Carrier Multiplication
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Carrier Multiplication
In solar cell research, carrier multiplication is the phenomenon wherein the absorption of a single photon leads to the excitation of multiple electrons from the valence band to conduction band. In the theory of a conventional solar cell, each photon is only able to excite one electron across the band gap of the semiconductor, and any excess energy in that photon is dissipated as heat. In a material with carrier multiplication, high-energy photons excite on average more than one electron across the band gap, and so in principle the solar cell can produce more useful work. In quantum dot solar cells, the excited electron in the conduction band interacts with the hole it leaves behind in the valence band, and this composite uncharged object is known as an exciton. The carrier multiplication effect in a dot can be understood as creating multiple excitons, and is called multiple exciton generation (MEG). MEG may considerably increase the energy conversion efficiency of nanocrystal ...
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Quantum Beats
In physics, quantum beats are simple examples of phenomena that cannot be described by semiclassical theory, but can be described by fully quantized calculation, especially quantum electrodynamics. In semiclassical theory (SCT), there is an interference or beat note term for both V-type and \Lambda-type atoms. However, in the quantum electrodynamic (QED) calculation, V-type atoms have a beat term but \Lambda-types do not. This is strong evidence in support of quantum electrodynamics. Historical overview The observation of quantum beats was first reported by A.T. Forrester, R.A. Gudmundsen and P.O. Johnson in 1955, in an experiment that was performed on the basis of an earlier proposal by A.T. Forrester, W.E. Parkins and E. Gerjuoy. This experiment involved the mixing of the Zeeman components of ordinary incoherent light, that is, the mixing of different components resulting from a split of the spectral line into several components in the presence of a magnetic field due to the Ze ...
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Graphene
Graphene () is an allotrope of carbon consisting of a single layer of atoms arranged in a hexagonal lattice nanostructure.
"Carbon nanostructures for electromagnetic shielding applications", Mohammed Arif Poothanari, Sabu Thomas, et al., ''Industrial Applications of Nanomaterials'', 2019. "Carbon nanostructures include various low-dimensional allotropes of carbon including carbon black (CB), carbon fiber, carbon nanotubes (CNTs), fullerene, and graphene."
The name is derived from "graphite" and the suffix -ene, reflecting the fact that the allotrope of carbon contains numerous double bonds. Each atom in a graphene sheet is connecte ...
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Indium Phosphide
Indium phosphide (InP) is a binary semiconductor composed of indium and phosphorus. It has a face-centered cubic ("zincblende") crystal structure, identical to that of GaAs and most of the III-V semiconductors. Manufacturing Indium phosphide can be prepared from the reaction of white phosphorus and indium iodide at 400 °C., also by direct combination of the purified elements at high temperature and pressure, or by thermal decomposition of a mixture of a trialkyl indium compound and phosphine. Uses InP is used in high-power and high-frequency electronics because of its superior electron velocity with respect to the more common semiconductors silicon and gallium arsenide. It was used with indium gallium arsenide to make a record breaking pseudomorphic heterojunction bipolar transistor that could operate at 604 GHz. It also has a direct bandgap, making it useful for optoelectronics devices like laser diodes. The company Infinera uses indium phosphide as its major techn ...
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Silicon
Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic table: carbon is above it; and germanium, tin, lead, and flerovium are below it. It is relatively unreactive. Because of its high chemical affinity for oxygen, it was not until 1823 that Jöns Jakob Berzelius was first able to prepare it and characterize it in pure form. Its oxides form a family of anions known as silicates. Its melting and boiling points of 1414 °C and 3265 °C, respectively, are the second highest among all the metalloids and nonmetals, being surpassed only by boron. Silicon is the eighth most common element in the universe by mass, but very rarely occurs as the pure element in the Earth's crust. It is widely distributed in space in cosmic dusts, planetoids, and planets as various forms of silicon dioxide ( ...
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Indium Arsenide
Indium arsenide, InAs, or indium monoarsenide, is a narrow-bandgap semiconductor composed of indium and arsenic. It has the appearance of grey cubic crystals with a melting point of 942 °C. Indium arsenide is similar in properties to gallium arsenide and is a direct bandgap material, with a bandgap of 0.35 eV at room temperature. Indium arsenide is used for construction of infrared detectors, for the wavelength range of 1–3.8 µm. The detectors are usually photovoltaic photodiodes. Cryogenically cooled detectors have lower noise, but InAs detectors can be used in higher-power applications at room temperature as well. Indium arsenide is also used for making of diode lasers. InAs is well known for its high electron mobility and narrow energy bandgap. It is widely used as terahertz radiation source as it is a strong photo-Dember emitter. The optoelectronic properties and phonon vibrations are slightly changed under the effect of temperature over the range form 0 K ...
