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Bose Gas
An ideal Bose gas is a quantum-mechanical phase of matter, analogous to a classical ideal gas. It is composed of bosons, which have an integer value of spin, and abide by Bose–Einstein statistics. The statistical mechanics of bosons were developed by Satyendra Nath Bose for a photon gas, and extended to massive particles by Albert Einstein who realized that an ideal gas of bosons would form a condensate at a low enough temperature, unlike a classical ideal gas. This condensate is known as a Bose–Einstein condensate. Introduction and examples Bosons are quantum mechanical particles that follow Bose–Einstein statistics, or equivalently, that possess integer spin. These particles can be classified as elementary: these are the Higgs boson, the photon, the gluon, the W/Z and the hypothetical graviton; or composite like the atom of hydrogen, the atom of 16 O, the nucleus of deuterium, mesons etc. Additionally, some quasiparticles in more complex systems can also be c ...
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Phase Of Matter
In the physical sciences, a phase is a region of space (a thermodynamic system), throughout which all physical properties of a material are essentially uniform. Examples of physical properties include density, index of refraction, magnetization and chemical composition. A simple description is that a phase is a region of material that is chemically uniform, physically distinct, and (often) mechanically separable. In a system consisting of ice and water in a glass jar, the ice cubes are one phase, the water is a second phase, and the humid air is a third phase over the ice and water. The glass of the jar is another separate phase. (See ) The term ''phase'' is sometimes used as a synonym for state of matter, but there can be several immiscible phases of the same state of matter. Also, the term ''phase'' is sometimes used to refer to a set of equilibrium states demarcated in terms of state variables such as pressure and temperature by a phase boundary on a phase diagram. Bec ...
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Oxygen
Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as well as with other compounds. Oxygen is Earth's most abundant element, and after hydrogen and helium, it is the third-most abundant element in the universe. At standard temperature and pressure, two atoms of the element bind to form dioxygen, a colorless and odorless diatomic gas with the formula . Diatomic oxygen gas currently constitutes 20.95% of the Earth's atmosphere, though this has changed considerably over long periods of time. Oxygen makes up almost half of the Earth's crust in the form of oxides.Atkins, P.; Jones, L.; Laverman, L. (2016).''Chemical Principles'', 7th edition. Freeman. Many major classes of organic molecules in living organisms contain oxygen atoms, such as proteins, nucleic acids, carbohydrates, and ...
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Helium-4
Helium-4 () is a stable isotope of the element helium. It is by far the more abundant of the two naturally occurring isotopes of helium, making up about 99.99986% of the helium on Earth. Its nucleus is identical to an alpha particle, and consists of two protons and two neutrons. Alpha decay of heavy elements in the Earth's crust is the source of most naturally occurring helium-4 on Earth, produced after the planet cooled and solidified. While it is also produced by nuclear fusion in stars, most helium-4 in the Sun and in the universe is thought to have been produced by the Big Bang, and is referred to as " primordial helium". However, primordial helium-4 is largely absent from the Earth, having escaped during the high-temperature phase of Earth's formation. Helium-4 makes up about one quarter of the ordinary matter in the universe by mass, with almost all of the rest being hydrogen. When liquid helium-4 is cooled to below , it becomes a superfluid, with properties that are ...
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Heat Capacity
Heat capacity or thermal capacity is a physical property of matter, defined as the amount of heat to be supplied to an object to produce a unit change in its temperature. The SI unit of heat capacity is joule per kelvin (J/K). Heat capacity is an extensive property. The corresponding intensive property is the specific heat capacity, found by dividing the heat capacity of an object by its mass. Dividing the heat capacity by the amount of substance in moles yields its molar heat capacity. The volumetric heat capacity measures the heat capacity per volume. In architecture and civil engineering, the heat capacity of a building is often referred to as its thermal mass. Definition Basic definition The heat capacity of an object, denoted by C, is the limit : C = \lim_\frac, where \Delta Q is the amount of heat that must be added to the object (of mass ''M'') in order to raise its temperature by \Delta T. The value of this parameter usually varies considerably depending on ...
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Peter Debye
Peter Joseph William Debye (; ; March 24, 1884 – November 2, 1966) was a Dutch-American physicist and physical chemist, and Nobel laureate in Chemistry. Biography Early life Born Petrus Josephus Wilhelmus Debije in Maastricht, Netherlands, Debye enrolled in the Aachen University of Technology in 1901. In 1905, he completed his first degree in electrical engineering. He published his first paper, a mathematically elegant solution of a problem involving eddy currents, in 1907. At Aachen, he studied under the theoretical physicist Arnold Sommerfeld, who later claimed that his most important discovery was Peter Debye. In 1906, Sommerfeld received an appointment at Munich, Bavaria, and took Debye with him as his assistant. Debye got his Ph.D. with a dissertation on radiation pressure in 1908. In 1910, he derived the Planck radiation formula using a method which Max Planck agreed was simpler than his own. In 1911, when Albert Einstein took an appointment as a professor at Prag ...
