Chrysotype
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Chrysotype
Chrysotype (also known as a chripotype or gold print) is a photographic process invented by John Herschel in 1842. Named from the Greek for "gold", it uses colloidal gold to record images on paper. Processes Herschel's process Herschel's system involved coating paper with ferric citrate, exposing it to the sun in contact with an etching used as mask, then developing the print with a chloroaurate solution. This did not provide continuous-tone photographs. In 2006, 164 years after Herschel's work with gold printing, photographers Liam Lawless and Robert Wolfgang Schramm published a formula based on Herschel's process. Processes based on ziatype Following the introduction of Richard Sullivan's ziatype process in 1997, which uses ammonium ferric oxalate to print out palladium Palladium is a chemical element with the symbol Pd and atomic number 46. It is a rare and lustrous silvery-white metal discovered in 1803 by the English chemist William Hyde Wollaston. He named ...
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Photographic Process
A list of photographic processing techniques. Color *Agfacolor **Ap-41 process (pre-1978 Agfa color slides; 1978-1983 was a transition period when Agfa slowly changed their color slide films from AP-41 to E6) *Anthotype *Autochrome Lumière, 1903 * Carbon print, 1862 *Chromogenic positive (Ektachrome) **E-3 process **E-4 process **E-6 process *Chromogenic negative **C-41 process **RA-4 process *Dufaycolor *Dye destruction **Cibachrome **Ilfochrome *Dye-transfer process *Finlaycolor *Heliochrome *Kinemacolor *Kodachrome **K-12 process **K-14 process *Lippmann plate, 1891 *One-light Black and white (monochrome) A * Abration tone *Acetate film *Albertype *Albumen print, 1850 * Algraphy *Ambrotype * Amphitype * Amylotype * Anaglyph *Anthotype * Anthrakotype * Archertype * Argentotype *Argyrotype *Aristo paper * Aristotype *Aristo * Artotype * Atrephograph * Atrograph *Aurotype *Autotype (photographic process) B * Barrieotype *Baryta coated paper *Bayard process * Bichromate proces ...
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John Herschel
Sir John Frederick William Herschel, 1st Baronet (; 7 March 1792 – 11 May 1871) was an English polymath active as a mathematician, astronomer, chemist, inventor, experimental photographer who invented the blueprint and did botanical work. Herschel originated the use of the Julian day system in astronomy. He named seven moons of Saturn and four moons of Uranus – the seventh planet, discovered by his father Sir William Herschel. He made many contributions to the science of photography, and investigated colour blindness and the chemical power of ultraviolet rays. His ''Preliminary Discourse'' (1831), which advocated an inductive approach to scientific experiment and theory-building, was an important contribution to the philosophy of science. Early life and work on astronomy Herschel was born in Slough, Buckinghamshire, the son of Mary Baldwin and astronomer William Herschel. He was the nephew of astronomer Caroline Herschel. He studied shortly at Eton College an ...
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Greek Language
Greek ( el, label=Modern Greek, Ελληνικά, Elliniká, ; grc, Ἑλληνική, Hellēnikḗ) is an independent branch of the Indo-European family of languages, native to Greece, Cyprus, southern Italy (Calabria and Salento), southern Albania, and other regions of the Balkans, the Black Sea coast, Asia Minor, and the Eastern Mediterranean. It has the longest documented history of any Indo-European language, spanning at least 3,400 years of written records. Its writing system is the Greek alphabet, which has been used for approximately 2,800 years; previously, Greek was recorded in writing systems such as Linear B and the Cypriot syllabary. The alphabet arose from the Phoenician script and was in turn the basis of the Latin, Cyrillic, Armenian, Coptic, Gothic, and many other writing systems. The Greek language holds a very important place in the history of the Western world. Beginning with the epics of Homer, ancient Greek literature includes many works of lasting impo ...
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Colloidal Gold
Colloidal gold is a sol or colloidal suspension of nanoparticles of gold in a fluid, usually water. The colloid is usually either wine-red coloured (for spherical particles less than 100  nm) or blue/purple (for larger spherical particles or nanorods). Due to their optical, electronic, and molecular-recognition properties, gold nanoparticles are the subject of substantial research, with many potential or promised applications in a wide variety of areas, including electron microscopy, electronics, nanotechnology, materials science, and biomedicine. The properties of colloidal gold nanoparticles, and thus their potential applications, depend strongly upon their size and shape. For example, rodlike particles have both a transverse and longitudinal absorption peak, and anisotropy of the shape affects their self-assembly. History Used since ancient times as a method of staining glass colloidal gold was used in the 4th-century Lycurgus Cup, which changes color dependin ...
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Ferric Citrate
Ferric citrate or iron(III) citrate describes any of several complexes formed upon binding any of the several conjugate bases derived from citric acid with ferric ions. Most of these complexes are orange or red-brown. They contain two or more Fe(III) centers. Ferric citrates contribute to the metabolism of iron by some organisms. Citrates, which are released by plant roots and by some microorganisms, can solubilize iron compounds in the soil. For example ferric hydroxide reacts with citrates to give form soluble complexes. This solubilization provides a pathway for the absorption of the ferric ions by various organisms. Ferric citrate is used in medicine to regulate the blood levels of iron in patients with chronic kidney disease on dialysis. It acts by forming an insoluble compound with phosphate present in the diet and thus minimizing its uptake by the digestive system. Structure Citrate forms a variety of coordination complexes with ferric ions.Xiang Hao, Yongge Wei, Sh ...
