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Bis-triazinyl Bipyridine
The ''bis''-triazinyl bipyridines (BTBPs) are a class of chemical compounds which are tetradentate ligands similar in shape to quaterpyridine. The BTBPs are made by the reaction of hydrazine and a 1,2-diketone (such as hexane-3,4-dione) with 6,6'-dicyano-2,2'-bipyridine. The dicyanobipy can be made by reacting 2,2'- bipy with hydrogen peroxide in acetic acid, (followed by the addition of acetone) to form 2,2'-bipyridine-''N,N''-dioxide. The 2,2'-bipyridine-''N,N''-dioxide is then converted into the dicyano compound by treatment with potassium cyanide and benzoyl chloride in a mixture of water and THF. The BTBPs were first reported as synthetic intermediates in the synthesis of quaterpyridines by a Diels-Alder reaction of the triazine ring with tributylstannyl acetylene or norbornadiene, after the Diels-Alder reaction a series of other reactions cause the adjunct to lose a molecule of nitrogen and a molecule of cyclopentadiene to form the pyridine ring. The BTBPs are relat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bis-triazinyl Bipyridine
The ''bis''-triazinyl bipyridines (BTBPs) are a class of chemical compounds which are tetradentate ligands similar in shape to quaterpyridine. The BTBPs are made by the reaction of hydrazine and a 1,2-diketone (such as hexane-3,4-dione) with 6,6'-dicyano-2,2'-bipyridine. The dicyanobipy can be made by reacting 2,2'- bipy with hydrogen peroxide in acetic acid, (followed by the addition of acetone) to form 2,2'-bipyridine-''N,N''-dioxide. The 2,2'-bipyridine-''N,N''-dioxide is then converted into the dicyano compound by treatment with potassium cyanide and benzoyl chloride in a mixture of water and THF. The BTBPs were first reported as synthetic intermediates in the synthesis of quaterpyridines by a Diels-Alder reaction of the triazine ring with tributylstannyl acetylene or norbornadiene, after the Diels-Alder reaction a series of other reactions cause the adjunct to lose a molecule of nitrogen and a molecule of cyclopentadiene to form the pyridine ring. The BTBPs are relat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Acetylene
Acetylene (systematic name: ethyne) is the chemical compound with the formula and structure . It is a hydrocarbon and the simplest alkyne. This colorless gas is widely used as a fuel and a chemical building block. It is unstable in its pure form and thus is usually handled as a solution. Pure acetylene is odorless, but commercial grades usually have a marked odor due to impurities such as divinyl sulfide and phosphine.Compressed Gas Association (1995Material Safety and Data Sheet – Acetylene As an alkyne, acetylene is unsaturated because its two carbon atoms are bonded together in a triple bond. The carbon–carbon triple bond places all four atoms in the same straight line, with CCH bond angles of 180°. Discovery Acetylene was discovered in 1836 by Edmund Davy, who identified it as a "new carburet of hydrogen". It was an accidental discovery while attempting to isolate potassium metal. By heating potassium carbonate with carbon at very high temperatures, he produced a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Crystallography
Crystallography is the experimental science of determining the arrangement of atoms in crystalline solids. Crystallography is a fundamental subject in the fields of materials science and solid-state physics (condensed matter physics). The word "crystallography" is derived from the Greek word κρύσταλλος (''krystallos'') "clear ice, rock-crystal", with its meaning extending to all solids with some degree of transparency, and γράφειν (''graphein'') "to write". In July 2012, the United Nations recognised the importance of the science of crystallography by proclaiming that 2014 would be the International Year of Crystallography. denote a direction vector (in real space). * Coordinates in ''angle brackets'' or ''chevrons'' such as <100> denote a ''family'' of directions which are related by symmetry operations. In the cubic crystal system for example, would mean 00 10 01/nowiki> or the negative of any of those directions. * Miller indices in ''parentheses'' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
X-ray
An X-ray, or, much less commonly, X-radiation, is a penetrating form of high-energy electromagnetic radiation. Most X-rays have a wavelength ranging from 10 picometers to 10 nanometers, corresponding to frequencies in the range 30 petahertz to 30 exahertz ( to ) and energies in the range 145 eV to 124 keV. X-ray wavelengths are shorter than those of UV rays and typically longer than those of gamma rays. In many languages, X-radiation is referred to as Röntgen radiation, after the German scientist Wilhelm Conrad Röntgen, who discovered it on November 8, 1895. He named it ''X-radiation'' to signify an unknown type of radiation.Novelline, Robert (1997). ''Squire's Fundamentals of Radiology''. Harvard University Press. 5th edition. . Spellings of ''X-ray(s)'' in English include the variants ''x-ray(s)'', ''xray(s)'', and ''X ray(s)''. The most familiar use of X-rays is checking for fractures (broken bones), but X-rays are also used in other ways. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Integrated Project (EU)
