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Clebsch–Gordan Coefficients
In physics, the Clebsch–Gordan (CG) coefficients are numbers that arise in angular momentum coupling in quantum mechanics. They appear as the expansion coefficients of total angular momentum eigenstates in an uncoupled tensor product basis. In more mathematical terms, the CG coefficients are used in representation theory, particularly of compact Lie groups, to perform the explicit direct sum decomposition of the tensor product of two irreducible representations (i.e., a reducible representation into irreducible representations, in cases where the numbers and types of irreducible components are already known abstractly). The name derives from the German mathematicians Alfred Clebsch and Paul Gordan, who encountered an equivalent problem in invariant theory. From a vector calculus perspective, the CG coefficients associated with the SO(3) group can be defined simply in terms of integrals of products of spherical harmonics and their complex conjugates. The addition of spins in qu ...
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Representation Theory
Representation theory is a branch of mathematics that studies abstract algebraic structures by ''representing'' their elements as linear transformations of vector spaces, and studies modules over these abstract algebraic structures. In essence, a representation makes an abstract algebraic object more concrete by describing its elements by matrices and their algebraic operations (for example, matrix addition, matrix multiplication). The theory of matrices and linear operators is well-understood, so representations of more abstract objects in terms of familiar linear algebra objects helps glean properties and sometimes simplify calculations on more abstract theories. The algebraic objects amenable to such a description include groups, associative algebras and Lie algebras. The most prominent of these (and historically the first) is the representation theory of groups, in which elements of a group are represented by invertible matrices in such a way that the group operation i ...
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Physics
Physics is the natural science that studies matter, its fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge which relates to the order of nature, or, in other words, to the regular succession of events." Physics is one of the most fundamental scientific disciplines, with its main goal being to understand how the universe behaves. "Physics is one of the most fundamental of the sciences. Scientists of all disciplines use the ideas of physics, including chemists who study the structure of molecules, paleontologists who try to reconstruct how dinosaurs walked, and climatologists who study how human activities affect the atmosphere and oceans. Physics is also the foundation of all engineering and technology. No engineer could design a flat-screen TV, an interplanetary spacecraft, or even a better mousetrap without first understanding the basic laws of physic ...
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Spherical Harmonic
In mathematics and physical science, spherical harmonics are special functions defined on the surface of a sphere. They are often employed in solving partial differential equations in many scientific fields. Since the spherical harmonics form a complete set of orthogonal functions and thus an orthonormal basis, each function defined on the surface of a sphere can be written as a sum of these spherical harmonics. This is similar to periodic functions defined on a circle that can be expressed as a sum of circular functions (sines and cosines) via Fourier series. Like the sines and cosines in Fourier series, the spherical harmonics may be organized by (spatial) angular frequency, as seen in the rows of functions in the illustration on the right. Further, spherical harmonics are basis functions for irreducible representations of SO(3), the group of rotations in three dimensions, and thus play a central role in the group theoretic discussion of SO(3). Spherical harmonics originat ...
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Representation Theory Of SU(2)
In the study of the representation theory of Lie groups, the study of representations of SU(2) is fundamental to the study of representations of semisimple Lie groups. It is the first case of a Lie group that is both a compact group and a non-abelian group. The first condition implies the representation theory is discrete: representations are direct sums of a collection of basic irreducible representations (governed by the Peter–Weyl theorem). The second means that there will be irreducible representations in dimensions greater than 1. SU(2) is the universal covering group of SO(3), and so its representation theory includes that of the latter, by dint of a surjective homomorphism to it. This underlies the significance of SU(2) for the description of non-relativistic spin in theoretical physics; see below for other physical and historical context. As shown below, the finite-dimensional irreducible representations of SU(2) are indexed by a non-negative integer m and have dimens ...
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Casimir Operator
In mathematics, a Casimir element (also known as a Casimir invariant or Casimir operator) is a distinguished element of the Center (ring theory), center of the universal enveloping algebra of a Lie algebra. A prototypical example is the squared angular momentum operator, which is a Casimir element of the three-dimensional Rotation group SO(3), rotation group. The Casimir element is named after Hendrik Casimir, who identified them in his description of rigid body dynamics in 1931. Definition The most commonly-used Casimir invariant is the quadratic invariant. It is the simplest to define, and so is given first. However, one may also have Casimir invariants of higher order, which correspond to homogeneous symmetric polynomials of higher order. Quadratic Casimir element Suppose that \mathfrak is an n-dimensional Lie algebra. Let ''B'' be a nondegenerate bilinear form on \mathfrak that is invariant under the Adjoint_representation_of_a_Lie_algebra, adjoint action of \mathfrak on ...
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Spherical Basis
In pure mathematics, pure and applied mathematics, particularly quantum mechanics and computer graphics and their applications, a spherical basis is the basis (linear algebra), basis used to express spherical tensors. The spherical basis closely relates to the description of angular momentum in quantum mechanics and spherical harmonic functions. While spherical polar coordinates are one orthogonal coordinates, orthogonal coordinate system for expressing vectors and tensors using polar and azimuthal angles and radial distance, the spherical basis are constructed from the standard basis and use complex numbers. In three dimensions A vector A in 3D Euclidean space can be expressed in the familiar Cartesian coordinate system in the standard basis e''x'', e''y'', e''z'', and Coordinate vector, coordinates ''Ax'', ''Ay'', ''Az'': or any other coordinate system with associated basis (linear algebra), basis set of vectors. From this extend the scalars to allow multiplication by co ...
