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CdTe
Cadmium telluride (CdTe) is a stable crystalline compound formed from cadmium and tellurium. It is mainly used as the semiconducting material in cadmium telluride photovoltaics and an infrared optical window. It is usually sandwiched with cadmium sulfide to form a p–n junction solar PV cell. Applications CdTe is used to make thin film solar cells, accounting for about 8% of all solar cells installed in 2011. They are among the lowest-cost types of solar cell, although a comparison of total installed cost depends on installation size and many other factors, and has changed rapidly from year to year. The CdTe solar cell market is dominated by First Solar. In 2011, around 2 GWp of CdTe solar cells were produced; For more details and discussion see cadmium telluride photovoltaics. CdTe can be alloyed with mercury to make a versatile infrared detector material ( HgCdTe). CdTe alloyed with a small amount of zinc makes an excellent solid-state X-ray and gamma ray de ...
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Cadmium Telluride Photovoltaics
Cadmium telluride (CdTe) photovoltaics is a photovoltaic (PV) technology based on the use of cadmium telluride in a thin semiconductor layer designed to absorb and convert sunlight into electricity. Cadmium telluride PV is the only thin film technology with lower costs than conventional solar cells made of crystalline silicon in multi-kilowatt systems.K. Zweibel, J. Mason, V. Fthenakis,A Solar Grand Plan, ''Scientific American'', Jan 2008. CdTe PV is the cheapest example of PV technologies and prices are about 16¢/kWh with US Southwest sunlight. , on a lifecycle basis, CdTe PV has the smallest carbon footprint, lowest water use and shortest energy payback time of any current photo voltaic technology. CdTe's energy payback time of less than a year allows for faster carbon reductions without short-term energy deficits. The toxicity of cadmium is an environmental concern during production and when the panels are disposed of. Some of this might be mitigated by recycling of C ...
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Thin Film Solar Cell
A thin-film solar cell is a second generation solar cell that is made by depositing one or more thin layers, or thin film (TF) of photovoltaic material on a substrate, such as glass, plastic or metal. Thin-film solar cells are commercially used in several technologies, including cadmium telluride (CdTe), copper indium gallium diselenide (CIGS), and amorphous thin-film silicon (a-Si, TF-Si). Film thickness varies from a few nanometers ( nm) to tens of micrometers (µm), much thinner than thin-film's rival technology, the conventional, first-generation crystalline silicon solar cell (c-Si), that uses wafers of up to 200 µm thick. This allows thin film cells to be flexible, and lower in weight. It is used in building-integrated photovoltaics and as semi- transparent, photovoltaic glazing material that can be laminated onto windows. Other commercial applications use rigid thin film solar panels (interleaved between two panes of glass) in some of the world's largest ph ...
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First Solar
First Solar, Inc. is an American manufacturer of solar panels, and a provider of utility-scale PV power plants and supporting services that include finance, construction, maintenance and end-of-life panel recycling. First Solar uses rigid thin-film modules for its solar panels, and produces CdTe panels using cadmium telluride (CdTe) as a semiconductor. The company was founded in 1990 by inventor Harold McMaster as Solar Cells, Inc. and the Florida Corporation in 1993 with JD Polk. In 1999 it was purchased by True North Partners, LLC, who rebranded it as First Solar, Inc. The company went public in 2006, trading on the NASDAQ. Its current chief executive is Mark Widmar, who succeeded the previous CEO James Hughes July 1, 2016. First Solar is based in Tempe, Arizona. In 2009, First Solar became the first solar panel manufacturing company to lower its manufacturing cost to $1 per watt. As of 2010, First Solar was considered the second-largest maker of PV modules worldwide ...
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Infrared
Infrared (IR), sometimes called infrared light, is electromagnetic radiation (EMR) with wavelengths longer than those of visible light. It is therefore invisible to the human eye. IR is generally understood to encompass wavelengths from around 1  millimeter (300  GHz) to the nominal red edge of the visible spectrum, around 700 nanometers (430  THz). Longer IR wavelengths (30 μm-100 μm) are sometimes included as part of the terahertz radiation range. Almost all black-body radiation from objects near room temperature is at infrared wavelengths. As a form of electromagnetic radiation, IR propagates energy and momentum, exerts radiation pressure, and has properties corresponding to both those of a wave and of a particle, the photon. It was long known that fires emit invisible heat; in 1681 the pioneering experimenter Edme Mariotte showed that glass, though transparent to sunlight, obstructed radiant heat. In 1800 the astronomer Sir William Herschel ...
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Tellurium
Tellurium is a chemical element with the symbol Te and atomic number 52. It is a brittle, mildly toxic, rare, silver-white metalloid. Tellurium is chemically related to selenium and sulfur, all three of which are chalcogens. It is occasionally found in native form as elemental crystals. Tellurium is far more common in the Universe as a whole than on Earth. Its extreme rarity in the Earth's crust, comparable to that of platinum, is due partly to its formation of a volatile hydride that caused tellurium to be lost to space as a gas during the hot nebular formation of Earth.Anderson, Don L.; "Chemical Composition of the Mantle" in ''Theory of the Earth'', pp. 147-175 Tellurium-bearing compounds were first discovered in 1782 in a gold mine in Kleinschlatten, Transylvania (now Zlatna, Romania) by Austrian mineralogist Franz-Joseph Müller von Reichenstein, although it was Martin Heinrich Klaproth who named the new element in 1798 after the Latin 'earth'. Gold telluride minera ...
