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Clausius–Duhem Inequality
The Clausius–Duhem inequality is a way of expressing the second law of thermodynamics that is used in continuum mechanics. This inequality is particularly useful in determining whether the constitutive relation of a material is thermodynamically allowable.. This inequality is a statement concerning the irreversibility of natural processes, especially when energy dissipation is involved. It was named after the German physicist Rudolf Clausius and French physicist Pierre Duhem. Clausius–Duhem inequality in terms of the specific entropy The Clausius–Duhem inequality can be expressed in integral form as : \frac\left(\int_\Omega \rho \eta \, dV\right) \ge \int_ \rho \eta \left(u_n - \mathbf\cdot\mathbf\right) dA - \int_ \frac~ dA + \int_\Omega \frac~dV. In this equation t is the time, \Omega represents a body and the integration is over the volume of the body, \partial \Omega represents the surface of the body, \rho is the mass density of the body, \eta is th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Second Law Of Thermodynamics
The second law of thermodynamics is a physical law based on universal experience concerning heat and Energy transformation, energy interconversions. One simple statement of the law is that heat always moves from hotter objects to colder objects (or "downhill"), unless energy in some form is supplied to reverse the direction of heat flow. Another definition is: "Not all heat energy can be converted into Work (thermodynamics), work in a cyclic process."Young, H. D; Freedman, R. A. (2004). ''University Physics'', 11th edition. Pearson. p. 764. The second law of thermodynamics in other versions establishes the concept of entropy as a physical property of a thermodynamic system. It can be used to predict whether processes are forbidden despite obeying the requirement of conservation of energy as expressed in the first law of thermodynamics and provides necessary criteria for spontaneous processes. The second law may be formulated by the observation that the entropy of isolated systems ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Euclidean Vector
In mathematics, physics, and engineering, a Euclidean vector or simply a vector (sometimes called a geometric vector or spatial vector) is a geometric object that has magnitude (or length) and direction. Vectors can be added to other vectors according to vector algebra. A Euclidean vector is frequently represented by a '' directed line segment'', or graphically as an arrow connecting an ''initial point'' ''A'' with a ''terminal point'' ''B'', and denoted by \overrightarrow . A vector is what is needed to "carry" the point ''A'' to the point ''B''; the Latin word ''vector'' means "carrier". It was first used by 18th century astronomers investigating planetary revolution around the Sun. The magnitude of the vector is the distance between the two points, and the direction refers to the direction of displacement from ''A'' to ''B''. Many algebraic operations on real numbers such as addition, subtraction, multiplication, and negation have close analogues for vectors, operations whic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Entropy Production
Entropy production (or generation) is the amount of entropy which is produced in any irreversible processes such as heat and mass transfer processes including motion of bodies, heat exchange, fluid flow, substances expanding or mixing, anelastic deformation of solids, and any irreversible thermodynamic cycle, including thermal machines such as power plants, heat engines, refrigerators, heat pumps, and air conditioners. In the dual representation entropy–exergy for accounting the second law of thermodynamics it can be expressed in equivalent terms of exergy disruption. Short history Entropy is produced in irreversible processes. The importance of avoiding irreversible processes (hence reducing the entropy production) was recognized as early as 1824 by Carnot. In 1865 Rudolf Clausius expanded his previous work from 1854 on the concept of "unkompensierte Verwandlungen" (uncompensated transformations), which, in our modern nomenclature, would be called the entropy production. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dissipation
In thermodynamics, dissipation is the result of an irreversible process that takes place in homogeneous thermodynamic systems. In a dissipative process, energy (internal, bulk flow kinetic, or system potential) transforms from an initial form to a final form, where the capacity of the final form to do thermodynamic work is less than that of the initial form. For example, heat transfer is dissipative because it is a transfer of internal energy from a hotter body to a colder one. Following the second law of thermodynamics, the entropy varies with temperature (reduces the capacity of the combination of the two bodies to do work), but never decreases in an isolated system. These processes produce entropy at a certain rate. The entropy production rate times ambient temperature gives the dissipated power. Important examples of irreversible processes are: heat flow through a thermal resistance, fluid flow through a flow resistance, diffusion (mixing), chemical reactions, and electric cu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cartesian Coordinate System
A Cartesian coordinate system (, ) in a plane is a coordinate system that specifies each point uniquely by a pair of numerical coordinates, which are the signed distances to the point from two fixed perpendicular oriented lines, measured in the same unit of length. Each reference coordinate line is called a ''coordinate axis'' or just ''axis'' (plural ''axes'') of the system, and the point where they meet is its ''origin'', at ordered pair . The coordinates can also be defined as the positions of the perpendicular projections of the point onto the two axes, expressed as signed distances from the origin. One can use the same principle to specify the position of any point in three-dimensional space by three Cartesian coordinates, its signed distances to three mutually perpendicular planes (or, equivalently, by its perpendicular projection onto three mutually perpendicular lines). In general, ''n'' Cartesian coordinates (an element of real ''n''-space) specify the point in an ' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Conservation Of Momentum