The Framework Programmes for Research and Technological Development, also called Framework Programmes or abbreviated FP1 to FP9, are funding programmes created by the European Union/European Commission to support and foster research in the European Research Area (ERA). Starting in 2014, the funding programmes were named Horizon. The funding programmes began in 1984 and continue to the present day. The most recent programme, Horizon Europe, has a budget of 95.5 billion Euros to be distributed over 7 years. The specific objectives and actions vary between funding periods. In FP6 and FP7, focus was on technological research. In Horizon 2020, the focus was on innovation, delivering economic growth faster, and delivering solutions to end users that are often governmental agencies. Background Conducting European research policies and implementing European research programmes is an obligation under the Amsterdam Treaty, which includes a chapter on research and technological development. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nuclear Reprocessing
Nuclear reprocessing is the chemical separation of fission products and actinides from spent nuclear fuel. Originally, reprocessing was used solely to extract plutonium for producing nuclear weapons. With commercialization of nuclear power, the reprocessed plutonium was recycled back into MOX nuclear fuel for thermal reactors. The reprocessed uranium, also known as the spent fuel material, can in principle also be re-used as fuel, but that is only economical when uranium supply is low and prices are high. A breeder reactor is not restricted to using recycled plutonium and uranium. It can employ all the actinides, closing the nuclear fuel cycle and potentially multiplying the energy extracted from natural uranium by about 60 times. Reprocessing must be highly controlled and carefully executed in advanced facilities by highly specialized personnel. Fuel bundles which arrive at the sites from nuclear power plants (after having cooled down for several years) are completely dissolv ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
European Union
The European Union (EU) is a supranational political and economic union of member states that are located primarily in Europe. The union has a total area of and an estimated total population of about 447million. The EU has often been described as a '' sui generis'' political entity (without precedent or comparison) combining the characteristics of both a federation and a confederation. Containing 5.8per cent of the world population in 2020, the EU generated a nominal gross domestic product (GDP) of around trillion in 2021, constituting approximately 18per cent of global nominal GDP. Additionally, all EU states but Bulgaria have a very high Human Development Index according to the United Nations Development Programme. Its cornerstone, the Customs Union, paved the way to establishing an internal single market based on standardised legal framework and legislation that applies in all member states in those matters, and only those matters, where the states have agreed to act ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Berkshire
Berkshire ( ; in the 17th century sometimes spelt phonetically as Barkeshire; abbreviated Berks.) is a historic county in South East England. One of the home counties, Berkshire was recognised by Queen Elizabeth II as the Royal County of Berkshire in 1957 because of the presence of Windsor Castle, and letters patent were issued in 1974. Berkshire is a county of historic origin, a ceremonial county and a non-metropolitan county without a county council. The county town is Reading. The River Thames formed the historic northern boundary, from Buscot in the west to Old Windsor in the east. The historic county, therefore, includes territory that is now administered by the Vale of White Horse and parts of South Oxfordshire in Oxfordshire, but excludes Caversham, Slough and five less populous settlements in the east of the Royal Borough of Windsor and Maidenhead. All the changes mentioned, apart from the change to Caversham, took place in 1974. The towns of Abingdon, Didcot, Far ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Reading, Berkshire
Reading ( ) is a town and borough in Berkshire, Southeast England, southeast England. Located in the Thames Valley at the confluence of the rivers River Thames, Thames and River Kennet, Kennet, the Great Western Main Line railway and the M4 motorway serve the town. Reading is east of Swindon, south of Oxford, west of London and north of Basingstoke. Reading is a major commercial centre, especially for information technology and insurance. It is also a regional retail centre, serving a large area of the Thames Valley with its shopping centre, the The Oracle, Reading, Oracle. It is home to the University of Reading. Every year it hosts the Reading and Leeds Festivals, Reading Festival, one of England's biggest music festivals. Reading has a professional association football team, Reading F.C., and participates in many other sports. Reading dates from the 8th century. It was an important trading and ecclesiastical centre in the Middle Ages, the site of Reading Abbey, one of th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