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Zinc Telluride
Zinc telluride is a binary chemical compound with the formula ZnTe. This solid is a semiconductor material with a direct band gap of 2.26 eV. It is usually a p-type semiconductor. Its crystal structure is cubic, like that for sphalerite and diamond. Properties ZnTe has the appearance of grey or brownish-red powder, or ruby-red crystals when refined by sublimation. Zinc telluride typically had a cubic (sphalerite, or "zincblende") crystal structure, but can be also prepared as rocksalt crystals or in hexagonal crystals (wurtzite structure). Irradiated by a strong optical beam burns in presence of oxygen. Its lattice constant is 0.6101 nm, allowing it to be grown with or on aluminium antimonide, gallium antimonide, indium arsenide, and lead selenide. With some lattice mismatch, it can also be grown on other substrates such as GaAs, and it can be grown in thin-film polycrystalline (or nanocrystalline) form on substrates such as glass, for example, in the manufacture of thi ...
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Cadmium
Cadmium is a chemical element with the symbol Cd and atomic number 48. This soft, silvery-white metal is chemically similar to the two other stable metals in group 12, zinc and mercury. Like zinc, it demonstrates oxidation state +2 in most of its compounds, and like mercury, it has a lower melting point than the transition metals in groups 3 through 11. Cadmium and its congeners in group 12 are often not considered transition metals, in that they do not have partly filled ''d'' or ''f'' electron shells in the elemental or common oxidation states. The average concentration of cadmium in Earth's crust is between 0.1 and 0.5 parts per million (ppm). It was discovered in 1817 simultaneously by Stromeyer and Hermann, both in Germany, as an impurity in zinc carbonate. Cadmium occurs as a minor component in most zinc ores and is a byproduct of zinc production. Cadmium was used for a long time as a corrosion-resistant plating on steel, and cadmium compounds are used as red, ora ...
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Infrared Detector
An infrared detector is a detector that reacts to infrared (IR) radiation. The two main types of detectors are thermal and photonic (photodetectors). The thermal effects of the incident IR radiation can be followed through many temperature dependent phenomena. Bolometers and microbolometers are based on changes in resistance. Thermocouples and thermopiles use the thermoelectric effect. Golay cells follow thermal expansion. In IR spectrometers the pyroelectric detectors are the most widespread. The response time and sensitivity of photonic detectors can be much higher, but usually these have to be cooled to cut thermal noise. The materials in these are semiconductors with narrow band gaps. Incident IR photons can cause electronic excitations. In photoconductive detectors, the resistivity of the detector element is monitored. Photovoltaic detectors contain a p-n junction on which photoelectric current appears upon illumination. An infrared detector is hybridized by connect ...
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Electro-optic Effect
Electro–optics is a branch of electrical engineering, electronic engineering, materials science, and material physics involving components, electronic devices such as lasers, laser diodes, LEDs, waveguides, etc. which operate by the propagation and interaction of light with various tailored materials. It is closely related to the branch of optics, involving application of generation of photons, called photonics. It is not only concerned with the " electro–optic effect", since it deals with the interaction between the electromagnetic (optical) and the electrical ( electronic) states of materials. Electro-optical devices The electro-optic effect is a change in the optical properties of an optically active material due to interaction with light. This interaction usually results in a change in the birefringence, and not simply the refractive index of the medium. In a Kerr cell, the change in birefringence is proportional to the square of the optical electric field, and t ...
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Electro-optic Modulator
An electro-optic modulator (EOM) is an optical device in which a signal-controlled element exhibiting an electro-optic effect is used to modulate a beam of light. The modulation may be imposed on the phase, frequency, amplitude, or polarization of the beam. Modulation bandwidths extending into the gigahertz range are possible with the use of laser-controlled modulators. The electro-optic effect is the change in the refractive index of a material resulting from the application of a DC or low-frequency electric field. This is caused by forces that distort the position, orientation, or shape of the molecules constituting the material. Generally, a nonlinear optical material (organic polymers have the fastest response rates, and thus are best for this application) with an incident static or low frequency optical field will see a modulation of its refractive index. The simplest kind of EOM consists of a crystal, such as lithium niobate (LiNbO3), whose refractive index is a function ...
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Lens (optics)
A lens is a transmissive optical device which focuses or disperses a light beam by means of refraction. A simple lens consists of a single piece of transparent material, while a compound lens consists of several simple lenses (''elements''), usually arranged along a common axis. Lenses are made from materials such as glass or plastic, and are ground and polished or molded to a desired shape. A lens can focus light to form an image, unlike a prism, which refracts light without focusing. Devices that similarly focus or disperse waves and radiation other than visible light are also called lenses, such as microwave lenses, electron lenses, acoustic lenses, or explosive lenses. Lenses are used in various imaging devices like telescopes, binoculars and cameras. They are also used as visual aids in glasses to correct defects of vision such as myopia and hypermetropia. History The word '' lens'' comes from '' lēns'', the Latin name of the lentil (a seed of a ...
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Cadmium Zinc Telluride
Cadmium zinc telluride, (CdZnTe) or CZT, is a compound of cadmium, zinc and tellurium or, more strictly speaking, an alloy of cadmium telluride and zinc telluride. A direct bandgap semiconductor, it is used in a variety of applications, including semiconductor radiation detectors, photorefractive gratings, electro-optic modulators, solar cells, and terahertz generation and detection. The band gap varies from approximately 1.4 to 2.2 eV, depending on composition. Radiation detectors using CZT can operate in direct-conversion (or photoconductive) mode at room temperature, unlike some other materials (particularly germanium) which require cooling. Their relative advantages include high sensitivity for X-rays and gamma rays, due to the high atomic numbers of Cd and Te, and better energy resolution than scintillator detectors. CZT can be formed into different shapes for different radiation-detecting applications, and a variety of electrode geometries, such as coplanar grids and ...
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