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Chemical Looping Reforming And Gasification
Chemical looping reforming (CLR) and gasification (CLG) are the operations that involve the use of gaseous carbonaceous feedstock and solid carbonaceous feedstock, respectively, in their conversion to syngas in the chemical looping scheme. The typical gaseous carbonaceous feedstocks used are natural gas and reducing tail gas, while the typical solid carbonaceous feedstocks used are coal and biomass Biomass is plant-based material used as a fuel for heat or electricity production. It can be in the form of wood, wood residues, energy crops, agricultural residues, and waste from industry, farms, and households. Some people use the terms bi .... The feedstocks are partially oxidized to generate syngas using metal oxide oxygen carriers as the oxidant. The reduced metal oxide is then oxidized in the regeneration step using air. The syngas is an important intermediate for generation of such diverse products as electricity, chemicals, hydrogen, and liquid fuels. The motivation for de ...
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Syngas
Syngas, or synthesis gas, is a mixture of hydrogen and carbon monoxide, in various ratios. The gas often contains some carbon dioxide and methane. It is principly used for producing ammonia or methanol. Syngas is combustible and can be used as a fuel. Historically, it has been used as a replacement for gasoline, when gasoline supply has been limited; for example, wood gas was used to power cars in Europe during WWII (in Germany alone half a million cars were built or rebuilt to run on wood gas). Production Syngas is produced by steam reforming or partial oxidation of natural gas or liquid hydrocarbons, or coal gasification. Steam reforming of methane is an endothermic reaction requiring 206 kJ/mol of methane: : In principle, but rarely in practice, biomass and related hydrocarbon feedstocks could be used to generate biogas and biochar in waste-to-energy gasification facilities. The gas generated (mostly methane and carbon dioxide) is sometimes described as ''syngas'' but its co ...
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CLR Fig 4
CLR may refer to: * Calcium Lime Rust, a household cleaning-product * California Law Review, a publication by the UC Berkeley School of Law * Centerline Radius, a term in the tubing industry used to describe the radius of a bend * Central London Railway, an underground railway line in London - now the central part of the London Underground's Central line * Chief Langalibalele Rifles, an infantry regiment of the South African Army * Cliff Hatfield Memorial Airport, an airport in Calipatria, California * CLR (formerly Computer Language Research), a subsidiary of Thomson Reuters Tax & Accounting * Coffee leaf rust, a plant disease caused by the fungus ''Hemileia vastatrix'' * Combat Logistics Regiment, a type of United States Marine Corps regiment * Command, Leadership, Resource management, another acronym for Cockpit Resource Management * Commando Logistic Regiment, a logistic regiment of the Royal Marines * Commonwealth Law Reports, reports of decisions of the High Court of Austral ...
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Chemical Process Engineering
A chemical substance is a form of matter having constant chemical composition and characteristic properties. Some references add that chemical substance cannot be separated into its constituent elements by physical separation methods, i.e., without breaking chemical bonds. Chemical substances can be simple substances (substances consisting of a single chemical element), chemical compounds, or alloys. Chemical substances are often called 'pure' to set them apart from mixtures. A common example of a chemical substance is pure water; it has the same properties and the same ratio of hydrogen to oxygen whether it is isolated from a river or made in a laboratory. Other chemical substances commonly encountered in pure form are diamond (carbon), gold, table salt (sodium chloride) and refined sugar (sucrose). However, in practice, no substance is entirely pure, and chemical purity is specified according to the intended use of the chemical. Chemical substances exist as solids, liquids, g ...
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Chemical Processes
A chemical substance is a form of matter having constant chemical composition and characteristic properties. Some references add that chemical substance cannot be separated into its constituent elements by physical separation methods, i.e., without breaking chemical bonds. Chemical substances can be simple substances (substances consisting of a single chemical element), chemical compounds, or alloys. Chemical substances are often called 'pure' to set them apart from mixtures. A common example of a chemical substance is pure water; it has the same properties and the same ratio of hydrogen to oxygen whether it is isolated from a river or made in a laboratory. Other chemical substances commonly encountered in pure form are diamond (carbon), gold, table salt ( sodium chloride) and refined sugar ( sucrose). However, in practice, no substance is entirely pure, and chemical purity is specified according to the intended use of the chemical. Chemical substances exist as solids, liqu ...
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Chemical Looping Technologies
A chemical substance is a form of matter having constant chemical composition and characteristic properties. Some references add that chemical substance cannot be separated into its constituent elements by physical separation methods, i.e., without breaking chemical bonds. Chemical substances can be simple substances (substances consisting of a single chemical element), chemical compounds, or alloys. Chemical substances are often called 'pure' to set them apart from mixtures. A common example of a chemical substance is pure water; it has the same properties and the same ratio of hydrogen to oxygen whether it is isolated from a river or made in a laboratory. Other chemical substances commonly encountered in pure form are diamond (carbon), gold, table salt (sodium chloride) and refined sugar (sucrose). However, in practice, no substance is entirely pure, and chemical purity is specified according to the intended use of the chemical. Chemical substances exist as solids, liquids, g ...
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Oxidative Coupling Of Methane
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a decrease in the oxidation state. There are two classes of redox reactions: * ''Electron-transfer'' – Only one (usually) electron flows from the reducing agent to the oxidant. This type of redox reaction is often discussed in terms of redox couples and electrode potentials. * ''Atom transfer'' – An atom transfers from one substrate to another. For example, in the rusting of iron, the oxidation state of iron atoms increases as the iron converts to an oxide, and simultaneously the oxidation state of oxygen decreases as it accepts electrons released by the iron. Although oxidation reactions are commonly associated with the formation of oxides, other chemical species can serve the same function. In hydrogenation, C=C (and other) bonds ar ...
