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Coker Unit
A coker or coker unit is an oil refinery processing unit that converts the residual oil from the vacuum distillation column into low molecular weight hydrocarbon gases, naphtha, light and heavy gas oils, and petroleum coke. The process thermally cracks the long chain hydrocarbon molecules in the residual oil feed into shorter chain molecules leaving behind the excess carbon in the form of petroleum coke. This petroleum coke can either be fuel grade (high in sulphur and metals) or anode grade (low in sulphur and metals). The raw coke from the coker is often referred to as green coke. In this context, "green" means unprocessed. The further processing of green coke by calcining in a rotary kiln removes residual volatile hydrocarbons from the coke. The calcined petroleum coke can be further processed in an anode baking oven in order to produce anode coke of the desired shape and physical properties. The anodes are mainly used in the aluminium and steel industry. Types of coker u ...
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Oil Refinery
An oil refinery or petroleum refinery is an industrial process plant where petroleum (crude oil) is transformed and refined into useful products such as gasoline (petrol), diesel fuel, asphalt base, fuel oils, heating oil, kerosene, liquefied petroleum gas and petroleum naphtha. Petrochemicals feedstock like ethylene and propylene can also be produced directly by cracking crude oil without the need of using refined products of crude oil such as naphtha. The crude oil feedstock has typically been processed by an oil production plant. There is usually an oil depot at or near an oil refinery for the storage of incoming crude oil feedstock as well as bulk liquid products. In 2020, the total capacity of global refineries for crude oil was about 101.2 million barrels per day. Oil refineries are typically large, sprawling industrial complexes with extensive piping running throughout, carrying streams of fluids between large chemical processing units, such as distillation colu ...
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Aluminium
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It has a great affinity towards oxygen, and forms a protective layer of oxide on the surface when exposed to air. Aluminium visually resembles silver, both in its color and in its great ability to reflect light. It is soft, non-magnetic and ductile. It has one stable isotope, 27Al; this isotope is very common, making aluminium the twelfth most common element in the Universe. The radioactivity of 26Al is used in radiodating. Chemically, aluminium is a post-transition metal in the boron group; as is common for the group, aluminium forms compounds primarily in the +3 oxidation state. The aluminium cation Al3+ is small and highly charged; as such, it is polarizing, and bonds aluminium forms tend towards covalency. The strong affinity tow ...
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Oil Refineries
An oil refinery or petroleum refinery is an industrial process plant where petroleum (crude oil) is transformed and refined into useful products such as gasoline (petrol), diesel fuel, asphalt base, fuel oils, heating oil, kerosene, liquefied petroleum gas and petroleum naphtha. Petrochemicals feedstock like ethylene and propylene can also be produced directly by cracking crude oil without the need of using refined products of crude oil such as naphtha. The crude oil feedstock has typically been processed by an oil production plant. There is usually an oil depot at or near an oil refinery for the storage of incoming crude oil feedstock as well as bulk liquid products. In 2020, the total capacity of global refineries for crude oil was about 101.2 million barrels per day. Oil refineries are typically large, sprawling industrial complexes with extensive piping running throughout, carrying streams of fluids between large chemical processing units, such as distillation columns. I ...
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Petroleum Coke
Petroleum coke, abbreviated coke or petcoke, is a final carbon-rich solid material that derives from oil refining, and is one type of the group of fuels referred to as cokes. Petcoke is the coke that, in particular, derives from a final cracking process—a thermo-based chemical engineering process that splits long chain hydrocarbons of petroleum into shorter chains—that takes place in units termed coker units. (Other types of coke are derived from coal.) Stated succinctly, coke is the "carbonization product of high-boiling hydrocarbon fractions obtained in petroleum processing (heavy residues)". Petcoke is also produced in the production of synthetic crude oil (syncrude) from bitumen extracted from Canada’s oil sands and from Venezuela's Orinoco oil sands. In petroleum coker units, residual oils from other distillation processes used in petroleum refining are treated at a high temperature and pressure leaving the petcoke after driving off gases and volatiles, and separa ...
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Burton Process
The Burton process is a thermal cracking process invented by William Merriam Burton and Robert E. Humphreys, each of whom held a PhD in chemistry from Johns Hopkins University. The process they developed is often called the Burton process. More fairly, though, it should be known as the Burton-Humphreys process, since both men played key roles in its development. This issue was settled in court, although the decision gave primary recognition to Burton. The process uses the destructive distillation of crude oil heated in a still under pressure. In this revolutionary still, different products emerging from a bubble tower at different temperatures and pressures. Of critical importance, the use of these stills more than doubled the production of gasoline from most kinds of oil. The first large-scale use of these towers began with the decision by Standard Oil of Indiana to build 120 stills for an appropriation of $709,000, authorized in 1911. This decision was taken just as the US Supreme ...
