and H II regions. In these objects, most atoms are ionised by photons from hot stars embedded within the nebular gas, stripping away electrons. The emitted electrons, (called photoelectrons), may collide with atoms or ions within the gas, and excite them. When these excited atoms or ions revert to their ground state, they will emit a photon. The spectral lines formed by these photons are called ''collisionally excited lines'' (often abbreviated to CELs). CELs are only seen in gases at very low densities (typically less than a few thousand particles per cm³) for forbidden transitions. For allowed transitions, the gas density can be substantially higher. At higher densities, the reverse process o ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Kinetic Energy
In physics, the kinetic energy of an object is the energy that it possesses due to its motion. It is defined as the work needed to accelerate a body of a given mass from rest to its stated velocity. Having gained this energy during its acceleration, the body maintains this kinetic energy unless its speed changes. The same amount of work is done by the body when decelerating from its current speed to a state of rest. Formally, a kinetic energy is any term in a system's Lagrangian which includes a derivative with respect to time. In classical mechanics, the kinetic energy of a non-rotating object of mass ''m'' traveling at a speed ''v'' is \fracmv^2. In relativistic mechanics, this is a good approximation only when ''v'' is much less than the speed of light. The standard unit of kinetic energy is the joule, while the English unit of kinetic energy is the foot-pound. History and etymology The adjective ''kinetic'' has its roots in the Greek word κίνησις ''kinesis'', m ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Vacuum
A vacuum is a space devoid of matter. The word is derived from the Latin adjective ''vacuus'' for "vacant" or "void". An approximation to such vacuum is a region with a gaseous pressure much less than atmospheric pressure. Physicists often discuss ideal test results that would occur in a ''perfect'' vacuum, which they sometimes simply call "vacuum" or free space, and use the term partial vacuum to refer to an actual imperfect vacuum as one might have in a laboratory or in space. In engineering and applied physics on the other hand, vacuum refers to any space in which the pressure is considerably lower than atmospheric pressure. The Latin term ''in vacuo'' is used to describe an object that is surrounded by a vacuum. The ''quality'' of a partial vacuum refers to how closely it approaches a perfect vacuum. Other things equal, lower gas pressure means higher-quality vacuum. For example, a typical vacuum cleaner produces enough suction to reduce air pressure by around 20%. But hig ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Collision-induced Absorption And Emission
In spectroscopy, collision-induced absorption and emission refers to spectral features generated by inelastic collisions of molecules in a gas. Such inelastic collisions (along with the absorption or emission of photons) may induce quantum transitions in the molecules, or the molecules may form transient supramolecular complexes with spectral features different from the underlying molecules. Collision-induced absorption and emission is particularly important in dense gases, such as hydrogen and helium clouds found in astronomical systems. Collision-induced absorption and emission is distinguished from collisional broadening in spectroscopy in that collisional broadening comes from elastic collisions of molecules, whereas collision-induced absorption and emission is an inherently inelastic process. Collision-induced spectra of gases Ordinary spectroscopy is concerned with the spectra of single atoms or molecules. Here we outline the very different spectra of complexes consistin ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Collision-induced Dissociation
Collision-induced dissociation (CID), also known as collisionally activated dissociation (CAD), is a mass spectrometry technique to induce fragmentation of selected ions in the gas phase. The selected ions (typically molecular ions or protonated molecules) are usually accelerated by applying an electrical potential to increase the ion kinetic energy and then allowed to collide with neutral molecules (often helium, nitrogen or argon). In the collision some of the kinetic energy is converted into internal energy which results in bond breakage and the fragmentation of the molecular ion into smaller fragments. These fragment ions can then be analyzed by tandem mass spectrometry. CID and the fragment ions produced by CID are used for several purposes. Partial or complete structural determination can be achieved. In some cases identity can be established based on previous knowledge without determining structure. Another use is in simply achieving more sensitive and specific detection ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Argon
Argon is a chemical element with the symbol Ar and atomic number 18. It is in group 18 of the periodic table and is a noble gas. Argon is the third-most abundant gas in Earth's atmosphere, at 0.934% (9340 ppmv). It is more than twice as abundant as water vapor (which averages about 4000 ppmv, but varies greatly), 23 times as abundant as carbon dioxide (400 ppmv), and more than 500 times as abundant as neon (18 ppmv). Argon is the most abundant noble gas in Earth's crust, comprising 0.00015% of the crust. Nearly all of the argon in Earth's atmosphere is radiogenic argon-40, derived from the decay of potassium-40 in Earth's crust. In the universe, argon-36 is by far the most common argon isotope, as it is the most easily produced by stellar nucleosynthesis in supernovas. The name "argon" is derived from the Greek word , neuter singular form of meaning 'lazy' or 'inactive', as a reference to the fact that the element undergoes almost no chemical reactions. The complete octe ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitrogen
Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at seventh in total abundance in the Milky Way and the Solar System. At standard temperature and pressure, two atoms of the element bond to form N2, a colorless and odorless diatomic gas. N2 forms about 78% of Earth's atmosphere, making it the most abundant uncombined element. Nitrogen occurs in all organisms, primarily in amino acids (and thus proteins), in the nucleic acids ( DNA and RNA) and in the energy transfer molecule adenosine triphosphate. The human body contains about 3% nitrogen by mass, the fourth most abundant element in the body after oxygen, carbon, and hydrogen. The nitrogen cycle describes the movement of the element from the air, into the biosphere and organic compounds, then back into the atmosphere. Many indus ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Helium