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Normal Mode
A normal mode of a dynamical system is a pattern of motion in which all parts of the system move sinusoidally with the same frequency and with a fixed phase relation. The free motion described by the normal modes takes place at fixed frequencies. These fixed frequencies of the normal modes of a system are known as its natural frequencies or resonant frequencies. A physical object, such as a building, bridge, or molecule, has a set of normal modes and their natural frequencies that depend on its structure, materials and boundary conditions. The most general motion of a system is a superposition of its normal modes. The modes are normal in the sense that they can move independently, that is to say that an excitation of one mode will never cause motion of a different mode. In mathematical terms, normal modes are orthogonal to each other. General definitions Mode In the wave theory of physics and engineering, a mode in a dynamical system is a standing wave state of exci ...
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Debye Model
In thermodynamics and solid-state physics, the Debye model is a method developed by Peter Debye in 1912 for estimating the phonon contribution to the specific heat (Heat capacity) in a solid. It treats the vibrations of the atomic lattice (heat) as phonons in a box, in contrast to the Einstein photoelectron model, which treats the solid as many individual, non-interacting quantum harmonic oscillators. The Debye model correctly predicts the low-temperature dependence of the heat capacity of solids, which is proportional to T^3 – the Debye ''T'' 3 law. Just like the Einstein photoelectron model, it also recovers the Dulong–Petit law at high temperatures. But due to simplifying assumptions, its accuracy suffers at intermediate temperatures. Derivation The Debye model is a solid-state equivalent of Planck's law of black body photon radiation, where one treats electromagnetic photonic radiation as a photon gas. The Debye model treats atomic vibrations as phonons in a bo ...
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Phonon
In physics, a phonon is a collective excitation in a periodic, elastic arrangement of atoms or molecules in condensed matter, specifically in solids and some liquids. A type of quasiparticle, a phonon is an excited state in the quantum mechanical quantization of the modes of vibrations for elastic structures of interacting particles. Phonons can be thought of as quantized sound waves, similar to photons as quantized light waves. The study of phonons is an important part of condensed matter physics. They play a major role in many of the physical properties of condensed matter systems, such as thermal conductivity and electrical conductivity, as well as in models of neutron scattering and related effects. The concept of phonons was introduced in 1932 by Soviet physicist Igor Tamm. The name ''phonon'' comes from the Greek word (), which translates to ''sound'' or ''voice'', because long-wavelength phonons give rise to sound. The name is analogous to the word ''photon''. ...
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Black-body Radiation
Black-body radiation is the thermal electromagnetic radiation within, or surrounding, a body in thermodynamic equilibrium with its environment, emitted by a black body (an idealized opaque, non-reflective body). It has a specific, continuous spectrum of wavelengths, inversely related to intensity, that depend only on the body's temperature, which is assumed, for the sake of calculations and theory, to be uniform and constant., Chapter 13. A perfectly insulated enclosure which is in thermal equilibrium internally contains black-body radiation, and will emit it through a hole made in its wall, provided the hole is small enough to have a negligible effect upon the equilibrium. The thermal radiation spontaneously emitted by many ordinary objects can be approximated as black-body radiation. Of particular importance, although planets and stars (including the Earth and Sun) are neither in thermal equilibrium with their surroundings nor perfect black bodies, black-body radiation is ...
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Planck's Law
In physics, Planck's law describes the spectral density of electromagnetic radiation emitted by a black body in thermal equilibrium at a given temperature , when there is no net flow of matter or energy between the body and its environment. At the end of the 19th century, physicists were unable to explain why the observed spectrum of black-body radiation, which by then had been accurately measured, diverged significantly at higher frequencies from that predicted by existing theories. In 1900, German physicist Max Planck heuristically derived a formula for the observed spectrum by assuming that a hypothetical electrically charged oscillator in a cavity that contained black-body radiation could only change its energy in a minimal increment, , that was proportional to the frequency of its associated electromagnetic wave. This resolved the problem of the ultraviolet catastrophe predicted by classical physics. This discovery was a pioneering insight of modern physics and is of ...
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Plasma Oscillation
Plasma oscillations, also known as Langmuir waves (after Irving Langmuir), are rapid oscillations of the electron density in conducting media such as plasmas or metals in the ultraviolet region. The oscillations can be described as an instability in the dielectric function of a free electron gas. The frequency only depends weakly on the wavelength of the oscillation. The quasiparticle resulting from the quantization of these oscillations is the plasmon. Langmuir waves were discovered by American physicists Irving Langmuir and Lewi Tonks in the 1920s. They are parallel in form to Jeans instability waves, which are caused by gravitational instabilities in a static medium. Mechanism Consider an electrically neutral plasma in equilibrium, consisting of a gas of positively charged ions and negatively charged electrons. If one displaces by a tiny amount an electron or a group of electrons with respect to the ions, the Coulomb force pulls the electrons back, acting as a restoring ...
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Plasmon
In physics, a plasmon is a quantum of plasma oscillation. Just as light (an optical oscillation) consists of photons, the plasma oscillation consists of plasmons. The plasmon can be considered as a quasiparticle since it arises from the quantization of plasma oscillations, just like phonons are quantizations of mechanical vibrations. Thus, plasmons are collective (a discrete number) oscillations of the free electron gas density. For example, at optical frequencies, plasmons can couple with a photon to create another quasiparticle called a plasmon polariton. Derivation The plasmon was initially proposed in 1952 by David Pines and David Bohm and was shown to arise from a Hamiltonian for the long-range electron-electron correlations. Since plasmons are the quantization of classical plasma oscillations, most of their properties can be derived directly from Maxwell's equations. Explanation Plasmons can be described in the classical picture as an oscillation of electron de ...
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