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Boron Monohydride
Borane(1), boron monohydride, hydridoboron or borylene is the molecule with the formula BH. It exists as a gas but rapidly degrades when condensed. By contrast, the cluster B12H122- (dodecaborate), which has very similar empirical formula, forms robust salts. Formation Boron monohydride can be formed from borane carbonyl exposed to ultraviolet light. BH3CO → BH + CH2O Boron monohydride is formed when boron compounds are heated to a high temperature in the presence of hydrogen. Boron monohydride is formed when the boron anion B− reacts with a hydrogen ion H+. It is also formed when atomic boron reacts with hydrogen. B + H2 → BH + H. There is too much energy in the reaction for BH2 to be stable. Boron monohydride probably exists in sunspots, but as of 2008 has not been detected. Properties The ionization potential is around 9.77 eV. The dissociation energy for the ground state molecule is 81.5 kcal/mol. The electron affinity is roughly 0.3 eV, and the HB− ion ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dodecaborate
The dodecaborate(12) anion, 12H12sup>2−, is a borane with an icosahedral arrangement of 12 boron atoms, with each boron atom being attached to a hydrogen atom. Its symmetry is classified by the molecular point group Ih. Synthesis and reactions The existence of the dodecaborate(12) anion, 12H12sup>2−, was predicted by H. C. Longuet-Higgins and M. de V. Roberts in 1955. Hawthorne and Pitochelli first made it 5 years later, by the reaction of 2-iododecaborane with triethylamine in benzene solution at 80 °C. It is more conveniently prepared in two steps from sodium borohydride. First the borohydride is converted into a triborate anion using the etherate of boron trifluoride: : 5 NaBH4 + BF3 → 2 NaB3H8 + 3 NaF + 2 H2 Pyrolysis of the triborate gives the twelve-boron cluster as the sodium salt. A variety of other synthetic methods have been published. Salts of the dodecaborate ion are stable in air and do not react with hot aqueous sodium hydroxide or hydrochloric acid. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Borane Carbonyl
Borane carbonyl is the inorganic compound with the formula H3BCO. This colorless gas is the adduct of borane and carbon monoxide Carbon monoxide (chemical formula CO) is a colorless, poisonous, odorless, tasteless, flammable gas that is slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simple .... It is usually prepared by combining borane-ether complexes and CO. The compound is mainly of theoretical and pedagogical interest. It reacts with aqueous base to give boranocarbonate H3BCO22−. Bond distances are B−C, 1.529; C−O, 1.140; 1.194 Å. The H−B−H angle is 113.7°. The CO vibrational band is at 2165 cm−1, 22 cm−1 higher than that of free CO. Experimental data Enthalpy of vaporization Vibrational levels (cm−1) vibrational zero-point energy: 7826.5 cm−1 (from fundamental vibrations) Rotational Constants (cm−1) Geometric Data Point Gro ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sunspot
Sunspots are phenomena on the Sun's photosphere that appear as temporary spots that are darker than the surrounding areas. They are regions of reduced surface temperature caused by concentrations of magnetic flux that inhibit convection. Sunspots appear within active regions, usually in pairs of opposite magnetic polarity. Their number varies according to the approximately 11-year solar cycle. Individual sunspots or groups of sunspots may last anywhere from a few days to a few months, but eventually decay. Sunspots expand and contract as they move across the surface of the Sun, with diameters ranging from to . Larger sunspots can be visible from Earth without the aid of a telescope. They may travel at relative speeds, or proper motions, of a few hundred meters per second when they first emerge. Indicating intense magnetic activity, sunspots accompany other active region phenomena such as coronal loops, prominences, and reconnection events. Most solar flares and coronal mas ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electron Volt
In physics, an electronvolt (symbol eV, also written electron-volt and electron volt) is the measure of an amount of kinetic energy gained by a single electron accelerating from rest through an electric potential difference of one volt in vacuum. When used as a unit of energy, the numerical value of 1 eV in joules (symbol J) is equivalent to the numerical value of the charge of an electron in coulombs (symbol C). Under the 2019 redefinition of the SI base units, this sets 1 eV equal to the exact value Historically, the electronvolt was devised as a standard unit of measure through its usefulness in electrostatic particle accelerator sciences, because a particle with electric charge ''q'' gains an energy after passing through a voltage of ''V.'' Since ''q'' must be an integer multiple of the elementary charge ''e'' for any isolated particle, the gained energy in units of electronvolts conveniently equals that integer times the voltage. It is a common unit of energy within p ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dissociation Energy
The bond-dissociation energy (BDE, ''D''0, or ''DH°'') is one measure of the strength of a chemical bond . It can be defined as the standard enthalpy change when is cleaved by homolysis to give fragments A and B, which are usually radical species. The enthalpy change is temperature-dependent, and the bond-dissociation energy is often defined to be the enthalpy change of the homolysis at 0 K ( absolute zero), although the enthalpy change at 298 K (standard conditions) is also a frequently encountered parameter. As a typical example, the bond-dissociation energy for one of the C−H bonds in ethane () is defined as the standard enthalpy change of the process : , : ''DH''°298() = Δ''H°'' = 101.1(4) kcal/mol = 423.0 ± 1.7 kJ/mol = 4.40(2) eV (per bond). To convert a molar BDE to the energy needed to dissociate the bond ''per molecule'', the conversion factor 23.060 kcal/mol (96.485 kJ/mol) for each eV can be used. A variety of experi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Debye