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Shukhov Cracking Process
The Shukhov cracking process is a thermal cracking process invented by Vladimir Shukhov and Sergei Gavrilov. Shukhov designed and built the first thermal cracking device for the petrochemical industry. His patent (Shukhov cracking process – patent of Russian empire No. 12926 from November 27, 1891) on cracking was used to invalidate Standard Oil's patents (Burton process – Patent of United States No. 1,049,667 on January 7, 1913) on oil refineries. In 1937 the Shukhov cracking process was superseded by catalytic cracking. It is still in use today to produce diesel. See also * Cracking (chemistry) * Timeline of historic inventions * Burton process The Burton process is a thermal cracking process invented by William Merriam Burton and Robert E. Humphreys, each of whom held a PhD in chemistry from Johns Hopkins University. The process they developed is often called the Burton process. More fai ... References Information on cracking in oil refining* "Vladimir G. Suchov 1853 ...
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Delayed Coker
A delayed coker is a type of coker whose process consists of heating a residual oil feed to its thermal cracking temperature in a furnace with multiple parallel passes. This cracks the heavy, long chain hydrocarbon molecules of the residual oil into coker gas oil and petroleum coke. Delayed coking is one of the unit processes used in many oil refineries. The adjacent photograph depicts a delayed coking unit with 4 drums. However, larger units have tandem pairs of drums, some with as many as 8 drums, each of which may have diameters of up to 10 meters and overall heights of up to 43 meters. The yield of coke from the delayed coking process ranges from about 18 to 30 percent by weight of the feedstock residual oil, depending on the composition of the feedstock and the operating variables. Many refineries worldwide produce as much as 2,000 to 3,000 tons per day of petroleum coke and some produce even more. Schematic flow diagram and description The flow diagram and description in ...
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Fluid Coker
In physics, a fluid is a liquid, gas, or other material that continuously deforms (''flows'') under an applied shear stress, or external force. They have zero shear modulus, or, in simpler terms, are substances which cannot resist any shear force applied to them. Although the term ''fluid'' generally includes both the liquid and gas phases, its definition varies among branches of science. Definitions of ''solid'' vary as well, and depending on field, some substances can be both fluid and solid. Viscoelastic fluids like Silly Putty appear to behave similar to a solid when a sudden force is applied. Substances with a very high viscosity such as pitch appear to behave like a solid (see pitch drop experiment) as well. In particle physics, the concept is extended to include fluidic matters other than liquids or gases. A fluid in medicine or biology refers any liquid constituent of the body (body fluid), whereas "liquid" is not used in this sense. Sometimes liquids given for fluid ...
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Delayed Coker
A delayed coker is a type of coker whose process consists of heating a residual oil feed to its thermal cracking temperature in a furnace with multiple parallel passes. This cracks the heavy, long chain hydrocarbon molecules of the residual oil into coker gas oil and petroleum coke. Delayed coking is one of the unit processes used in many oil refineries. The adjacent photograph depicts a delayed coking unit with 4 drums. However, larger units have tandem pairs of drums, some with as many as 8 drums, each of which may have diameters of up to 10 meters and overall heights of up to 43 meters. The yield of coke from the delayed coking process ranges from about 18 to 30 percent by weight of the feedstock residual oil, depending on the composition of the feedstock and the operating variables. Many refineries worldwide produce as much as 2,000 to 3,000 tons per day of petroleum coke and some produce even more. Schematic flow diagram and description The flow diagram and description in ...
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Steel
Steel is an alloy made up of iron with added carbon to improve its strength and fracture resistance compared to other forms of iron. Many other elements may be present or added. Stainless steels that are corrosion- and oxidation-resistant typically need an additional 11% chromium. Because of its high tensile strength and low cost, steel is used in buildings, infrastructure, tools, ships, trains, cars, machines, electrical appliances, weapons, and rockets. Iron is the base metal of steel. Depending on the temperature, it can take two crystalline forms (allotropic forms): body-centred cubic and face-centred cubic. The interaction of the allotropes of iron with the alloying elements, primarily carbon, gives steel and cast iron their range of unique properties. In pure iron, the crystal structure has relatively little resistance to the iron atoms slipping past one another, and so pure iron is quite ductile, or soft and easily formed. In steel, small amounts of carbon, other ...
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Calcined Petroleum Coke
Petroleum coke, abbreviated coke or petcoke, is a final carbon-rich solid material that derives from oil refining, and is one type of the group of fuels referred to as cokes. Petcoke is the coke that, in particular, derives from a final cracking process—a thermo-based chemical engineering process that splits long chain hydrocarbons of petroleum into shorter chains—that takes place in units termed coker units. (Other types of coke are derived from coal.) Stated succinctly, coke is the "carbonization product of high-boiling hydrocarbon fractions obtained in petroleum processing (heavy residues)". Petcoke is also produced in the production of synthetic crude oil (syncrude) from bitumen extracted from Canada’s oil sands and from Venezuela's Orinoco oil sands. In petroleum coker units, residual oils from other distillation processes used in petroleum refining are treated at a high temperature and pressure leaving the petcoke after driving off gases and volatiles, and separ ...
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