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Cadmium Selenide
Cadmium selenide is an inorganic compound with the formula Cadmium, CdSelenide, Se. It is a black to red-black solid that is classified as a II-VI semiconductor of the n-type semiconductor, n-type. Much of the current research on this compound is focused on its nanoparticles. Structure Three crystalline forms of CdSe are known which follow the structures of: Wurtzite (crystal structure), wurtzite (hexagonal), Cubic crystal system#Zincblende structure, sphalerite (cubic) and Cubic crystal system#Rock-salt structure, rock-salt (cubic). The sphalerite CdSe structure is unstable and converts to the wurtzite form upon moderate heating. The transition starts at about 130 °C, and at 700 °C it completes within a day. The rock-salt structure is only observed under high pressure. Production The production of cadmium selenide has been carried out in two different ways. The preparation of bulk crystalline CdSe is done by the High-Pressure Vertical Bridgman method or High-Pressur ...
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Cadmium Sulfide
Cadmium sulfide is the inorganic compound with the formula CdS. Cadmium sulfide is a yellow solid.Egon Wiberg, Arnold Frederick Holleman (2001''Inorganic Chemistry'' Elsevier It occurs in nature with two different crystal structures as the rare minerals greenockite and hawleyite, but is more prevalent as an impurity substituent in the similarly structured zinc ores sphalerite and wurtzite, which are the major economic sources of cadmium. As a compound that is easy to isolate and purify, it is the principal source of cadmium for all commercial applications. Its vivid yellow color led to its adoption as a pigment for the yellow paint "cadmium yellow" in the 18th century. Production Cadmium sulfide can be prepared by the precipitation from soluble cadmium(II) salts with sulfide ion. This reaction has been used for gravimetric analysis and qualitative inorganic analysis.The preparative route and the subsequent treatment of the product, affects the polymorphic form that is produced ( ...
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Lead(II) Telluride
Lead telluride is a compound of lead and tellurium (PbTe). It crystallizes in the NaCl crystal structure with Pb atoms occupying the cation and Te forming the anionic lattice. It is a narrow gap semiconductor with a band gap of 0.32 eV. It occurs naturally as the mineral altaite. Properties * Dielectric constant ~1000. * Electron Effective mass ~ 0.01 ''m''e * Hole mobility, μp = 600 cm2 V−1 s−1 (0 K); 4000 cm2 V−1 s−1 (300 K) Applications PbTe has proven to be a very important intermediate thermoelectric material. The performance of thermoelectric materials can be evaluated by the figure of merit, ZT=S^2\sigma T/\kappa, in which S is the Seebeck coefficient, \sigma is the electrical conductivity and \kappa is the thermal conductivity. In order to improve the thermoelectric performance of materials, the power factor (S^2\sigma) needs to be maximized and the thermal conductivity needs to be minimized. ...
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Lead(II) Sulfide
Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, lead is a shiny gray with a hint of blue. It tarnishes to a dull gray color when exposed to air. Lead has the highest atomic number of any stable element and three of its isotopes are endpoints of major nuclear decay chains of heavier elements. Lead is toxic, even in small amounts, especially to children. Lead is a relatively unreactive post-transition metal. Its weak metallic character is illustrated by its amphoteric nature; lead and lead oxides react with acids and bases, and it tends to form covalent bonds. Compounds of lead are usually found in the +2 oxidation state rather than the +4 state common with lighter members of the carbon group. Exceptions are mostly limited to organolead compounds. Like the lighter members of the group, le ...
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Quantum Dots
Quantum dots (QDs) are semiconductor particles a few nanometres in size, having optical and electronic properties that differ from those of larger particles as a result of quantum mechanics. They are a central topic in nanotechnology. When the quantum dots are illuminated by UV light, an electron in the quantum dot can be excited to a state of higher energy. In the case of a semiconducting quantum dot, this process corresponds to the transition of an electron from the valence band to the conductance band. The excited electron can drop back into the valence band releasing its energy as light. This light emission ( photoluminescence) is illustrated in the figure on the right. The color of that light depends on the energy difference between the conductance band and the valence band, or the transition between discrete energy states when band structure is no longer a good definition in QDs. In the language of materials science, nanoscale semiconductor materials tightly confine eith ...
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Lead(II) Selenide
Lead selenide (PbSe), or lead(II) selenide, a selenide of lead, is a semiconductor material. It forms cubic crystals of the NaCl structure; it has a direct bandgap of 0.27 eV at room temperature. (Note that incorrectly identifies PbSe and other IV–VI semiconductors as indirect gap materials.) A grey solid, it is used for manufacture of infrared detectors for thermal imaging. The mineral clausthalite is a naturally occurring lead selenide. It may be formed by direct reaction between its constituent elements, lead and selenium. Infrared detection PbSe was one of the first materials found to be sensitive to the infrared radiation used for military applications. Early research works on the material as infrared detector were carried out during the 1930s and the first useful devices were processed by Germans, Americans and British during and just after World War II. Since then, PbSe has been commonly used as an infrared photodetector in multiple applications, from spectrom ...
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