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Etching
Etching is traditionally the process of using strong acid or mordant to cut into the unprotected parts of a metal surface to create a design in intaglio (incised) in the metal. In modern manufacturing, other chemicals may be used on other types of material. As a method of printmaking, it is, along with engraving, the most important technique for old master prints, and remains in wide use today. In a number of modern variants such as microfabrication etching and photochemical milling it is a crucial technique in much modern technology, including circuit boards. In traditional pure etching, a metal plate (usually of copper, zinc or steel) is covered with a waxy ground which is resistant to acid. The artist then scratches off the ground with a pointed etching needle where the artist wants a line to appear in the finished piece, exposing the bare metal. The échoppe, a tool with a slanted oval section, is also used for "swelling" lines. The plate is then dipped in a bath of aci ...
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Chloroaurate
Chloroauric acid is an inorganic compound with the chemical formula . It forms hydrates . Both the trihydrate and tetrahydrate are known. Both are orange-yellow solids consisting of the planar anion. Often chloroauric acid is handled as a solution, such as those obtained by dissolution of gold in aqua regia. These solutions can be converted to other gold complexes or reduced to metallic gold or gold nanoparticles. Properties Structure The tetrahydrate crystallizes as and two water molecules. The oxidation state of gold in and anion is +3. The salts of (tetrachloroauric(III) acid) are tetrachloroaurates(III), containing anions (tetrachloroaurate(III) anions), which have square planar molecular geometry. The Au–Cl distances are around 2.28 Å. Other d8 complexes adopt similar structures, e.g. tetrachloroplatinate(II) . Solute properties Solid chloroauric acid is a hydrophilic ( ionic) protic solute. It is soluble in water and other oxygen-containing solvents, s ...
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Ammonium Ferric Oxalate
Ferric ammonium oxalate (ammonium ferrioxalate, ammonium tris(oxalato)ferrate) is the ammonium salt of the anionic trisoxalato coordination complex of iron(III). It is a precursor to iron oxides, diverse coordination polymers, and Prussian Blue. The latter behavior is relevant to the manufacture of blueprint paper. Ferric ammonium oxalate has also been used in the synthesis of superconducting salts with bis(ethylene)dithiotetrathiafulvalene (BEDT-TTF), see Organic superconductor. See also * Potassium ferrioxalate Potassium ferrioxalate, also called potassium trisoxalatoferrate or potassium tris(oxalato)ferrate(III) is a chemical compound with the formula []. It often occurs as the trihydrate . Both are crystalline compounds, lime green in colour.A. Sarith ... References External links * http://www.chemblink.com/products/13268-42-3.htm * http://chemicalland21.com/specialtychem/perchem/FERRIC%20AMMONIUM%20OXALATE.htm Ammonium compounds Iron(III) compounds Oxalato ...
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Palladium
Palladium is a chemical element with the symbol Pd and atomic number 46. It is a rare and lustrous silvery-white metal discovered in 1803 by the English chemist William Hyde Wollaston. He named it after the asteroid Pallas, which was itself named after the epithet of the Greek goddess Athena, acquired by her when she slew Pallas. Palladium, platinum, rhodium, ruthenium, iridium and osmium form a group of elements referred to as the platinum group metals (PGMs). They have similar chemical properties, but palladium has the lowest melting point and is the least dense of them. More than half the supply of palladium and its congener platinum is used in catalytic converters, which convert as much as 90% of the harmful gases in automobile exhaust (hydrocarbons, carbon monoxide, and nitrogen dioxide) into nontoxic substances (nitrogen, carbon dioxide and water vapor). Palladium is also used in electronics, dentistry, medicine, hydrogen purification, chemical applications, groundwate ...
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Ascorbate
Vitamin C (also known as ascorbic acid and ascorbate) is a water-soluble vitamin found in citrus and other fruits and vegetables, also sold as a dietary supplement and as a topical 'serum' ingredient to treat melasma (dark pigment spots) and wrinkles on the face. It is used to prevent and treat scurvy. Vitamin C is an essential nutrient involved in the repair of tissue, the formation of collagen, and the enzymatic production of certain neurotransmitters. It is required for the functioning of several enzymes and is important for immune system function. It also functions as an antioxidant. Most animals are able to synthesize their own vitamin C. However, apes (including humans) and monkeys (but not all primates), most bats, some rodents, and certain other animals must acquire it from dietary sources. There is some evidence that regular use of supplements may reduce the duration of the common cold, but it does not appear to prevent infection. It is unclear whether supplementa ...
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Mike Ware (photographer)
Michael J. Ware (born 1939, Bromley) is a chemist and photographer, known for his work in alternative photographic processes, earlier methods of printing photographic images that were succeeded by the more common silver-gelatin used today. In the Present, Ware acts as a consultant, most recently on the history and development of the platinotype and palladium processes. His has also written about chemistry's influence on the history of photography. Early life and education Ware was born in 1939 in Bromley. He earned his Ph.D. at the University of Oxford in 1965. His thesis was ''The vibrational spectra of some inorganic complexes.'' Awards and honours * 1982 Fellow of the Royal Society of Chemistry * 1990 Hood Medal The Royal Photographic Society of Great Britain, commonly known as the Royal Photographic Society (RPS), is one of the world's oldest photographic societies. It was founded in London, England, in 1853 as the Photographic Society of London with ..., awarded by t ...
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