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CL-20
Hexanitrohexaazaisowurtzitane, also called HNIW and CL-20, is a polycyclic nitroamine explosive with the formula C6H6N12O12. In the 1980s, CL-20 was developed by the China Lake facility, primarily to be used in propellants. It has a better oxidizer-to-fuel ratio than conventional HMX or RDX. It releases 20% more energy than traditional HMX-based propellants, and is widely superior to conventional high-energy propellants and explosives. While most development of CL-20 has been fielded by the Thiokol Corporation, the US Navy (through ONR) has also been interested in CL-20 for use in rocket propellants, such as for missiles, as it has lower observability characteristics such as less visible smoke. CL-20 has not yet been fielded in any production weapons system, but is undergoing testing for stability, production capabilities, and other weapons characteristics. Synthesis First, benzylamine (1) is condensed with glyoxal (2) under acidic and dehydrating conditions to yield the ...
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Adam Matzger
Adam J. Matzger, a researcher in polymers and crystals, is the Charles G. Overberger Collegiate Professor of Chemistry at the University of Michigan, and an associate editor for the American Chemical Society's journal '' Crystal Growth & Design''. Biography Matzger is a native of Piedmont, California but moved to Ohio to complete his undergraduate career at Oberlin College, where he graduated with a Bachelor of Arts in Chemistry in 1992. From there he moved back to California for his graduate work at the University of California at Berkeley where he studied under Professor Peter C. Vollhardt. In 1997 he earned his Ph. D. degree with a thesis titled "Synthetic, Theoretical, and Structural Studies on Dehydrobenzoannulenes and Phenylenes." He then was a Postdoctoral Researcher at California Institute of Technology (co-mentored by Robert H. Grubbs and Nathan S. Lewis) until 2000 when he was appointed Assistant Professor of Chemistry and of Macromolecular Science and Engineeri ...
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Benzylamine
Benzylamine is an organic chemical compound with the condensed structural formula C6H5CH2NH2 (sometimes abbreviated as PhCH2NH2 or BnNH2). It consists of a benzyl group, C6H5CH2, attached to an amine functional group, NH2. This colorless water-soluble liquid is a common precursor in organic chemistry and used in the industrial production of many pharmaceuticals. The hydrochloride salt was used to treat motion sickness on the Mercury-Atlas 6 mission in which NASA astronaut John Glenn became the first American to orbit the Earth. Manufacturing Benzylamine can be produced by several methods, the main industrial route being the reaction of benzyl chloride and ammonia. It is also produced by the reduction of benzonitrile and reductive amination of benzaldehyde, both done over Raney nickel. : It was first produced accidentally by Rudolf Leuckart in the reaction of benzaldehyde with formamide in a process now known as the Leuckart reaction, a general process in which reductive am ...
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HHTDD
HHTDD (hexanitrohexaazatricyclododecanedione) is a powerful but moisture sensitive explosive compound. It is essentially an open analogue of the cyclic nitroamine cage compounds such as CL-20. While it is highly explosive, with a velocity of detonation even higher than that of CL-20, HHTDD readily decomposes in the presence of even trace amounts of water, making it unsuitable for any practical applications. See also * TNGU *2,4,6-Tris(trinitromethyl)-1,3,5-triazine *4,4’-Dinitro-3,3’-diazenofuroxan (DDF) *Heptanitrocubane *Octanitrocubane *RE factor TNT equivalent is a convention for expressing energy, typically used to describe the energy released in an explosion. The is a unit of energy defined by that convention to be , which is the approximate energy released in the detonation of a m ... References Explosive chemicals Nitroamines {{Explosive-stub ...
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Cocrystal
Cocrystals are "solids that are crystalline single phase materials composed of two or more different molecular or ionic compounds generally in a stoichiometric ratio which are neither solvates nor simple salts." A broader definition is that cocrystals "consist of two or more components that form a unique crystalline structure having unique properties." Several subclassifications of cocrystals exist. Cocrystals can encompass many types of compounds, including hydrates, solvates and clathrates, which represent the basic principle of host–guest chemistry. Hundreds of examples of cocrystallization are reported annually. History The first reported cocrystal, quinhydrone, was studied by Friedrich Wöhler in 1844. Quinhydrone is a cocrystal of quinone and hydroquinone (known archaically as quinol). He found that this material was made up of a 1:1 molar combination of the components. Quinhydrone was analyzed by numerous groups over the next decade and several related cocrystals were made ...
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Rocket Propellant
Rocket propellant is the reaction mass of a rocket. This reaction mass is ejected at the highest achievable velocity from a rocket engine A rocket engine uses stored rocket propellants as the reaction mass for forming a high-speed propulsive jet of fluid, usually high-temperature gas. Rocket engines are reaction engines, producing thrust by ejecting mass rearward, in accordanc ... to produce thrust. The energy required can either come from the propellants themselves, as with a chemical rocket, or from an external source, as with ion engines. Overview Rockets create thrust by expelling mass rear-ward, at high velocity. The thrust produced can be calculated by multiplying the mass flow rate of the propellants by their exhaust velocity relative to the rocket (specific impulse). A rocket can be thought of as being accelerated by the pressure of the combusting gases against the combustion chamber and Rocket engine nozzle, nozzle, not by "pushing" against the air behind or belo ...