Helium (from el, ἥλιος, helios, lit=sun) is a chemical element with the symbol He and atomic number 2. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas and the first in the noble gas group in the periodic table. Its boiling and melting point are the lowest among all the elements. It is the second lightest and second most abundant element in the observable universe (hydrogen is the lightest and most abundant). It is present at about 24% of the total elemental mass, which is more than 12 times the mass of all the heavier elements combined. Its abundance is similar to this in both the Sun and in Jupiter, due to the very high nuclear binding energy (per nucleon) of helium-4, with respect to the next three elements after helium. This helium-4 binding energy also accounts for why it is a product of both nuclear fusion and radioactive decay. The most common isotope of helium in the universe is helium-4, the vast majority of which was formed during t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Accelerate
In mechanics, acceleration is the rate of change of the velocity of an object with respect to time. Accelerations are vector quantities (in that they have magnitude and direction). The orientation of an object's acceleration is given by the orientation of the ''net'' force acting on that object. The magnitude of an object's acceleration, as described by Newton's Second Law, is the combined effect of two causes: * the net balance of all external forces acting onto that object — magnitude is directly proportional to this net resulting force; * that object's mass, depending on the materials out of which it is made — magnitude is inversely proportional to the object's mass. The SI unit for acceleration is metre per second squared (, \mathrm). For example, when a vehicle starts from a standstill (zero velocity, in an inertial frame of reference) and travels in a straight line at increasing speeds, it is accelerating in the direction of travel. If the vehicle turns, an accel ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mass Spectrometry
Mass spectrometry (MS) is an analytical technique that is used to measure the mass-to-charge ratio of ions. The results are presented as a ''mass spectrum'', a plot of intensity as a function of the mass-to-charge ratio. Mass spectrometry is used in many different fields and is applied to pure samples as well as complex mixtures. A mass spectrum is a type of plot of the ion signal as a function of the mass-to-charge ratio. These spectra are used to determine the elemental or isotopic signature of a sample, the masses of particles and of molecules, and to elucidate the chemical identity or structure of molecules and other chemical compounds. In a typical MS procedure, a sample, which may be solid, liquid, or gaseous, is ionized, for example by bombarding it with a beam of electrons. This may cause some of the sample's molecules to break up into positively charged fragments or simply become positively charged without fragmenting. These ions (fragments) are then separated accordin ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxygen
Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as well as with other compounds. Oxygen is Earth's most abundant element, and after hydrogen and helium, it is the third-most abundant element in the universe. At standard temperature and pressure, two atoms of the element bind to form dioxygen, a colorless and odorless diatomic gas with the formula . Diatomic oxygen gas currently constitutes 20.95% of the Earth's atmosphere, though this has changed considerably over long periods of time. Oxygen makes up almost half of the Earth's crust in the form of oxides.Atkins, P.; Jones, L.; Laverman, L. (2016).''Chemical Principles'', 7th edition. Freeman. Many major classes of organic molecules in living organisms contain oxygen atoms, such as proteins, nucleic acids, carbohydrates, and fats, as ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nebulium
Nebulium was a proposed element found in astronomical observation of a nebula by William Huggins in 1864. The strong green emission lines of the Cat's Eye Nebula, discovered using spectroscopy, led to the postulation that an as yet unknown element was responsible for this emission. In 1927, Ira Sprague Bowen showed that the lines are emitted by doubly ionized oxygen (O2+), and no new element was necessary to explain them. History William Hyde Wollaston in 1802 and Joseph von Fraunhofer in 1814 described the dark lines within the solar spectrum. Later, Gustav Kirchhoff explained the lines by atomic absorption or emission, which allowed the lines to be used for the identification of chemical elements. In the early days of telescopic astronomy, the word nebula was used to describe any fuzzy patch of light that did not look like a star. Many of these, such as the Andromeda Nebula, had spectra that looked like stellar spectra, and these turned out to be galaxies. Others, such a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cat's Eye Nebula
The Cat's Eye Nebula (also known as NGC 6543 and Caldwell 6) is a planetary nebula in the northern constellation of Draco, discovered by William Herschel on February 15, 1786. It was the first planetary nebula whose spectrum was investigated by the English amateur astronomer William Huggins, demonstrating that planetary nebulae were gaseous and not stellar in nature. Structurally, the object has had high-resolution images by the Hubble Space Telescope revealing knots, jets, bubbles and complex arcs, being illuminated by the central hot planetary nebula nucleus (PNN). It is a well-studied object that has been observed from radio to X-ray wavelengths. General information NGC 6543 is a high northern declination deep-sky object. It has the combined magnitude of 8.1, with high surface brightness. Its small bright inner nebula subtends an average of 16.1 arcsec, with the outer prominent condensations about 25 arcsec. Deep images reveal an extended halo about 300 arcsec or 5 arcminut ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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