Bioavailability (soil)
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Bioavailability (soil)
Bioavailability, in environmental and soil sciences, represents the amount of an element or compound that is accessible to an organism for uptake or adsorption across its cellular membrane.American Society for Testing and Materials (ASTM). 1998. Standard guide for conducting laboratory soil toxicity or bioaccumulation test with the lumbricid earthworm ''Eisenia foetida''. E 1676-97. Philadelphia, PA: ASTM.Casarett, & Doull. 2001. Toxicology. ''The Basic Science of Poisons'', Sixth Edition. C. D. Klaassen (ed.)Semple, K. T., Doick, K. J., Jones, K. C., Burauel, P., Craven, A., & Harms, H. 2004. Peer reviewed: defining bioavailability and bioaccessibility of contaminated soil and sediment is complicated. ''Environmental Science & Technology'', 38(12), 228A-231A. New York: McGraw-Hill. In environmental and agricultural applications, bioavailability most often refers to availability of contaminants, such as organic pollutants or heavy metals, in soil systems and is also used frequently ...
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Soil Science
Soil science is the study of soil as a natural resource on the surface of the Earth including soil formation, classification and mapping; physical, chemical, biological, and fertility properties of soils; and these properties in relation to the use and management of soils.Jackson, J. A. (1997). Glossary of Geology (4. ed.). Alexandria, Virginia: American Geological Institute. p 604. Sometimes terms which refer to branches of soil science, such as pedology (formation, chemistry, morphology, and classification of soil) and edaphology (how soils interact with living things, especially plants), are used as if synonymous with soil science. The diversity of names associated with this discipline is related to the various associations concerned. Indeed, engineers, agronomists, chemists, geologists, physical geographers, ecologists, biologists, microbiologists, silviculturists, sanitarians, archaeologists, and specialists in regional planning, all contribute to further knowledge ...
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Precipitation (chemistry)
In an aqueous solution, precipitation is the process of transforming a dissolved chemical substance, substance into an insoluble solid from a Supersaturated solution, super-saturated solution. The solid formed is called the precipitate. In case of an inorganic chemical reaction leading to precipitation, the chemical reagent causing the solid to form is called the ''precipitant''. The clear liquid remaining above the precipitated or the centrifuged solid phase is also called the 'supernate' or 'supernatant'. The notion of precipitation can also be extended to other domains of chemistry (organic chemistry and biochemistry) and even be applied to the solid phases (''e.g.'', metallurgy and alloys) when solid impurities Segregation (materials science), segregate from a solid phase. Supersaturation The precipitation of a compound may occur when its concentration exceeds its solubility. This can be due to temperature changes, solvent evaporation, or by mixing solvents. Precipitatio ...
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Fugacity
In chemical thermodynamics, the fugacity of a real gas is an effective partial pressure which replaces the mechanical partial pressure in an accurate computation of the chemical equilibrium constant. It is equal to the pressure of an ideal gas which has the same temperature and molar Gibbs free energy as the real gas. Fugacities are determined experimentally or estimated from various models such as a Van der Waals gas that are closer to reality than an ideal gas. The real gas pressure and fugacity are related through the dimensionless fugacity coefficient . \varphi = \frac For an ideal gas, fugacity and pressure are equal and so . Taken at the same temperature and pressure, the difference between the molar Gibbs free energies of a real gas and the corresponding ideal gas is equal to . The fugacity is closely related to the thermodynamic activity. For a gas, the activity is simply the fugacity divided by a reference pressure to give a dimensionless quantity. This reference press ...
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Solid Phase Extraction
Solid-phase extraction (SPE) is an extractive technique by which compounds that are dissolved or suspended in a liquid mixture are separated from other compounds in the mixture according to their physical and chemical properties. Analytical laboratories use solid phase extraction to concentrate and purify samples for analysis. Solid phase extraction can be used to isolate analytes of interest from a wide variety of matrices, including urine, blood, water, beverages, soil, and animal tissue. SPE uses the affinity of solutes dissolved or suspended in a liquid (known as the mobile phase) for a solid through which the sample is passed (known as the stationary phase) to separate a mixture into desired and undesired components. The result is that either the desired analytes of interest or undesired impurities in the sample are retained on the stationary phase. The portion that passes through the stationary phase is collected or discarded, depending on whether it contains the desired ...
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Eisenia Fetida
''Eisenia fetida'', known under various common names such as manure worm, redworm, brandling worm, panfish worm, trout worm, tiger worm, red wiggler worm, etc., is a species of earthworm adapted to decaying organic material. These worms thrive in rotting vegetation, compost, and manure. They are epigean, rarely found in soil. In this trait, they resemble ''Lumbricus rubellus''. Red wigglers are reddish-brown in color, haveĀ small rings around their body and haveĀ a yellowish tail. They have groups of bristles (called setae) on each segment that move in and out to grip nearby surfaces as the worms stretch and contract their muscles to push themselves forward or backward. ''Eisenia fetida'' worms are native to Europe, but have been introduced (both intentionally and unintentionally) to every other continent except Antarctica. ''Eisenia fetida'' also possess a unique natural defense system in their coelomic fluid: cells called coelomocytes secrete a protein called lysenin, wh ...
