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Catecholate
Catechol ( or ), also known as pyrocatechol or 1,2-dihydroxybenzene, is a toxic organic compound with the molecular formula . It is the ''ortho'' isomer of the three isomeric benzenediols. This colorless compound occurs naturally in trace amounts. It was first discovered by destructive distillation of the plant extract catechin. About 20,000 tonnes of catechol are now synthetically produced annually as a commodity organic chemical, mainly as a precursor to pesticides, flavors, and fragrances. Catechol occurs as feathery white crystals that are very rapidly soluble in water. Isolation and synthesis Catechol was first isolated in 1839 by Edgar Hugo Emil Reinsch (1809–1884) by Distillation, distilling it from the solid Tannin, tannic preparation catechin, which is the residuum of catechu, the boiled or concentrated juice of ''Mimosa catechu'' (''Acacia catechu''). Upon heating catechin above its decomposition point, a substance that Reinsch first named ''Brenz-Katechusäure'' (b ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Catechin
Catechin is a flavan-3-ol, a type of secondary metabolite providing antioxidant roles in plants. It belongs to the subgroup of polyphenols called flavonoids. The name of the catechin chemical family derives from ''catechu'', which is the tannic juice or boiled extract of ''Mimosa catechu'' (''Acacia catechu'' L.f). Chemistry Catechin possesses two benzene rings (called the A- and B-rings) and a dihydropyran heterocycle (the C-ring) with a hydroxyl group on carbon 3. The A-ring is similar to a resorcinol moiety while the B-ring is similar to a catechol moiety. There are two chiral centers on the molecule on carbons 2 and 3. Therefore, it has four diastereoisomers. Two of the isomers are in trans configuration and are called ''catechin'' and the other two are in cis configuration and are called ''epicatechin''. The most common catechin isomer is (+)-catechin. The other stereoisomer is (-)-catechin or ''ent''-catechin. The most common epicatechin isomer is (-)-epicatech ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tannin
Tannins (or tannoids) are a class of astringent, polyphenolic biomolecules that bind to and precipitate proteins and various other organic compounds including amino acids and alkaloids. The term ''tannin'' (from Anglo-Norman ''tanner'', from Medieval Latin ''tannāre'', from ''tannum'', oak bark) refers to the use of oak and other bark in tanning animal hides into leather. By extension, the term ''tannin'' is widely applied to any large polyphenolic compound containing sufficient hydroxyls and other suitable groups (such as carboxyls) to form strong complexes with various macromolecules. The tannin compounds are widely distributed in many species of plants, where they play a role in protection from predation (acting as pesticides) and might help in regulating plant growth. The astringency from the tannins is what causes the dry and puckery feeling in the mouth following the consumption of unripened fruit, red wine or tea. Likewise, the destruction or modification of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Beech
Beech (''Fagus'') is a genus of deciduous trees in the family Fagaceae, native to temperate Europe, Asia, and North America. Recent classifications recognize 10 to 13 species in two distinct subgenera, ''Engleriana'' and ''Fagus''. The ''Engleriana'' subgenus is found only in East Asia, distinctive for its low branches, often made up of several major trunks with yellowish bark. The better known ''Fagus'' subgenus beeches are high-branching with tall, stout trunks and smooth silver-grey bark. The European beech ('' Fagus sylvatica'') is the most commonly cultivated. Beeches are monoecious, bearing both male and female flowers on the same plant. The small flowers are unisexual, the female flowers borne in pairs, the male flowers wind-pollinating catkins. They are produced in spring shortly after the new leaves appear. The fruit of the beech tree, known as beechnuts or mast, is found in small burrs that drop from the tree in autumn. They are small, roughly triangular, and edib ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pterocarpus Marsupium