The debye (symbol: D) (; ) is a CGS unit (a non- SI metric unit) of electric dipole momentTwo equal and opposite charges separated by some distance constitute an electric dipole. This dipole possesses an electric dipole moment whose value is given as charge times length of separation, it is a vector whose direction is in the direction of the unit vector of the position vector of the positive charge w.r.t negative charge: :p = ''q''r. named in honour of the physicist Peter J. W. Debye. It is defined as statcoulomb-centimeters.The statcoulomb is also known as the franklin or electrostatic unit of charge. :1 statC = 1 Fr = 1 esu = 1 cm3/2⋅g1/2⋅s−1. Historically the debye was defined as the dipole moment resulting from two charges of opposite sign but an equal magnitude of 10−10 statcoulomb10−10 statcoulomb corresponds to approximately 0.2083 units of elementary charge. (generally called e.s.u. (electrostatic unit) in older scientific ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Band Head
In spectroscopy a band head is the abrupt edge of a spectroscopic band. When a band is described as degrading to the Violet (color), violet, it means that for wavelengths above the band head wavelength, the spectrum is dark as the band comes to a sudden stop(just above/after the head), and below the wavelength the brightness of the band weakens gradually. A band that degrades to the red, conversely means that the band head is a lower limit on wavelength for the band, and it fades off toward longer wavelengths, which in visible light is the red end of the spectrum. If a band spectrum is examined at high resolution it consists of many Spectral line, lines. At a band head the numbers often increase to a limit, or otherwise a series of lines may approach from one side and then reverse at the band head. The lines pile up on top of each other at the band head, and may not be viewed separately. They have become Spectral resolution, unresolvable. Double head Two bands may overlap with the h ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Paramagnetic
Paramagnetism is a form of magnetism whereby some materials are weakly attracted by an externally applied magnetic field, and form internal, induced magnetic fields in the direction of the applied magnetic field. In contrast with this behavior, diamagnetic materials are repelled by magnetic fields and form induced magnetic fields in the direction opposite to that of the applied magnetic field. Paramagnetic materials include most chemical elements and some compounds; they have a relative magnetic permeability slightly greater than 1 (i.e., a small positive magnetic susceptibility) and hence are attracted to magnetic fields. The magnetic moment induced by the applied field is linear in the field strength and rather weak. It typically requires a sensitive analytical balance to detect the effect and modern measurements on paramagnetic materials are often conducted with a SQUID magnetometer. Paramagnetism is due to the presence of unpaired electrons in the material, so most atoms wi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Torr
The torr (symbol: Torr) is a unit of pressure based on an absolute scale, defined as exactly of a standard atmosphere (). Thus one torr is exactly (≈ ). Historically, one torr was intended to be the same as one "millimeter of mercury", but subsequent redefinitions of the two units made them slightly different (by less than ). The torr is not part of the International System of Units (SI). It is often combined with the metric prefix milli to name one millitorr (mTorr) or 0.001 Torr. The unit was named after Evangelista Torricelli, an Italian physicist and mathematician who discovered the principle of the barometer in 1644. Nomenclature and common errors The unit name ''torr'' is written in lower case, while its symbol ("Torr") is always written with upper-case initial; including in combinations with prefixes and other unit symbols, as in "mTorr" (millitorr) or "Torr⋅L/s" (torr-litres per second). The symbol (uppercase) should be used with prefix symbols (thus, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Methane
Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on Earth makes it an economically attractive fuel, although capturing and storing it poses technical challenges due to its gaseous state under normal conditions for temperature and pressure. Naturally occurring methane is found both below ground and under the seafloor and is formed by both geological and biological processes. The largest reservoir of methane is under the seafloor in the form of methane clathrates. When methane reaches the surface and the atmosphere, it is known as atmospheric methane. The Earth's atmospheric methane concentration has increased by about 150% since 1750, and it accounts for 20% of the total radiative forcing from all of the long-lived and globally mixed greenhouse gases. It has also been detected on other plane ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Propane
Propane () is a three-carbon alkane with the molecular formula . It is a gas at standard temperature and pressure, but compressible to a transportable liquid. A by-product of natural gas processing and petroleum refining, it is commonly used as a fuel in domestic and industrial applications and in low-emissions public transportation. Discovered in 1857 by the French chemist Marcellin Berthelot, it became commercially available in the US by 1911. Propane is one of a group of liquefied petroleum gases (LP gases). The others include butane, propylene, butadiene, butylene, isobutylene, and mixtures thereof. Propane has lower volumetric energy density, but higher gravimetric energy density and burns more cleanly than gasoline and coal. Propane gas has become a popular choice for barbecues and portable stoves because its low −42 °C boiling point makes it vaporise inside pressurised liquid containers (2 phases). Propane powers buses, forklifts, taxis, outboard boat motors, and ic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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