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Bioaccumulation
Bioaccumulation is the gradual accumulation of substances, such as pesticides or other chemicals, in an organism. Bioaccumulation occurs when an organism absorbs a substance at a rate faster than that at which the substance is lost or eliminated by catabolism and excretion. Thus, the longer the biological half-life of a toxic substance, the greater the risk of chronic poisoning, even if environmental levels of the toxin are not very high. Bioaccumulation, for example in fish, can be predicted by models. Hypothesis for molecular size cutoff criteria for use as bioaccumulation potential indicators are not supported by data. Biotransformation can strongly modify bioaccumulation of chemicals in an organism. Toxicity induced by metals is associated with bioaccumulation and biomagnification. Storage or uptake of metals faster than the rate at which an organism metabolizes and excretes lead to the accumulation of that metal. The presence of various chemicals and harmful substances in ...
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Soil Water (retention)
Soils can process and hold considerable amounts of water. They can take in water, and will keep doing so until they are full, or until the rate at which they can transmit water into and through the pores is exceeded. Some of this water will steadily drain through the soil (via gravity) and end up in the waterways and streams, but much of it will be retained, despite the influence of gravity. Much of this retained water can be used by plants and other organisms, also contributing to land productivity and soil health. Soil water retention capacity Pores (the spaces that exist between soil particles) provide for the passage and/or retention of gasses and moisture within the soil profile. The soil's ability to retain water is strongly related to particle size; water molecules hold more tightly to the fine particles of a clay soil than to coarser particles of a sandy soil, so clays generally retain more water.Leeper, G.W. & Uren, N.C., 1993. ''Soil Science: An Introduction'', 5th edn. Me ...
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Soil Porosity
The pore space of soil contains the liquid and gas phases of soil, i.e., everything but the solid phase that contains mainly minerals of varying sizes as well as organic compounds. In order to understand porosity better a series of equations have been used to express the quantitative interactions between the three phases of soil. Macropores or fractures play a major role in infiltration rates in many soils as well as preferential flow patterns, hydraulic conductivity and evapotranspiration. Cracks are also very influential in gas exchange, influencing respiration within soils. Modeling cracks therefore helps understand how these processes work and what the effects of changes in soil cracking such as compaction, can have on these processes. The pore space of soil may contain the habitat of plants (rhizosphere) and microorganisms. Background Bulk density \rho = \frac The bulk density of soil depends greatly on the mineral make up of soil and the degree of compaction. The d ...
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Soil Texture
Soil texture is a classification instrument used both in the field and laboratory to determine soil classes based on their physical texture. Soil texture can be determined using qualitative methods such as texture by feel, and quantitative methods such as the hydrometer method based on Stokes' law. Soil texture has agricultural applications such as determining crop suitability and to predict the response of the soil to environmental and management conditions such as drought or calcium (lime) requirements. Soil texture focuses on the particles that are less than two millimeters in diameter which include sand, silt, and clay. The USDA soil taxonomy and WRB soil classification systems use 12 textural classes whereas the UK-ADAS system uses 11.''Soil Science Division Staff. 2017. Soil survey sand. C. Ditzler, K. Scheffe, and H.C. Monger (eds.). USDA Handbook 18. Government Printing Office, Washington, D.C.'' These classifications are based on the percentages of sand, silt, and clay ...
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Soil Organic Matter
Soil organic matter (SOM) is the organic matter component of soil, consisting of plant and animal detritus at various stages of decomposition, cells and tissues of soil microbes, and substances that soil microbes synthesize. SOM provides numerous benefits to the physical and chemical properties of soil and its capacity to provide regulatory ecosystem services. SOM is especially critical for soil functions and quality. The benefits of SOM result from a number of complex, interactive, edaphic factors; a non-exhaustive list of these benefits to soil function includes improvement of soil structure, aggregation, water retention, soil biodiversity, absorption and retention of pollutants, buffering capacity, and the cycling and storage of plant nutrients. SOM increases soil fertility by providing cation exchange sites and being a reserve of plant nutrients, especially nitrogen (N), phosphorus (P), and sulfur (S), along with micronutrients, which the mineralization of SOM slowly release ...
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Ion Exchange
Ion exchange is a reversible interchange of one kind of ion present in an insoluble solid with another of like charge present in a solution surrounding the solid with the reaction being used especially for softening or making water demineralised, the purification of chemicals and separation of substances. Ion exchange usually describes a process of purification of aqueous solutions using solid polymeric ion-exchange resin. More precisely, the term encompasses a large variety of processes where ions are exchanged between two electrolytes. Aside from its use to purify drinking water, the technique is widely applied for purification and separation of a variety of industrially and medicinally important chemicals. Although the term usually refers to applications of synthetic (man-made) resins, it can include many other materials such as soil. Typical ion exchangers are ion-exchange resins (functionalized porous or gel polymer), zeolites, montmorillonite, clay, and soil humus. Ion exc ...
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Soil PH
Soil pH is a measure of the acidity or basicity (alkalinity) of a soil. Soil pH is a key characteristic that can be used to make informative analysis both qualitative and quantitatively regarding soil characteristics. pH is defined as the negative logarithm (base 10) of the activity of hydronium ions ( or, more precisely, ) in a solution. In soils, it is measured in a slurry of soil mixed with water (or a salt solution, such as  ), and normally falls between 3 and 10, with 7 being neutral. Acid soils have a pH below 7 and alkaline soils have a pH above 7. Ultra-acidic soils (pH 9) are rare. Soil pH is considered a master variable in soils as it affects many chemical processes. It specifically affects plant nutrient Plant nutrition is the study of the chemical elements and compounds necessary for plant growth and reproduction, plant metabolism and their external supply. In its absence the plant is unable to complete a normal life cycle, or that the element i ... ...
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