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Capillary Condensation
Capillary condensation is the "process by which multilayer adsorption from the vapor haseinto a porous medium proceeds to the point at which pore spaces become filled with condensed liquid from the vapor hase"Schramm, L.L ''The Language of Colloid & Interface Science'' 1993, ACS Professional Reference Book, ACS: Washington, D.C. The unique aspect of capillary condensation is that vapor condensation occurs below the saturation vapor pressure, Psat, of the pure liquid.Hunter, R.J. ''Foundations of Colloid Science'' 2nd Edition, Oxford University Press, 2001. This result is due to an increased number of van der Waals interactions between vapor phase molecules inside the confined space of a capillary. Once condensation has occurred, a meniscus immediately forms at the liquid-vapor interface which allows for equilibrium below the saturation vapor pressure. Meniscus formation is dependent on the surface tension of the liquid and the shape of the capillary, as shown by the Young-Lapl ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Porous Medium
A porous medium or a porous material is a material containing pores (voids). The skeletal portion of the material is often called the "matrix" or "frame". The pores are typically filled with a fluid (liquid or gas). The skeletal material is usually a solid, but structures like foams are often also usefully analyzed using concept of porous media. A porous medium is most often characterised by its porosity. Other properties of the medium (e.g. permeability, tensile strength, electrical conductivity, tortuosity) can sometimes be derived from the respective properties of its constituents (solid matrix and fluid) and the media porosity and pores structure, but such a derivation is usually complex. Even the concept of porosity is only straightforward for a poroelastic medium. Often both the solid matrix and the pore network (also known as the pore space) are continuous, so as to form two interpenetrating continua such as in a sponge. However, there is also a concept of closed porosit ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Phase Diagrams
A phase diagram in physical chemistry, engineering, mineralogy, and materials science is a type of chart used to show conditions (pressure, temperature, volume, etc.) at which thermodynamically distinct phases (such as solid, liquid or gaseous states) occur and coexist at equilibrium. Overview Common components of a phase diagram are ''lines of equilibrium'' or ''phase boundaries'', which refer to lines that mark conditions under which multiple phases can coexist at equilibrium. Phase transitions occur along lines of equilibrium. Metastable phases are not shown in phase diagrams as, despite their common occurrence, they are not equilibrium phases. Triple points are points on phase diagrams where lines of equilibrium intersect. Triple points mark conditions at which three different phases can coexist. For example, the water phase diagram has a triple point corresponding to the single temperature and pressure at which solid, liquid, and gaseous water can coexist in a stabl ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Wetting
Wetting is the ability of a liquid to maintain contact with a solid surface, resulting from intermolecular interactions when the two are brought together. This happens in presence of a gaseous phase or another liquid phase not miscible with the first one. The degree of wetting (wettability) is determined by a force balance between adhesive and cohesive forces. Wetting is important in the bonding or adherence of two materials. Wetting and the surface forces that control wetting are also responsible for other related effects, including capillary effects. There are two types of wetting: non-reactive wetting and reactive wetting. Wetting deals with three phases of matter: gas, liquid, and solid. It is now a center of attention in nanotechnology and nanoscience studies due to the advent of many nanomaterials in the past two decades (e.g. graphene, Carbon nano tube, carbon nanotube, boron nitride nanomesh). Explanation Adhesive forces between a liquid and solid cause a liquid ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Wetting
Wetting is the ability of a liquid to maintain contact with a solid surface, resulting from intermolecular interactions when the two are brought together. This happens in presence of a gaseous phase or another liquid phase not miscible with the first one. The degree of wetting (wettability) is determined by a force balance between adhesive and cohesive forces. Wetting is important in the bonding or adherence of two materials. Wetting and the surface forces that control wetting are also responsible for other related effects, including capillary effects. There are two types of wetting: non-reactive wetting and reactive wetting. Wetting deals with three phases of matter: gas, liquid, and solid. It is now a center of attention in nanotechnology and nanoscience studies due to the advent of many nanomaterials in the past two decades (e.g. graphene, Carbon nano tube, carbon nanotube, boron nitride nanomesh). Explanation Adhesive forces between a liquid and solid cause a liquid ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Wetting Angle
The contact angle is the angle, conventionally measured through the liquid, where a liquid–vapor interface meets a solid surface. It quantifies the wettability of a solid surface by a liquid via the Young equation. A given system of solid, liquid, and vapor at a given temperature and pressure has a unique equilibrium contact angle. However, in practice a dynamic phenomenon of contact angle hysteresis is often observed, ranging from the advancing (maximal) contact angle to the receding (minimal) contact angle. The equilibrium contact is within those values, and can be calculated from them. The equilibrium contact angle reflects the relative strength of the liquid, solid, and vapour molecular interaction. The contact angle depends upon the medium above the free surface of the liquid, and the nature of the liquid and solid in contact. It is independent of the inclination of solid to the liquid surface. It changes with surface tension and hence with the temperature and purity of th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Contact Angle
