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Bararite
Bararite is a natural form of ammonium fluorosilicate (also known as hexafluorosilicate or fluosilicate). It has chemical formula (NH4)2SiF6 and Trigonal crystal system, trigonal crystal structure. This mineral was once classified as part of cryptohalite. Bararite is named after the place where it was first described, Barari, India.Palache, C., Berman, H., and Frondel, C. (1951) Dana’s System of Mineralogy, Volume II: Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, etc. John Wiley and Sons, Inc., New York, 7th edition. It is found at the fumaroles of volcanoes (Vesuvius, Italy), over Coal seam fire, burning coal seams (Barari, India), and in burning piles of anthracite (Pennsylvania, United States, U.S.). It is a Volcanic sublimate, sublimation product that forms with cryptohalite, sal ammoniac, and native sulfur.Anthony, J.W., Bideaux, R.A., Bladh, K.W., and Nichols, M.C. (1997) Handbook of Mineralogy, Volume III: Halides, Hydroxid ...
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Halide Mineral
Halide minerals are those minerals with a dominant halide anion (, , and ). Complex halide minerals may also have polyatomic anions. Examples include the following: *Atacamite * Avogadrite (K,Cs)BF *Bararite (β) *Bischofite * Brüggenite *Calomel *Carnallite *Carnallite * Cerargyrite/Horn silver AgCl * Chlorargyrite AgCl, bromargyrite AgBr, and iodargyrite AgI *Cryolite *Cryptohalite (a) Vanadates), 09 Silicates: * ''neso-'': insular (from Greek , "island") * ''soro-'': grouped (from Greek , "heap, pile, mound") * ''cyclo-'': ringed (from Greek , "circle") * ''ino-'': chained (from Greek , "fibre", rom Ancient Greek * ''phyllo-'': sheeted (from Greek , "leaf") * ''tecto-'': of three-dimensional framework (from Greek , "of building") ;Nickel–Strunz code scheme ''NN.XY.##x'': * ''NN'': Nickel–Strunz mineral class number * ''X'': Nickel–Strunz mineral division letter * ''Y'': Nickel–Strunz mineral family letter * ''##x'': Nickel–Strunz mineral/group n ...
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Hexafluorosilicic Acid
Hexafluorosilicic acid is an inorganic compound with the chemical formula . Aqueous solutions of hexafluorosilicic acid consist of salts of the cation and hexafluorosilicate anion. These salts and their aqueous solutions are colorless. Hexafluorosilicic acid is produced naturally on a large scale in volcanoes.Palache, C., Berman, H., and Frondel, C. (1951) Dana’s System of Mineralogy, Volume II: Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, etc. John Wiley and Sons, Inc., New York, 7th edition.Anthony, J.W., Bideaux, R.A., Bladh, K.W., and Nichols, M.C. (1997) Handbook of Mineralogy, Volume III: Halides, Hydroxides, Oxides. Mineral Data Publishing, Tucson.link to bararite It is manufactured as a coproduct in the production of phosphate fertilizers. The resulting hexafluorosilicic acid is almost exclusively consumed as a precursor to aluminum trifluoride and synthetic cryolite, which are used in aluminium processing. Salts der ...
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Cryptohalite
Ammonium fluorosilicate (also known as ammonium hexafluorosilicate, ammonium fluosilicate or ammonium silicofluoride) has the formula (NH4)2SiF6. It is a toxic chemical, like all salts of fluorosilicic acid.Wiberg, E., Wiberg, N., and Holleman, A. F. (2001) ''Inorganic chemistry''. Academic Press, San Diego. It is made of white crystals, which have at least three Polymorphism (materials science), polymorphs and appears in nature as rare minerals cryptohalite or bararite. Structure Ammonium fluorosilicate has three major Polymorphism (materials science), polymorphs: α-(NH4)2[SiF6] form is Cubic crystal system, cubic (space group Fm3m, No. 225) and corresponds to the mineral cryptohalite. The β form is Trigonal crystal system, trigonal (scalenohedral) and occurs in nature as mineral bararite. A third (γ) form was discovered in 2001 and identified with the Hexagonal crystal system, hexagonal 6mm symmetry. In all three configurations, the [SiF6]2− VSEPR theory, octahedra are arra ...
