Clarke's Equation
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Clarke's Equation
In combustion, Clarke's equation is a third-order nonlinear partial differential equation, first derived by John Frederick Clarke in 1978.Clarke, J. F. (1982). "Non-steady Gas Dynamic Effects in the Induction Domain Behind a Strong Shock Wave", College of Aeronautics report. 8229, Cranfield Inst. of Tech. https://repository.tudelft.nl/view/aereports/uuid%3A9c064b5f-97b4-4527-a97e-a805d5e1abd7 The equation describes the thermal explosion process, including both effects of constant-volume and constant-pressure processes, as well as the effects of adiabatic and isothermal sound speeds. The equation reads as :(\theta_t-\gamma e^)_=(\theta_t-e^\theta)_ where \theta is the non-dimensional temperature perturbation and \gamma is the specific heat ratio In thermal physics and thermodynamics, the heat capacity ratio, also known as the adiabatic index, the ratio of specific heats, or Laplace's coefficient, is the ratio of the heat capacity at constant pressure () to heat capacity at cons ...
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Combustion
Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion does not always result in fire, because a flame is only visible when substances undergoing combustion vaporize, but when it does, a flame is a characteristic indicator of the reaction. While the activation energy must be overcome to initiate combustion (e.g., using a lit match to light a fire), the heat from a flame may provide enough energy to make the reaction self-sustaining. Combustion is often a complicated sequence of elementary radical reactions. Solid fuels, such as wood and coal, first undergo endothermic pyrolysis to produce gaseous fuels whose combustion then supplies the heat required to produce more of them. Combustion is often hot enough that incandescent light in the form of either glowing or a flame is produced. A ...
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Partial Differential Equation
In mathematics, a partial differential equation (PDE) is an equation which imposes relations between the various partial derivatives of a Multivariable calculus, multivariable function. The function is often thought of as an "unknown" to be solved for, similarly to how is thought of as an unknown number to be solved for in an algebraic equation like . However, it is usually impossible to write down explicit formulas for solutions of partial differential equations. There is, correspondingly, a vast amount of modern mathematical and scientific research on methods to Numerical methods for partial differential equations, numerically approximate solutions of certain partial differential equations using computers. Partial differential equations also occupy a large sector of pure mathematics, pure mathematical research, in which the usual questions are, broadly speaking, on the identification of general qualitative features of solutions of various partial differential equations, such a ...
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John Frederick Clarke
John Frederick Clarke FRS (1 May 1927 – 11 June 2013) was a professor, an aeronautical engineer, and a pilot. Biography After his schooling, he got training from Fleet Air Arm as a Navy Pilot and then from Royal Air force at Lossiemouth. He left Navy and worked few months at Armstrong Siddeley Motors, but his interest were in academics. Subsequently he quit the job and joined Queen Mary College in Aeronautical engineering course in 1949. He married Jean Gentle in 1953. His thesis advisor Norman A.V. Piercy died in 1953,Winny, H. F. (1953). Prof. NAV Piercy. Nature, 171(4353), 593-594. then he temporarily advised by Leslie G. Whitehead and then finally by Alec David Young. He received his PhD at Queen Mary College in 1957. He briefly worked for English Electric company from 1955 to 1957. In 1958 he joined Cranfield University as a lecturer and stayed there till 1991. After his retirement he continued to do research for a decade. His research interests were Shock waves, det ...
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Thermal Runaway
Thermal runaway describes a process that is accelerated by increased temperature, in turn releasing energy that further increases temperature. Thermal runaway occurs in situations where an increase in temperature changes the conditions in a way that causes a further increase in temperature, often leading to a destructive result. It is a kind of uncontrolled positive feedback. In chemistry (and chemical engineering), thermal runaway is associated with strongly exothermic reactions that are accelerated by temperature rise. In electrical engineering, thermal runaway is typically associated with increased current flow and power dissipation. Thermal runaway can occur in civil engineering, notably when the heat released by large amounts of curing concrete is not controlled. In astrophysics, runaway nuclear fusion reactions in stars can lead to nova and several types of supernova explosions, and also occur as a less dramatic event in the normal evolution of solar-mass stars, the " he ...
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Sound Speed
The speed of sound is the distance travelled per unit of time by a sound wave as it propagates through an elastic medium. At , the speed of sound in air is about , or one kilometre in or one mile in . It depends strongly on temperature as well as the medium through which a sound wave is propagating. At , the speed of sound in air is about . The speed of sound in an ideal gas depends only on its temperature and composition. The speed has a weak dependence on frequency and pressure in ordinary air, deviating slightly from ideal behavior. In colloquial speech, ''speed of sound'' refers to the speed of sound waves in air. However, the speed of sound varies from substance to substance: typically, sound travels most slowly in gases, faster in liquids, and fastest in solids. For example, while sound travels at in air, it travels at in water (almost 4.3 times as fast) and at in iron (almost 15 times as fast). In an exceptionally stiff material such as diamond, sound travels at , ...
