Blossite
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Blossite
Blossite is an anhydrous copper vanadate mineral with the formula: . Blossite was named for mineralogist F. Donald Bloss of Virginia Polytechnic Institute and State University. Natural and synthetic occurrence Blossite was first described for an occurrence in the “Y” fumarole in the summit crater of Izalco Volcano, El Salvador. There it occurs with several high-temperature minerals including: stoiberite, fingerite, ziesite, and mcbirneyite. The natural analogues of these compounds crystallize in the CuO-V2O5 binary system first studied by Brisi and Molinari (1958) and were first discovered as synthetic compounds. Blossite is the low temperature polymorph of ziesite, β-Cu2V2O7. All of the blossite crystals identified to date are inter-grown with other fumarolic copper vanadates. The discovered location of these copper vanadates, in the outer sulfate zone of the fumarole, indicates a sublimation temperature between 100 °C and 200 °C. Physical properties Bloss ...
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Ziesite
Ziesite is a copper vanadate mineral with formula: β-Cu2V2O7. It was discovered in 1980 as monoclinic crystals occurring as volcanic sublimates around fumaroles in the crater of the Izalco Volcano, El Salvador. It is named after Emanuel George Zies (1883–1981), an American geochemist who studied Izalco in the 1930s. Closely related is blossite, also a copper vanadate with formula of α-Cu2V2O7. It forms orthorhombic crystals. Blossite was also first described for specimens from the Izalco volcano. Ziesite and blossite are polymorphs, different crystal structure for the same chemical composition and are quite similar in physical properties. Associated minerals include stoiberite, shcherbinaite, bannermanite, fingerite, mcbirneyite, blossite, chalcocyanite and chalcanthite Chalcanthite (, ) is a richly colored blue-green water-soluble sulfate mineral . It is commonly found in the late-stage oxidation zones of copper deposits. Due to its ready solubility, chalcanth ...
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Izalco Volcano
Izalco is an active stratovolcano on the side of the Santa Ana Volcano, which is located in western El Salvador. It is situated on the southern flank of the Santa Ana volcano. Izalco erupted almost continuously from 1770 (when it formed) to 1958 earning it the nickname of "Lighthouse of the Pacific", and experienced a flank eruption in 1966. During an eruption in 1926, the village of Matazano was buried and 56 people were killed. The volcano erupted on highly arable land which was used for the production of coffee, cacao, and sugar cane. Geology and mineralogy The lava historically erupted from Izalco consists of vesicular vitrophyric olivine basalts. Izalco's formation was preceded by fumorolic activity in 1658, before Izalco was born in 1770. Today, Izalco experiences only fumarolic activity in the form of rainwater seeping into the volcano and contacting hot rocks, rather than steam emissions from underground gases. The fumarole deposits of the volcano are noted as sou ...
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Orthorhombic
In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with a rectangular base (''a'' by ''b'') and height (''c''), such that ''a'', ''b'', and ''c'' are distinct. All three bases intersect at 90° angles, so the three lattice vectors remain mutually orthogonal. Bravais lattices There are four orthorhombic Bravais lattices: primitive orthorhombic, base-centered orthorhombic, body-centered orthorhombic, and face-centered orthorhombic. For the base-centered orthorhombic lattice, the primitive cell has the shape of a right rhombic prism;See , row oC, column Primitive, where the cell parameters are given as a1 = a2, α = β = 90° it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. Note that the length a of the primit ...
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Orthorhombic Minerals
In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with a rectangular base (''a'' by ''b'') and height (''c''), such that ''a'', ''b'', and ''c'' are distinct. All three bases intersect at 90° angles, so the three lattice vectors remain mutually orthogonal. Bravais lattices There are four orthorhombic Bravais lattices: primitive orthorhombic, base-centered orthorhombic, body-centered orthorhombic, and face-centered orthorhombic. For the base-centered orthorhombic lattice, the primitive cell has the shape of a right rhombic prism;See , row oC, column Primitive, where the cell parameters are given as a1 = a2, α = β = 90° it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. Note that the length a of the primiti ...