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Naval Air Weapons Station China Lake
Naval Air Weapons Station (NAWS) China Lake is a large military installation in California that supports the research, testing and evaluation programs of the United States Navy. It is part of Navy Region Southwest under Commander, Navy Installations Command, and was originally known as Naval Ordnance Test Station (NOTS). The installation is located in the Western Mojave Desert region of California, approximately north of Los Angeles. Occupying land in three counties – Kern, San Bernardino, and Inyo – the installation's closest neighbors are the city of Ridgecrest and the communities of Inyokern, Trona, and Darwin. China Lake is the United States Navy's largest single landholding, representing 85% of the Navy's land for weapons and armaments research, development, acquisition, testing and evaluation (RDAT&E) use and 38% of the Navy's land holdings worldwide. In total, its two ranges and main site cover more than , an area larger than the state of Rhode Island. As of 2010, ...
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Metre Per Second
The metre per second is the unit of both speed (a scalar (physics), scalar quantity) and velocity (a Vector (mathematics and physics), vector quantity, which has direction and magnitude) in the International System of Units (SI), equal to the speed of a body covering a distance of one metre in a time of one second. The International System of Units, SI unit symbols are m/s, m·s−1, m s−1, or . Sometimes it is abbreviated as "mps". Conversions is equivalent to: : = 3.6 kilometres per hour, km/h (exactly) : ≈ 3.2808 feet per second (approximately) : ≈ 2.2369 miles per hour (approximately) : ≈ 1.9438 knot (unit), knots (approximately) 1 feet per second, foot per second = (exactly) 1 miles per hour, mile per hour = (exactly) 1 kilometres per hour, km/h = (exactly) Relation to other measures The benz, named in honour of Karl Benz, has been proposed as a name for one metre per second. Although it has seen some support as a practical unit, primarily from German ...
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Combust
Combust can refer to: * Combust (astrological aspect), the obscuring of the unassisted viewing of a planet by the Sun's light * Combustion Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combusti ...
, the exothermical chemical reaction {{Disambig ...
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Onas Bolton
The Selk'nam, also known as the Onawo or Ona people, are an indigenous people in the Patagonian region of southern Argentina and Chile, including the Tierra del Fuego islands. They were one of the last native groups in South America to be encountered by migrant Europeans in the late 19th century. In the mid-19th century, there were about 4000 Selk'nam; by 1919 there were 297, and by 1930 just over 100. They are considered extinct as a tribe. The exploration of gold and the introduction of farming in the region of Tierra del Fuego led to genocide of the Selk'nam. Joubert Yantén Gómez, a Chilean mestizo of part Selk'nam ancestry, has taught himself the language and is considered the only speaker; he uses the name ''Keyuk.''Judith Thurman, "A Loss for Words"
''The New Yorker'', 30 March 2015
W ...
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CrystEngComm
''CrystEngComm'' is a peer-reviewed online-only scientific journal publishing original research and review articles on all aspects of crystal engineering including properties, polymorphism, target materials, and crystalline nanomaterials. It is published biweekly by the Royal Society of Chemistry and the editor-in-chief is Pierangelo Metrangolo. According to the ''Journal Citation Reports'', the journal has a 2020 impact factor of 3.545. ''CrystEngComm'' has a close association with the virtual web community, CrystEngCommunity. History ''CrystEngComm'' was one of the first online-only chemistry journals when it was established in 1999. Initially, articles were published online as soon as they were accepted and the journal did not publish articles in issues. However, in 2000 issues were introduced and the journal was published monthly. As submissions increased, the journal switched in 2011 to a biweekly publication. Authors can elect to have accepted articles published as op ...
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Journal Of Physics And Chemistry Of Solids
''Journal of Physics and Chemistry of Solids'' is a peer-reviewed scientific journal of condensed matter physics and material science. The journal is edited by M. Azuma, A. Bansil, H.-P. Cheng, and K. Prassides. The journal was established in 1957 by Harvey Brooks, and is published monthly by Elsevier. In 1963 the Letters section of the journal split to form ''Solid State Communications''. Abstracting and indexing The journal is abstracted and indexed in the following databases: *Cambridge Scientific Abstracts *Chemical Abstracts *Current Contents/Engineering, Computing & Technology *Materials Science Citation Index * EIC/Intelligence *Engineering Index * INSPEC * PASCAL * SSSA/ CISA/ ECA/ ISMEC *Scopus Scopus is Elsevier's abstract and citation database launched in 2004. Scopus covers nearly 36,377 titles (22,794 active titles and 13,583 inactive titles) from approximately 11,678 publishers, of which 34,346 are peer-reviewed journals in top-l ... References External li ...
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Nitronium Tetrafluoroborate
Nitronium tetrafluoroborate is an inorganic compound with formula NO2BF4. It is a salt of nitronium cation and tetrafluoroborate anion. It is a colorless crystalline solid, which reacts with water to form the corrosive acids HF and HNO3. As such, it must be handled under water-free conditions. It is sparsely soluble in many organic solvents. Preparation Nitronium tetrafluoroborate can be prepared by adding a mixture of anhydrous hydrogen fluoride and boron trifluoride to a nitromethane solution of nitric acid or dinitrogen pentoxide. Applications Nitronium tetrafluoroborate is used as a nitration In organic chemistry, nitration is a general class of chemical processes for the introduction of a nitro group into an organic compound. The term also is applied incorrectly to the different process of forming nitrate esters between alcohols and ... agent. References Tetrafluoroborates Nitronium compounds {{inorganic-compound-stub ...
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