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Broadband Acoustic Resonance Dissolution Spectroscopy
Broadband acoustic resonance dissolution spectroscopy (BARDS) is a technique in analytical chemistry. Developed in the late 2000s,D. Fitzpatrick, 2009, "Instrumentation and analytical techniques suitable for broadband acoustic resonance dissolution spectroscopy", ''US Patent'', US8813566B2 it involves the analysis of the changes in sound frequency generated when a solute dissolves in a solvent, by harnessing the hot chocolate effect first described by Frank S. Crawford. The technique is partly based on the solubility difference of gas in pure solvents and in solutions. The dissolution of a compound in a pure solvent results in the generation of gas bubbles in the solvent, due to the lowering of gas solubility in the resulting solution, as well as the introduction of gases with the solute. The presence of these gas bubbles increases the compressibility of the solution, thereby lowering the velocity of sound in the solution. This effect can be monitored by means of the frequency ch ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Analytical Chemistry
Analytical chemistry studies and uses instruments and methods to separate, identify, and quantify matter. In practice, separation, identification or quantification may constitute the entire analysis or be combined with another method. Separation isolates analytes. Qualitative analysis identifies analytes, while quantitative analysis determines the numerical amount or concentration. Analytical chemistry consists of classical, wet chemical methods and modern, instrumental methods. Classical qualitative methods use separations such as precipitation, extraction, and distillation. Identification may be based on differences in color, odor, melting point, boiling point, solubility, radioactivity or reactivity. Classical quantitative analysis uses mass or volume changes to quantify amount. Instrumental methods may be used to separate samples using chromatography, electrophoresis or field flow fractionation. Then qualitative and quantitative analysis can be performed, often with ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Frequency
Frequency is the number of occurrences of a repeating event per unit of time. It is also occasionally referred to as ''temporal frequency'' for clarity, and is distinct from ''angular frequency''. Frequency is measured in hertz (Hz) which is equal to one event per second. The period is the interval of time between events, so the period is the reciprocal of the frequency. For example, if a heart beats at a frequency of 120 times a minute (2 hertz), the period, —the interval at which the beats repeat—is half a second (60 seconds divided by 120 beats). Frequency is an important parameter used in science and engineering to specify the rate of oscillatory and vibratory phenomena, such as mechanical vibrations, audio signals (sound), radio waves, and light. Definitions and units For cyclical phenomena such as oscillations, waves, or for examples of simple harmonic motion, the term ''frequency'' is defined as the number of cycles or vibrations per unit of time. The ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Solute
In chemistry, a solution is a special type of homogeneous mixture composed of two or more substances. In such a mixture, a solute is a substance dissolved in another substance, known as a solvent. If the attractive forces between the solvent and solute particles are greater than the attractive forces holding the solute particles together, the solvent particles pull the solute particles apart and surround them. These surrounded solute particles then move away from the solid solute and out into the solution. The mixing process of a solution happens at a scale where the effects of chemical polarity are involved, resulting in interactions that are specific to solvation. The solution usually has the state of the solvent when the solvent is the larger fraction of the mixture, as is commonly the case. One important parameter of a solution is the concentration, which is a measure of the amount of solute in a given amount of solution or solvent. The term "aqueous solution" is used when ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Solvent
A solvent (s) (from the Latin '' solvō'', "loosen, untie, solve") is a substance that dissolves a solute, resulting in a solution. A solvent is usually a liquid but can also be a solid, a gas, or a supercritical fluid. Water is a solvent for polar molecules and the most common solvent used by living things; all the ions and proteins in a cell are dissolved in water within the cell. The quantity of solute that can dissolve in a specific volume of solvent varies with temperature. Major uses of solvents are in paints, paint removers, inks, and dry cleaning. Specific uses for organic solvents are in dry cleaning (e.g. tetrachloroethylene); as paint thinners ( toluene, turpentine); as nail polish removers and solvents of glue (acetone, methyl acetate, ethyl acetate); in spot removers ( hexane, petrol ether); in detergents ( citrus terpenes); and in perfumes (ethanol). Solvents find various applications in chemical, pharmaceutical, oil, and gas industries, including in chemic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hot Chocolate Effect
The hot chocolate effect is a phenomenon of wave mechanics in which the pitch heard from tapping a cup of hot liquid rises after the addition of a soluble powder.Frank S. Crawford, May 1982, "The hot chocolate effect", ''American Journal of Physics'', Volume 50, Issue 5, pp. 398-404, doi:10.1119/1.13080 (Abstract only) It was first documented in 1980 by Frank Crawford of the Lawrence Berkeley Laboratory. It was initially observed in the making of hot chocolate or instant coffee, but also occurs in other situations such as adding salt to supersaturated hot water or cold beer. Recent research has found many more substances which create the effect, even in initially non-supersaturated liquids.D. Fitzpatrick ''et al.'', March 2012, "Principles and Applications of Broadband Acoustic Resonance Dissolution Spectroscopy (BARDS): A Sound Approach for the Analysis of Compounds", ''Analytical Chemistry'', Volume 84, Issue 5, pp. 2202-2210, doi:10.1021/ac202509s The effect is thought to happe ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Compressibility
In thermodynamics and fluid mechanics, the compressibility (also known as the coefficient of compressibility or, if the temperature is held constant, the isothermal compressibility) is a measure of the instantaneous relative volume change of a fluid or solid as a response to a pressure (or mean stress) change. In its simple form, the compressibility \kappa (denoted in some fields) may be expressed as :\beta =-\frac\frac, where is volume and is pressure. The choice to define compressibility as the negative of the fraction makes compressibility positive in the (usual) case that an increase in pressure induces a reduction in volume. The reciprocal of compressibility at fixed temperature is called the isothermal bulk modulus. Definition The specification above is incomplete, because for any object or system the magnitude of the compressibility depends strongly on whether the process is isentropic or isothermal. Accordingly, isothermal compressibility is defined: :\beta_T=-\f ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Velocity Of Sound
The speed of sound is the distance travelled per unit of time by a sound wave as it propagates through an elastic medium. At , the speed of sound in air is about , or one kilometre in or one mile in . It depends strongly on temperature as well as the medium through which a sound wave is propagating. At , the speed of sound in air is about . The speed of sound in an ideal gas depends only on its temperature and composition. The speed has a weak dependence on frequency and pressure in ordinary air, deviating slightly from ideal behavior. In colloquial speech, ''speed of sound'' refers to the speed of sound waves in air. However, the speed of sound varies from substance to substance: typically, sound travels most slowly in gases, faster in liquids, and fastest in solids. For example, while sound travels at in air, it travels at in water (almost 4.3 times as fast) and at in iron (almost 15 times as fast). In an exceptionally stiff material such as diamond, sound travels at , ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Acoustic Resonance Spectroscopy
Acoustic resonance spectroscopy (ARS) is a method of spectroscopy in the acoustic region, primarily the sonic and ultrasonic regions. ARS is typically much more rapid than HPLC and NIR. It is non destructive and requires no sample preparation as the sampling waveguide can simply be pushed into a sample powder/liquid or in contact with a solid sample. To date, the AR spectrometer has successfully differentiated and quantified sample analytes in various forms; (tablets, powders, and liquids). It has been used to measure and monitor the progression of chemical reactions, such as the setting and hardening of concrete from cement paste to solid. Acoustic spectrometry has also been used to measure the volume fraction of colloids in a dispersion medium, as well as for the investigation of physical properties of colloidal dispersions, such as aggregation and particle size distribution. Typically, these experiments are carried out with sinusoidal excitation signals and the experimental obs ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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