''Pterocarpus marsupium'', also known as Malabar kino, Indian kino, Vijayasar, or Venkai is a medium to large, deciduous tree that can grow up to tall. It is native to India (where it occurs in parts of the Western Ghats in the Karnataka-Kerala region and in the forests of Central India), Nepal, and Sri Lanka. File:Pterocarpus marsupium bark.jpg, ''Pterocarpus marsupium'' bark File:Pterocarpus marsupium 1.jpg, ''Pterocarpus marsupium'' tree File:Pterocarpus marsupium seeds - Kunming Botanical Garden - DSC03234.JPG, ''Pterocarpus marsupium'' seeds (Kunming Botanical Garden Kunming Institute of Botany, or KIB (), founded in 1938, is a research institution in the field of Botany, which is located in Kunming, the capital of Yunnan Province, China. The Institute is one of the major herbariums in China and maintains a co ...) References External links marsupium Flora of the Indian subcontinent {{Dalbergieae-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Journal Of The Chemical Society
The ''Journal of the Chemical Society'' was a scientific journal established by the Chemical Society in 1849 as the ''Quarterly Journal of the Chemical Society''. The first editor was Edmund Ronalds. The journal underwent several renamings, splits, and mergers throughout its history. In 1980, the Chemical Society merged with several other organizations into the Royal Society of Chemistry. The journal's continuity is found in '' Chemical Communications'', ''Dalton Transactions'', '' Faraday Transactions'', and '' Perkin Transactions'', all of which are published by the Royal Society of Chemistry. History ;''Proceedings of the Chemical Society'' * ''Memoirs of the Chemical Society of London'' (1841) * ''Proceedings of the Chemical Society of London'' (1842–1843) * ''Memoirs and Proceedings of the Chemical Society'' (1843–1848) * ''Proceedings of the Chemical Society, London'' (1885–1914) * Published as a supplement to ''Journal of the Chemical Society'' from 1914 to 1956 * '' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Diol
A diol is a chemical compound containing two hydroxyl groups ( groups). An aliphatic diol is also called a glycol. This pairing of functional groups is pervasive, and many subcategories have been identified. The most common industrial diol is ethylene glycol. Examples of diols in which the hydroxyl functional groups are more widely separated include 1,4-butanediol and propylene-1,3-diol, or beta propylene glycol, . Synthesis of classes of diols Geminal diols A geminal diol has two hydroxyl groups bonded to the same atom. These species arise by hydration of the carbonyl compounds. The hydration is usually unfavorable, but a notable exception is formaldehyde which, in water, exists in equilibrium with methanediol H2C(OH)2. Another example is (F3C)2C(OH)2, the hydrated form of hexafluoroacetone. Many gem-diols undergo further condensation to give dimeric and oligomeric derivatives. This reaction applies to glyoxal and related aldehydes. Vicinal diols In a vicinal diol, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
August Kekulé
Friedrich August Kekulé, later Friedrich August Kekule von Stradonitz ( , ; 7 September 1829 – 13 July 1896), was a German organic chemist. From the 1850s until his death, Kekulé was one of the most prominent chemists in Europe, especially in theoretical chemistry. He was the principal founder of the theory of chemical structure and in particular the Kekulé structure of benzene. Name Kekulé never used his first given name; he was known throughout his life as August Kekulé. After he was ennobled by the Kaiser in 1895, he adopted the name August Kekule von Stradonitz, without the French acute accent over the second "e". The French accent had apparently been added to the name by Kekulé's father during the Napoleonic occupation of Hesse by France, to ensure that French-speaking people pronounced the third syllable. Early years The son of a civil servant, Kekulé was born in Darmstadt, the capital of the Grand Duchy of Hesse. After graduating from secondary school (the Grand ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Otto Linné Erdmann
Otto Linné Erdmann (11 April 1804 – 9 October 1869) was a German chemist. He was the son of Karl Gottfried Erdmann, the physician who introduced vaccination into Saxony. He was born in Dresden on 11 April 1804. In 1820 he began to attend the medico-chirurgical academy of his native place, and in 1822 he entered the University of Leipzig, where in 1827 he became an associate professor, and in 1830 a full professor of chemistry. This office he held until his death, which happened at Leipzig on 9 October 1869. He was particularly successful as a teacher, and the laboratory established at Leipzig under his direction in 1843 was long regarded as a model institution. As an investigator he is best known for his work on nickel and indigo and other dye-stuffs. With R. F. Marchand (1813–1850) he also carried out a number of determinations of atomic weights. In 1828 he founded the ''Journal für technische und ökonomische Chemie'', which became in 1834 the ''Journal für praktische ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Philosophical Magazine