The contact angle is the angle, conventionally measured through the liquid, where a liquid–vapor interface meets a solid surface. It quantifies the wettability of a solid surface by a liquid via the Young equation. A given system of solid, liquid, and vapor at a given temperature and pressure has a unique equilibrium contact angle. However, in practice a dynamic phenomenon of contact angle hysteresis is often observed, ranging from the advancing (maximal) contact angle to the receding (minimal) contact angle. The equilibrium contact is within those values, and can be calculated from them. The equilibrium contact angle reflects the relative strength of the liquid, solid, and vapour molecular interaction. The contact angle depends upon the medium above the free surface of the liquid, and the nature of the liquid and solid in contact. It is independent of the inclination of solid to the liquid surface. It changes with surface tension and hence with the temperature and purity of t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Curvature And Contact Angle
In mathematics, curvature is any of several strongly related concepts in geometry. Intuitively, the curvature is the amount by which a curve deviates from being a straight line, or a surface deviates from being a plane. For curves, the canonical example is that of a circle, which has a curvature equal to the reciprocal of its radius. Smaller circles bend more sharply, and hence have higher curvature. The curvature ''at a point'' of a differentiable curve is the curvature of its osculating circle, that is the circle that best approximates the curve near this point. The curvature of a straight line is zero. In contrast to the tangent, which is a vector quantity, the curvature at a point is typically a scalar quantity, that is, it is expressed by a single real number. For surfaces (and, more generally for higher-dimensional manifolds), that are embedded in a Euclidean space, the concept of curvature is more complex, as it depends on the choice of a direction on the surface or man ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hysteresis
Hysteresis is the dependence of the state of a system on its history. For example, a magnet may have more than one possible magnetic moment in a given magnetic field, depending on how the field changed in the past. Plots of a single component of the moment often form a loop or hysteresis curve, where there are different values of one variable depending on the direction of change of another variable. This history dependence is the basis of memory in a hard disk drive and the remanence that retains a record of the Earth's magnetic field magnitude in the past. Hysteresis occurs in ferromagnetic and ferroelectric materials, as well as in the deformation of rubber bands and shape-memory alloys and many other natural phenomena. In natural systems it is often associated with irreversible thermodynamic change such as phase transitions and with internal friction; and dissipation is a common side effect. Hysteresis can be found in physics, chemistry, engineering, biology, and economics. I ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Vapor Pressures
Vapor pressure (or vapour pressure in English-speaking countries other than the US; see spelling differences) or equilibrium vapor pressure is defined as the pressure exerted by a vapor in thermodynamic equilibrium with its condensed phases (solid or liquid) at a given temperature in a closed system. The equilibrium vapor pressure is an indication of a liquid's evaporation rate. It relates to the tendency of particles to escape from the liquid (or a solid). A substance with a high vapor pressure at normal temperatures is often referred to as '' volatile''. The pressure exhibited by vapor present above a liquid surface is known as vapor pressure. As the temperature of a liquid increases, the kinetic energy of its molecules also increases. As the kinetic energy of the molecules increases, the number of molecules transitioning into a vapor also increases, thereby increasing the vapor pressure. The vapor pressure of any substance increases non-linearly with temperature accordi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Radius Of Curvature (mathematics)
In differential geometry, the radius of curvature, , is the reciprocal of the curvature. For a curve, it equals the radius of the circular arc which best approximates the curve at that point. For surfaces, the radius of curvature is the radius of a circle that best fits a normal section or combinations thereof. Definition In the case of a space curve, the radius of curvature is the length of the curvature vector. In the case of a plane curve, then is the absolute value of : R \equiv \left, \frac \ = \frac, where is the arc length from a fixed point on the curve, is the tangential angle and is the curvature. Formula In 2D If the curve is given in Cartesian coordinates as , i.e., as the graph of a function, then the radius of curvature is (assuming the curve is differentiable up to order 2): : R =\left, \frac \, \qquad\mbox\quad y' = \frac,\quad y'' = \frac, and denotes the absolute value of . If the curve is given parametrically by functions and , then the radius ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Condensation
Condensation is the change of the state of matter from the gas phase into the liquid phase, and is the reverse of vaporization. The word most often refers to the water cycle. It can also be defined as the change in the state of water vapor to liquid water when in contact with a liquid or solid surface or cloud condensation nuclei within the atmosphere. When the transition happens from the gaseous phase into the solid phase directly, the change is called deposition. Initiation Condensation is initiated by the formation of atomic/molecular clusters of that species within its gaseous volume—like rain drop or snow flake formation within clouds—or at the contact between such gaseous phase and a liquid or solid surface. In clouds, this can be catalyzed by water-nucleating proteins, produced by atmospheric microbes, which are capable of binding gaseous or liquid water molecules. Reversibility scenarios A few distinct reversibility scenarios emerge here with respect to the n ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Capillary Condensation
Capillary condensation is the "process by which multilayer adsorption from the vapor haseinto a porous medium proceeds to the point at which pore spaces become filled with condensed liquid from the vapor hase"Schramm, L.L ''The Language of Colloid & Interface Science'' 1993, ACS Professional Reference Book, ACS: Washington, D.C. The unique aspect of capillary condensation is that vapor condensation occurs below the saturation vapor pressure, Psat, of the pure liquid.Hunter, R.J. ''Foundations of Colloid Science'' 2nd Edition, Oxford University Press, 2001. This result is due to an increased number of van der Waals interactions between vapor phase molecules inside the confined space of a capillary. Once condensation has occurred, a meniscus immediately forms at the liquid-vapor interface which allows for equilibrium below the saturation vapor pressure. Meniscus formation is dependent on the surface tension of the liquid and the shape of the capillary, as shown by the Young-Lapl ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