In Newtonian mechanics, momentum (more specifically linear momentum or translational momentum) is the product of the mass and velocity of an object. It is a vector quantity, possessing a magnitude and a direction. If is an object's mass and is its velocity (also a vector quantity), then the object's momentum is : \mathbf = m \mathbf. In the International System of Units (SI), the unit of measurement of momentum is the kilogram metre per second (kg⋅m/s), which is equivalent to the newton-second. Newton's second law of motion states that the rate of change of a body's momentum is equal to the net force acting on it. Momentum depends on the frame of reference, but in any inertial frame it is a ''conserved'' quantity, meaning that if a closed system is not affected by external forces, its total linear momentum does not change. Momentum is also conserved in special relativity (with a modified formula) and, in a modified form, in electrodynamics, quantum mechanics, qu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Conservation Of Energy
In physics and chemistry, the law of conservation of energy states that the total energy of an isolated system remains constant; it is said to be ''conserved'' over time. This law, first proposed and tested by Émilie du Châtelet, means that energy can neither be created nor destroyed; rather, it can only be transformed or transferred from one form to another. For instance, chemical energy is converted to kinetic energy when a stick of dynamite explodes. If one adds up all forms of energy that were released in the explosion, such as the kinetic energy and potential energy of the pieces, as well as heat and sound, one will get the exact decrease of chemical energy in the combustion of the dynamite. Classically, conservation of energy was distinct from conservation of mass. However, special relativity shows that mass is related to energy and vice versa by ''E = mc2'', and science now takes the view that mass-energy as a whole is conserved. Theoretically, this implies that ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gradient
In vector calculus, the gradient of a scalar-valued differentiable function of several variables is the vector field (or vector-valued function) \nabla f whose value at a point p is the "direction and rate of fastest increase". If the gradient of a function is non-zero at a point , the direction of the gradient is the direction in which the function increases most quickly from , and the magnitude of the gradient is the rate of increase in that direction, the greatest absolute directional derivative. Further, a point where the gradient is the zero vector is known as a stationary point. The gradient thus plays a fundamental role in optimization theory, where it is used to maximize a function by gradient ascent. In coordinate-free terms, the gradient of a function f(\bf) may be defined by: :df=\nabla f \cdot d\bf where ''df'' is the total infinitesimal change in ''f'' for an infinitesimal displacement d\bf, and is seen to be maximal when d\bf is in the direction of the gradi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Stress (physics)
In continuum mechanics, stress is a physical quantity. It is a quantity that describes the magnitude of forces that cause deformation. Stress is defined as ''force per unit area''. When an object is pulled apart by a force it will cause elongation which is also known as deformation, like the stretching of an elastic band, it is called tensile stress. But, when the forces result in the compression of an object, it is called compressive stress. It results when forces like Tension (physics), tension or Compression (physics), compression act on a body. The greater this force and the smaller the cross-sectional area of the body on which it acts, the greater the stress. Therefore, stress is measured in newton per square meter (N/m2) or pascal (Pa). Stress expresses the internal forces that neighbouring particles of a continuous material exert on each other, while deformation (mechanics)#Strain, strain is the measure of the deformation of the material. For example, when a solid vertic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Internal Energy
The internal energy of a thermodynamic system is the total energy contained within it. It is the energy necessary to create or prepare the system in its given internal state, and includes the contributions of potential energy and internal kinetic energy. It keeps account of the gains and losses of energy of the system that are due to changes in its internal state. It does not include the kinetic energy of motion of the system as a whole, or any external energies from surrounding force fields. The internal energy of an isolated system is constant, which is expressed as the law of conservation of energy, a foundation of the first law of thermodynamics. The internal energy is an extensive property. The internal energy cannot be measured directly and knowledge of all its components is rarely interesting, such as the static rest mass energy of its constituent matter. Thermodynamics is chiefly concerned only with ''changes'' in the internal energy, not with its absolute value. Instea ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Conservation Of Mass
In physics and chemistry, the law of conservation of mass or principle of mass conservation states that for any system closed to all transfers of matter and energy, the mass of the system must remain constant over time, as the system's mass cannot change, so quantity can neither be added nor be removed. Therefore, the quantity of mass is conserved over time. The law implies that mass can neither be created nor destroyed, although it may be rearranged in space, or the entities associated with it may be changed in form. For example, in chemical reactions, the mass of the chemical components before the reaction is equal to the mass of the components after the reaction. Thus, during any chemical reaction and low-energy thermodynamic processes in an isolated system, the total mass of the reactants, or starting materials, must be equal to the mass of the products. The concept of mass conservation is widely used in many fields such as chemistry, mechanics, and fluid dynamics. Historic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Material Time Derivative
In continuum mechanics, the material derivative describes the time rate of change of some physical quantity (like heat or momentum) of a material element that is subjected to a space-and-time-dependent macroscopic velocity field. The material derivative can serve as a link between Eulerian and Lagrangian descriptions of continuum deformation. For example, in fluid dynamics, the velocity field is the flow velocity, and the quantity of interest might be the temperature of the fluid. In which case, the material derivative then describes the temperature change of a certain fluid parcel with time, as it flows along its pathline (trajectory). Other names There are many other names for the material derivative, including: *advective derivative *convective derivative *derivative following the motion *hydrodynamic derivative *Lagrangian derivative *particle derivative *substantial derivative *substantive derivative *Stokes derivative *total derivative, although the material derivative ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