The ''Philosophical Magazine'' is one of the oldest scientific journals published in English. It was established by Alexander Tilloch in 1798;John Burnett"Tilloch, Alexander (1759–1825)" Oxford Dictionary of National Biography, Oxford University Press, Sept 2004; online edn, May 2006, accessed 17 Feb 2010 in 1822 Richard Taylor became joint editor and it has been published continuously by Taylor & Francis ever since. Early history The name of the journal dates from a period when "natural philosophy" embraced all aspects of science. The very first paper published in the journal carried the title "Account of Mr Cartwright's Patent Steam Engine". Other articles in the first volume include "Methods of discovering whether Wine has been adulterated with any Metals prejudicial to Health" and "Description of the Apparatus used by Lavoisier to produce Water from its component Parts, Oxygen and Hydrogen". 19th century Early in the nineteenth century, classic papers by Humphry Davy, M ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Wilhelm Heinrich Wackenroder
Wilhelm Heinrich Wackenroder (13 July 1773 – 13 February 1798) was a German jurist and writer. With Ludwig Tieck and the Schlegel brothers, he has co-founded the German Romanticism. Life Wackenroder was born in Berlin. He was a close friend of Tieck from youth until his early death. They collaborated on virtually everything they wrote in this period. Wackenroder probably made substantial contributions to Tieck's novel ''Franz Sternbalds Wanderungen'' (''Franz Sternbald’s Wanderings,'' 1798), and Tieck to Wackenroder's influential collection of essays, ''Herzensergießungen eines kunstliebenden Klosterbruders'' (''Outpourings of an Art-Loving Friar,'' 1797). ''Outpourings'' is a tribute to Renaissance and medieval literature and art, attributing to them a sense of emotion Wackenroder and Tieck felt was missing in German Enlightenment thought. It was also the first work to claim for Northern Renaissance art a status equivalent to that of the Italian Renaissance, at lea ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Flavan-3-ol
Flavan-3-ols (sometimes referred to as flavanols) are a subgroup of flavonoids. They are derivatives of flavans that possess a 2-phenyl-3,4-dihydro-2''H''-chromen-3-ol skeleton. Flavan-3-ols are structurally diverse and include a range of compounds, such as catechin, epicatechin gallate, epigallocatechin, epigallocatechin gallate, proanthocyanidins, theaflavins, thearubigins. They are found in most plants and have a role in plant defense. Chemical structure The single-molecule (monomer) catechin, or isomer epicatechin (see diagram), adds four hydroxyls to flavan-3-ol, making building blocks for concatenated polymers ( proanthocyanidins) and higher order polymers ( anthocyanidins). Flavan-3-ols possess two chiral carbons, meaning four diastereoisomers occur for each of them. They are distinguished from the yellow, ketone-containing flavonoids such as quercitin and rutin, which are called flavonols. Early use of the term bioflavonoid was imprecisely applied to include t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Efflorescence
In chemistry, efflorescence (which means "to flower out" in French) is the migration of a salt to the surface of a porous material, where it forms a coating. The essential process involves the dissolving of an internally held salt in water, or occasionally in another solvent. The water, with the salt now held in solution, migrates to the surface, then evaporates, leaving a coating of the salt. In what has been described as "primary efflorescence", the water is the invader and the salt was already present internally, and a reverse process, where the salt is originally present externally and is then carried inside in solution, is referred to as "secondary efflorescence". Efflorescences can occur in natural and built environments. On porous construction materials it may present a cosmetic outer problem only (primary efflorescence causing staining), but can sometimes indicate internal structural weakness (migration/degradation of component materials). Efflorescence may clog the p ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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