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Maleic Anhydride
Maleic anhydride is an organic compound with the formula C2H2(CO)2O. It is the acid anhydride of maleic acid. It is a colorless or white solid with an acrid odor. It is produced industrially on a large scale for applications in coatings and polymers. Production Maleic anhydride is produced by vapor-phase oxidation of ''n''-butane. The overall process converts the methyl groups to carboxylate and dehydrogenates the backbone. The selectivity of the process reflects the robustness of maleic anhydride, with its conjugated double-bond system. Traditionally maleic anhydride was produced by the oxidation of benzene or other aromatic compounds. As of 2006, only a few smaller plants continue to use benzene. In both cases, benzene and butane are fed into a stream of hot air, and the mixture is passed through a catalyst bed at high temperature. The ratio of air to hydrocarbon is controlled to prevent the mixture from igniting. Vanadium pentoxide and molybdenum trioxide are the catalysts ...
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CLR Fig 6
CLR may refer to: * Calcium Lime Rust, a household cleaning-product * California Law Review, a publication by the UC Berkeley School of Law * Centerline Radius, a term in the tubing industry used to describe the radius of a bend * Central London Railway, an underground railway line in London - now the central part of the London Underground's Central line * Chief Langalibalele Rifles, an infantry regiment of the South African Army * Cliff Hatfield Memorial Airport, an airport in Calipatria, California * CLR (formerly Computer Language Research), a subsidiary of Thomson Reuters Tax & Accounting * Coffee leaf rust, a plant disease caused by the fungus ''Hemileia vastatrix'' * Combat Logistics Regiment, a type of United States Marine Corps regiment * Command, Leadership, Resource management, another acronym for Cockpit Resource Management * Commando Logistic Regiment, a logistic regiment of the Royal Marines * Commonwealth Law Reports, reports of decisions of the High Court of Austral ...
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Pyrolysis
The pyrolysis (or devolatilization) process is the thermal decomposition of materials at elevated temperatures, often in an inert atmosphere. It involves a change of chemical composition. The word is coined from the Greek-derived elements ''pyro'' "fire", "heat", "fever" and '' lysis'' "separating". Pyrolysis is most commonly used in the treatment of organic materials. It is one of the processes involved in charring wood.''Burning of wood''
, InnoFireWood's website. Accessed on 2010-02-06.
In general, pyrolysis of organic substances produces volatile products and leaves , a carbon-rich solid residue. Extreme pyrolysis, which leaves mostly

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Fluidized Bed
A fluidized bed is a physical phenomenon that occurs when a solid particulate substance (usually present in a holding vessel) is under the right conditions so that it behaves like a fluid. The usual way to achieve a fluidize bed is to pump pressurized fluid into the particles. The resulting medium then has many properties and characteristics of normal fluids, such as the ability to free-flow under gravity, or to be pumped using fluid technologies. The resulting phenomenon is called fluidization. Fluidized beds are used for several purposes, such as fluidized bed reactors (types of chemical reactors), solids separation, fluid catalytic cracking, fluidized bed combustion, heat or mass transfer or interface modification, such as applying a coating onto solid items. This technique is also becoming more common in aquaculture for the production of shellfish in integrated multi-trophic aquaculture systems. Properties A fluidized bed consists of fluid-solid mixture that exhibits fluid-l ...
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Fischer–Tropsch Process
The Fischer–Tropsch process is a collection of chemical reactions that converts a mixture of carbon monoxide and hydrogen, known as syngas, into liquid hydrocarbons. These reactions occur in the presence of metal catalysts, typically at temperatures of and pressures of one to several tens of atmospheres. The process was first developed by Franz Fischer and Hans Tropsch at the Kaiser Wilhelm Institute for Coal Research in Mülheim an der Ruhr, Germany, in 1925. As a premier example of C1 chemistry, the Fischer–Tropsch process is an important reaction in both coal liquefaction and gas to liquids technology for producing liquid hydrocarbons. In the usual implementation, carbon monoxide and hydrogen, the feedstocks for FT, are produced from coal, natural gas, or biomass in a process known as gasification. The process then converts these gases into synthetic oil, synthetic lubrication oil and synthetic fuel. This process has received intermittent attention as a source of low-s ...
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Autothermal Reforming
Steam reforming or steam methane reforming (SMR) is a method for producing syngas (hydrogen and carbon monoxide) by reaction of hydrocarbons with water. Commonly natural gas is the feedstock. The main purpose of this technology is hydrogen production. The reaction is represented by this equilibrium: :CH4 + H2O CO + 3 H2 The reaction is strongly endothermic (Δ''H''SR = 206 kJ/mol). Hydrogen produced by steam reforming is termed 'grey hydrogen' when the waste carbon monoxide is released to the atmosphere and 'blue hydrogen' when the carbon monoxide is (mostly) captured and stored geologically - see carbon capture and storage. Zero carbon 'green' hydrogen is produced by thermochemical water splitting, using solar thermal, low- or zero-carbon electricity or waste heat, or electrolysis, using low- or zero-carbon electricity. Zero carbon emissions 'turquoise' hydrogen is produced by one-step methane pyrolysis of natural gas. Steam reforming of natural gas produces most of the world ...
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