|
Cobalt Monosilicide
Cobalt monosilicide (CoSi) is an intermetallic compound, a silicide of cobalt. It is a diamagnetic semimetal with an electrical resistivity Electrical resistivity (also called specific electrical resistance or volume resistivity) is a fundamental property of a material that measures how strongly it resists electric current. A low resistivity indicates a material that readily allows ... of ca. 1 mOhm·cm. References Cobalt compounds Transition metal silicides Iron monosilicide structure type {{Alloy-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cubic Crystal System
In crystallography, the cubic (or isometric) crystal system is a crystal system where the Crystal_structure#Unit_cell, unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals. There are three main varieties of these crystals: *Primitive cubic (abbreviated ''cP'' and alternatively called simple cubic) *Body-centered cubic (abbreviated ''cI'' or bcc) *Face-centered cubic (abbreviated ''cF'' or fcc, and alternatively called Close-packing_of_equal_spheres, ''cubic close-packed'' or ccp) Each is subdivided into other variants listed below. Although the ''unit cells'' in these crystals are conventionally taken to be cubes, the primitive_cell, primitive unit cells often are not. Bravais lattices The three Bravais lattices in the cubic crystal system are: The primitive cubic lattice (cP) consists of one Lattice_(group), lattice point on each corner of the cube; this means each simple cubic unit cell has in total one latt ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pearson Symbol
The Pearson symbol, or Pearson notation, is used in crystallography as a means of describing a crystal structure, and was originated by W. B. Pearson. The symbol is made up of two letters followed by a number. For example: * Diamond structure, ''cF''8 * Rutile structure, ''tP''6 The two (italicised) letters specify the Bravais lattice. The lower-case letter specifies the crystal family, and the upper-case letter the centering type. The number at the end of the Pearson symbol gives the number of the atoms in the conventional unit cell.Nomenclature of Inorganic Chemistry IUPAC Recommendations 2005 IR-3.4.4, pp. 49–51; IR-11.5, pp. 241–242. |
Cobalt Germanide
Cobalt germanide (CoGe) is an intermetallic compound, a germanide of cobalt. Cubic CoGe crystals (space group P213, cP8, ''a'' = 0.4631 nm) can be produced by processing a mixture of Co and Ge powders at a pressure of 4 GPa and a temperature of 800–1000 °C for 1 to 3 hours. They have no inversion center, and are therefore helical, with right-hand and left-handed chiralities. The cubic CoGe is metastable, and converts into a monoclinic phase upon subsequent heating to 600 °C at ambient pressure. Cubic CoGe is an antiferromagnet In materials that exhibit antiferromagnetism, the magnetic moments of atoms or molecules, usually related to the spins of electrons, align in a regular pattern with neighboring spins (on different sublattices) pointing in opposite directions. ... with a transition temperature ''T''c of 132 K. References {{Cobalt compounds Cobalt compounds Germanides Iron monosilicide structure type ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iron Monosilicide
Iron monosilicide (FeSi) is an intermetallic compound, a silicide of iron that occurs in nature as the rare mineral naquite. It is a narrow-bandgap semiconductor with a room-temperature electrical resistivity of ca. 10,000 Ohm·cm and unusual magnetic properties at low temperatures. FeSi has a cubic crystal lattice with no inversion center; therefore its magnetic structure is helical, with right-hand and left-handed chiralities. The structure is similar to that of sodium chloride, with four iron atoms and four silicon atoms in each unit cell. Whereas in sodium chloride the eight atoms are at the corners of a cube and each ion is surrounded by six counter-ions, in iron monosilicide the atoms are all displaced parallele to body diagonals (along 3-fold axes) from the positions of sodium and chloride. The crystal therefore loses symmetry, but retains the 2-fold screw axes and the 3-fold axes of the sodium chloride crystal structure. As a result of this displacement, an iron atom is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Manganese Monosilicide
Manganese monosilicide (MnSi) is an intermetallic compound, a silicide of manganese. It occurs in cosmic dust as the mineral brownleeite. MnSi has a cubic crystal lattice with no inversion center; therefore its crystal structure is helical, with right-hand and left-hand chiralities. MnSi is a paramagnetic metal that turns into a ferromagnet at cryogenic temperatures below 29 K. In the ferromagnetic state, the spatial arrangement of electron spins in MnSi changes with magnetic field, forming helical, conical, skyrmion, and regular ferromagnetic phases. Crystal structure and magnetism Manganese monosilicide is a non-stoichiometric compound, meaning that the 1:1 Mn:Si composition, lattice constant and many other properties vary depending on the synthesis and processing history of the crystal. MnSi has a cubic crystal lattice with no inversion center; therefore its crystal structure is helical, with right-hand and left-hand chiralities. At low temperatures and magnetic fields, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cobalt Disilicide
Cobalt disilicide (CoSi2) is an intermetallic compound, a silicide of cobalt. It is a superconductor with a transition temperature of around 1.4 K and a critical field For a given temperature, the critical field refers to the maximum magnetic field strength below which a material remains superconducting. Superconductivity is characterized both by perfect conductivity (zero resistance) and by the complete expulsio ... of 105 Oe.Haynes, p. 12.70 References Cited sources * {{Silicides Cobalt compounds Transition metal silicides Fluorite crystal structure ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Intermetallic Compound