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Vanadate Minerals
Arsenate minerals usually refer to the naturally occurring orthoarsenates, possessing the (AsO4)3− anion group and, more rarely, other arsenates with anions like AsO3(OH)2− (also written HAsO42−) (example: pharmacolite Ca(AsO3OH).2H2O) or (very rarely) sO2(OH)2sup>− (example: andyrobertsite). Arsenite minerals are much less common. Both the Dana and the Strunz mineral classifications place the arsenates in with the phosphate minerals. Example arsenate minerals include: *Annabergite Ni3(AsO4)2·8H2O *Austinite CaZn(AsO4)(OH) *Clinoclase Cu3(AsO4)(OH)3 *Conichalcite CaCu(AsO4)(OH) *Cornubite Cu5(AsO4)2(OH)4 *Cornwallite Cu2+5(AsO4)2(OH)2 *Erythrite Co3(AsO4)2·8H2O *Mimetite Pb5(AsO4)3Cl *Olivenite Cu2(AsO4)OH Nickel–Strunz Classification -08- Phosphates IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 2009). This list uses it to modify the Classification of Nickel–Strunz ( mindat.org, 10 ed, pending publication). *Abbreviations: **"*" - discredited ( ...
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Copper(II) Minerals
Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orange color. Copper is used as a conductor of heat and electricity, as a building material, and as a constituent of various metal alloys, such as sterling silver used in jewelry, cupronickel used to make marine hardware and coins, and constantan used in strain gauges and thermocouples for temperature measurement. Copper is one of the few metals that can occur in nature in a directly usable metallic form (native metals). This led to very early human use in several regions, from circa 8000 BC. Thousands of years later, it was the first metal to be smelted from sulfide ores, circa 5000 BC; the first metal to be cast into a shape in a mold, c. 4000 BC; and the first metal to be purposely alloyed with another metal, tin, to create bronze, c. 350 ...
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Activation Energy
In chemistry and physics, activation energy is the minimum amount of energy that must be provided for compounds to result in a chemical reaction. The activation energy (''E''a) of a reaction is measured in joules per mole (J/mol), kilojoules per mole (kJ/mol) or kilocalories per mole (kcal/mol). Activation energy can be thought of as the magnitude of the potential barrier (sometimes called the energy barrier) separating minima of the potential energy surface pertaining to the initial and final thermodynamic state. For a chemical reaction to proceed at a reasonable rate, the temperature of the system should be high enough such that there exists an appreciable number of molecules with translational energy equal to or greater than the activation energy. The term "activation energy" was introduced in 1889 by the Swedish scientist Svante Arrhenius. Other uses Although less commonly used, activation energy also applies to nuclear reactions and various other physical phenomena. Te ...
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Volcanic Sublimate
A volcano is a rupture in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface. On Earth, volcanoes are most often found where tectonic plates are diverging or converging, and most are found underwater. For example, a mid-ocean ridge, such as the Mid-Atlantic Ridge, has volcanoes caused by divergent tectonic plates whereas the Pacific Ring of Fire has volcanoes caused by convergent tectonic plates. Volcanoes can also form where there is stretching and thinning of the crust's plates, such as in the East African Rift and the Wells Gray-Clearwater volcanic field and Rio Grande rift in North America. Volcanism away from plate boundaries has been postulated to arise from upwelling diapirs from the core–mantle boundary, deep in the Earth. This results in hotspot volcanism, of which the Hawaiian hotspot is an example. Volcanoes are usually not created where two tectonic plates slide pa ...
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Polymorphism (materials Science)
In materials science, polymorphism describes the existence of a solid material in more than one form or crystal structure. Polymorphism is a form of isomerism. Any crystalline material can exhibit the phenomenon. Allotropy refers to polymorphism for chemical elements. Polymorphism is of practical relevance to pharmaceuticals, agrochemicals, pigments, dyestuffs, foods, and explosives. According to IUPAC, a polymorphic transition is "A reversible transition of a solid crystalline phase at a certain temperature and pressure (the inversion point) to another phase of the same chemical composition with a different crystal structure." According to McCrone, polymorphs are "different in crystal structure but identical in the liquid or vapor states." Materials with two polymorphs are called dimorphic, with three polymorphs, trimorphic, etc. Examples Many compounds exhibit polymorphism. It has been claimed that "every compound has different polymorphic forms, and that, in general, the n ...
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Fingerite
Fingerite is a copper vanadate mineral with formula: β-Cu2V2O5. It was discovered as triclinic crystals occurring as volcanic sublimates around fumaroles in the crater of the Izalco Volcano, El Salvador. Associated minerals include thenardite, euchlorine, stoiberite, shcherbinaite, ziesite, bannermanite, chalcocyanite and chalcanthite Chalcanthite (, ) is a richly colored blue-green water-soluble sulfate mineral . It is commonly found in the late-stage oxidation zones of copper deposits. Due to its ready solubility, chalcanthite is more common in arid regions. Chalcanthite i .... The mineral also dissolves in water. Fingerite is named for Dr. Larry W. Finger (b. 1940) of the Geophysical Laboratory, Carnegie Institution of Washington. References Copper minerals Vanadate minerals Triclinic minerals Minerals in space group 2 {{Oxide-mineral-stub ...
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