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Tensor Operator
In pure and applied mathematics, quantum mechanics and computer graphics, a tensor operator generalizes the notion of operators which are scalars and vectors. A special class of these are spherical tensor operators which apply the notion of the spherical basis and spherical harmonics. The spherical basis closely relates to the description of angular momentum in quantum mechanics and spherical harmonic functions. The coordinate-free generalization of a tensor operator is known as a representation operator. The general notion of scalar, vector, and tensor operators In quantum mechanics, physical observables that are scalars, vectors, and tensors, must be represented by scalar, vector, and tensor operators, respectively. Whether something is a scalar, vector, or tensor depends on how it is viewed by two observers whose coordinate frames are related to each other by a rotation. Alternatively, one may ask how, for a single observer, a physical quantity transforms if the state of the ...
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Levi-Civita Permutation Symbol
In mathematics, particularly in linear algebra, tensor analysis, and differential geometry, the Levi-Civita symbol or Levi-Civita epsilon represents a collection of numbers; defined from the sign of a permutation of the natural numbers , for some positive integer . It is named after the Italian mathematician and physicist Tullio Levi-Civita. Other names include the permutation symbol, antisymmetric symbol, or alternating symbol, which refer to its antisymmetric property and definition in terms of permutations. The standard letters to denote the Levi-Civita symbol are the Greek lower case epsilon or , or less commonly the Latin lower case . Index notation allows one to display permutations in a way compatible with tensor analysis: \varepsilon_ where ''each'' index takes values . There are indexed values of , which can be arranged into an -dimensional array. The key defining property of the symbol is ''total antisymmetry'' in the indices. When any two indices are interchanged, e ...
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Commutation Relation
In mathematics, the commutator gives an indication of the extent to which a certain binary operation fails to be commutative. There are different definitions used in group theory and ring theory. Group theory The commutator of two elements, and , of a group , is the element : . This element is equal to the group's identity if and only if and commute (from the definition , being equal to the identity if and only if ). The set of all commutators of a group is not in general closed under the group operation, but the subgroup of ''G'' generated by all commutators is closed and is called the ''derived group'' or the ''commutator subgroup'' of ''G''. Commutators are used to define nilpotent and solvable groups and the largest abelian quotient group. The definition of the commutator above is used throughout this article, but many other group theorists define the commutator as :. Identities (group theory) Commutator identities are an important tool in group theory. The expr ...
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Self-adjoint Operator
In mathematics, a self-adjoint operator on an infinite-dimensional complex vector space ''V'' with inner product \langle\cdot,\cdot\rangle (equivalently, a Hermitian operator in the finite-dimensional case) is a linear map ''A'' (from ''V'' to itself) that is its own adjoint. If ''V'' is finite-dimensional with a given orthonormal basis, this is equivalent to the condition that the matrix of ''A'' is a Hermitian matrix, i.e., equal to its conjugate transpose ''A''. By the finite-dimensional spectral theorem, ''V'' has an orthonormal basis such that the matrix of ''A'' relative to this basis is a diagonal matrix with entries in the real numbers. In this article, we consider generalizations of this concept to operators on Hilbert spaces of arbitrary dimension. Self-adjoint operators are used in functional analysis and quantum mechanics. In quantum mechanics their importance lies in the Dirac–von Neumann formulation of quantum mechanics, in which physical observables such as positi ...
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Spherical Harmonics
In mathematics and physical science, spherical harmonics are special functions defined on the surface of a sphere. They are often employed in solving partial differential equations in many scientific fields. Since the spherical harmonics form a complete set of orthogonal functions and thus an orthonormal basis, each function defined on the surface of a sphere can be written as a sum of these spherical harmonics. This is similar to periodic functions defined on a circle that can be expressed as a sum of circular functions (sines and cosines) via Fourier series. Like the sines and cosines in Fourier series, the spherical harmonics may be organized by (spatial) angular frequency, as seen in the rows of functions in the illustration on the right. Further, spherical harmonics are basis functions for irreducible representations of SO(3), the group of rotations in three dimensions, and thus play a central role in the group theoretic discussion of SO(3). Spherical harmonics originate ...
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Bra–ket Notation
In quantum mechanics, bra–ket notation, or Dirac notation, is used ubiquitously to denote quantum states. The notation uses angle brackets, and , and a vertical bar , to construct "bras" and "kets". A ket is of the form , v \rangle. Mathematically it denotes a vector, \boldsymbol v, in an abstract (complex) vector space V, and physically it represents a state of some quantum system. A bra is of the form \langle f, . Mathematically it denotes a linear form f:V \to \Complex, i.e. a linear map that maps each vector in V to a number in the complex plane \Complex. Letting the linear functional \langle f, act on a vector , v\rangle is written as \langle f , v\rangle \in \Complex. Assume that on V there exists an inner product (\cdot,\cdot) with antilinear first argument, which makes V an inner product space. Then with this inner product each vector \boldsymbol \phi \equiv , \phi\rangle can be identified with a corresponding linear form, by placing the vector in the anti-line ...
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