An intermetallic (also called an intermetallic compound, intermetallic alloy, ordered intermetallic alloy, and a long-range-ordered alloy) is a type of metallic alloy that forms an ordered solid-state compound between two or more metallic elements. Intermetallics are generally hard and brittle, with good high-temperature mechanical properties. They can be classified as stoichiometric or nonstoichiometic intermetallic compounds. Although the term "intermetallic compounds", as it applies to solid phases, has been in use for many years, its introduction was regretted, for example by Hume-Rothery in 1955. Definitions Research definition Schulze in 1967 defined intermetallic compounds as ''solid phases containing two or more metallic elements, with optionally one or more non-metallic elements, whose crystal structure differs from that of the other constituents''. Under this definition, the following are included: #Electron (or Hume-Rothery) compounds #Size packing phases. e.g. Lav ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Silicide
A silicide is a type of chemical compound that combines silicon and a (usually) more electropositive element. Silicon is more electropositive than carbon. Silicides are structurally closer to borides than to carbides. Similar to borides and carbides, the composition of silicides cannot be easily specified as covalent molecules. The chemical bonds in silicides range from conductive metal-like structures to covalent or ionic. Silicides of all non-transition metals, with exception of beryllium, have been described. Overview Silicon atoms in silicides can have many possible organizations: *Isolated silicon atoms: electrically conductive (or semiconductive) CrSi, MnSi, FeSi, CoSi, , , , , and nonconductive , *Si2 pairs: , hafnium and thorium silicides *Si4 tetrahedra: KSi, RbSi, CsSi *Si''n'' chains: USi, , CaSi, SrSi, YSi *Planar hexagonal graphite-like Si layers: β-USi2, silicides of other lanthanoids and actinoids *Corrugated hexagonal Si layers: CaSi2 *Open three-dimensio ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cobalt
Cobalt is a chemical element with the symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, produced by reductive smelting, is a hard, lustrous, silver-gray metal. Cobalt-based blue pigments ( cobalt blue) have been used since ancient times for jewelry and paints, and to impart a distinctive blue tint to glass, but the color was for a long time thought to be due to the known metal bismuth. Miners had long used the name ''kobold ore'' (German for ''goblin ore'') for some of the blue-pigment-producing minerals; they were so named because they were poor in known metals, and gave poisonous arsenic-containing fumes when smelted. In 1735, such ores were found to be reducible to a new metal (the first discovered since ancient times), and this was ultimately named for the ''kobold''. Today, some cobalt is produced specifically from one of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Diamagnetic
Diamagnetic materials are repelled by a magnetic field; an applied magnetic field creates an induced magnetic field in them in the opposite direction, causing a repulsive force. In contrast, paramagnetic and ferromagnetic materials are attracted by a magnetic field. Diamagnetism is a quantum mechanical effect that occurs in all materials; when it is the only contribution to the magnetism, the material is called diamagnetic. In paramagnetic and ferromagnetic substances, the weak diamagnetic force is overcome by the attractive force of magnetic dipoles in the material. The magnetic permeability of diamagnetic materials is less than the permeability of vacuum, ''μ''0. In most materials, diamagnetism is a weak effect which can be detected only by sensitive laboratory instruments, but a superconductor acts as a strong diamagnet because it repels a magnetic field entirely from its interior. Diamagnetism was first discovered when Anton Brugmans observed in 1778 that bismuth was repel ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Semimetal
A semimetal is a material with a very small overlap between the bottom of the conduction band and the top of the valence band. According to electronic band theory, solids can be classified as insulators, semiconductors, semimetals, or metals. In insulators and semiconductors the filled valence band is separated from an empty conduction band by a band gap. For insulators, the magnitude of the band gap is larger (e.g., > 4 eV) than that of a semiconductor (e.g., < 4 eV). Because of the slight overlap between the conduction and valence bands, semimetals have no band gap and a negligible at the Fermi level. A metal, by contrast, has an appreciable density of states at the Fermi level because the conduction band is partially filled. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrical Resistivity
Electrical resistivity (also called specific electrical resistance or volume resistivity) is a fundamental property of a material that measures how strongly it resists electric current. A low resistivity indicates a material that readily allows electric current. Resistivity is commonly represented by the Greek letter (rho). The SI unit of electrical resistivity is the ohm-meter (Ω⋅m). For example, if a solid cube of material has sheet contacts on two opposite faces, and the resistance between these contacts is , then the resistivity of the material is . Electrical conductivity or specific conductance is the reciprocal of electrical resistivity. It represents a material's ability to conduct electric current. It is commonly signified by the Greek letter ( sigma), but (kappa) (especially in electrical engineering) and (gamma) are sometimes used. The SI unit of electrical conductivity is siemens per metre (S/m). Resistivity and conductivity are intensi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