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Biographical Memoirs Of Fellows Of The Royal Society
The ''Biographical Memoirs of Fellows of the Royal Society'' is an academic journal on the history of science published annually by the Royal Society. It publishes obituaries of Fellows of the Royal Society. It was established in 1932 as ''Obituary Notices of Fellows of the Royal Society'' and obtained its current title in 1955, with volume numbering restarting at 1. Prior to 1932, obituaries were published in the ''Proceedings of the Royal Society''. The memoirs are a significant historical record and most include a full bibliography of works by the subjects. The memoirs are often written by a scientist of the next generation, often one of the subject's own former students, or a close colleague. In many cases the author is also a Fellow. Notable biographies published in this journal include Albert Einstein, Alan Turing, Bertrand Russell, Claude Shannon, Clement Attlee, Ernst Mayr, and Erwin Schrödinger. Each year around 40 to 50 memoirs of deceased Fellows of the Royal Soci ...
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Specific Heat Ratio
In thermal physics and thermodynamics, the heat capacity ratio, also known as the adiabatic index, the ratio of specific heats, or Laplace's coefficient, is the ratio of the heat capacity at constant pressure () to heat capacity at constant volume (). It is sometimes also known as the ''isentropic expansion factor'' and is denoted by ( gamma) for an ideal gasγ first appeared in an article by the French mathematician, engineer, and physicist Siméon Denis Poisson: * On p. 332, Poisson defines γ merely as a small deviation from equilibrium which causes small variations of the equilibrium value of the density ρ. In Poisson's article of 1823 – * γ was expressed as a function of density D (p. 8) or of pressure P (p. 9). Meanwhile, in 1816 the French mathematician and physicist Pierre-Simon Laplace had found that the speed of sound depends on the ratio of the specific heats. * However, he didn't denote the ratio as γ. In 1825, Laplace stated that the speed of sound is ...
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Frank-Kamenetskii Theory
In combustion, Frank-Kamenetskii theory explains the Thermal runaway, thermal explosion of a homogeneous mixture of reactants, kept inside a closed vessel with constant temperature walls. It is named after a Russian scientist David A. Frank-Kamenetskii, who along with Nikolay Semyonov, Nikolay Semenov developed the theory in the 1930s. Problem description Sources: Consider a vessel maintained at a constant temperature T_o, containing a homogeneous reacting mixture. Let the characteristic size of the vessel be a. Since the mixture is homogeneous, the density \rho is constant. During the initial period of Combustion, ignition, the consumption of reactant concentration is negligible (see t_f and t_e below), thus the explosion is governed only by the energy equation. Assuming a one-step global reaction \text + \text \rightarrow \text + q, where q is the amount of heat released per unit mass of fuel consumed, and a reaction rate governed by Arrhenius law, the energy equation becomes ...
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Partial Differential Equations
In mathematics, a partial differential equation (PDE) is an equation which imposes relations between the various partial derivatives of a multivariable function. The function is often thought of as an "unknown" to be solved for, similarly to how is thought of as an unknown number to be solved for in an algebraic equation like . However, it is usually impossible to write down explicit formulas for solutions of partial differential equations. There is, correspondingly, a vast amount of modern mathematical and scientific research on methods to numerically approximate solutions of certain partial differential equations using computers. Partial differential equations also occupy a large sector of pure mathematical research, in which the usual questions are, broadly speaking, on the identification of general qualitative features of solutions of various partial differential equations, such as existence, uniqueness, regularity, and stability. Among the many open questions are the e ...
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Fluid Dynamics
In physics and engineering, fluid dynamics is a subdiscipline of fluid mechanics that describes the flow of fluids— liquids and gases. It has several subdisciplines, including ''aerodynamics'' (the study of air and other gases in motion) and hydrodynamics (the study of liquids in motion). Fluid dynamics has a wide range of applications, including calculating forces and moments on aircraft, determining the mass flow rate of petroleum through pipelines, predicting weather patterns, understanding nebulae in interstellar space and modelling fission weapon detonation. Fluid dynamics offers a systematic structure—which underlies these practical disciplines—that embraces empirical and semi-empirical laws derived from flow measurement and used to solve practical problems. The solution to a fluid dynamics problem typically involves the calculation of various properties of the fluid, such as flow velocity, pressure, density, and temperature, as functions of space and time. ...
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