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Ammonium Fluorosilicate
Ammonium fluorosilicate (also known as ammonium hexafluorosilicate, ammonium fluosilicate or ammonium silicofluoride) has the formula (NH4)2SiF6. It is a toxic chemical, like all salts of fluorosilicic acid.Wiberg, E., Wiberg, N., and Holleman, A. F. (2001) ''Inorganic chemistry''. Academic Press, San Diego. It is made of white crystals, which have at least three polymorphs and appears in nature as rare minerals cryptohalite or bararite. Structure Ammonium fluorosilicate has three major polymorphs: α-(NH4)2 iF6form is cubic (space group Fm3m, No. 225) and corresponds to the mineral cryptohalite. The β form is trigonal (scalenohedral) and occurs in nature as mineral bararite. A third (γ) form was discovered in 2001 and identified with the hexagonal 6mm symmetry. In all three configurations, the iF6sup>2− octahedra are arranged in layers. In the α form, these layers are perpendicular to 11directions. In the β- and γ- forms, the layers are perpendicular to the c-axis. ...
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Ammonium Fluorosilicate
Ammonium fluorosilicate (also known as ammonium hexafluorosilicate, ammonium fluosilicate or ammonium silicofluoride) has the formula (NH4)2SiF6. It is a toxic chemical, like all salts of fluorosilicic acid.Wiberg, E., Wiberg, N., and Holleman, A. F. (2001) ''Inorganic chemistry''. Academic Press, San Diego. It is made of white crystals, which have at least three polymorphs and appears in nature as rare minerals cryptohalite or bararite. Structure Ammonium fluorosilicate has three major polymorphs: α-(NH4)2 iF6form is cubic (space group Fm3m, No. 225) and corresponds to the mineral cryptohalite. The β form is trigonal (scalenohedral) and occurs in nature as mineral bararite. A third (γ) form was discovered in 2001 and identified with the hexagonal 6mm symmetry. In all three configurations, the iF6sup>2− octahedra are arranged in layers. In the α form, these layers are perpendicular to 11directions. In the β- and γ- forms, the layers are perpendicular to the c-axis. ...
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Barium Sulfate
Barium sulfate (or sulphate) is the inorganic compound with the chemical formula Ba SO4. It is a white crystalline solid that is odorless and insoluble in water. It occurs as the mineral barite, which is the main commercial source of barium and materials prepared from it. The white opaque appearance and its high density are exploited in its main applications.Holleman, A. F. and Wiberg, E. (2001) ''Inorganic Chemistry'', San Diego, CA : Academic Press, . Uses Drilling fluids About 80% of the world's barium sulfate production, mostly purified mineral, is consumed as a component of oil well drilling fluid. It increases the density of the fluid, increasing the hydrostatic pressure in the well and reducing the chance of a blowout. Radiocontrast agent Barium sulfate in suspension is often used medically as a radiocontrast agent for X-ray imaging and other diagnostic procedures. It is most often used in imaging of the GI tract during what is colloquially known as a "barium meal". ...
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Calcium Fluoride
Calcium fluoride is the inorganic compound of the elements calcium and fluorine with the formula CaF2. It is a white insoluble solid. It occurs as the mineral fluorite (also called fluorspar), which is often deeply coloured owing to impurities. Chemical structure The compound crystallizes in a cubic motif called the fluorite structure. Ca2+ centres are eight-coordinate, being centered in a cube of eight F− centres. Each F− centre is coordinated to four Ca2+ centres in the shape of a tetrahedron. Although perfectly packed crystalline samples are colorless, the mineral is often deeply colored due to the presence of F-centers. The same crystal structure is found in numerous ionic compounds with formula AB2, such as CeO2, cubic ZrO2, UO2, ThO2, and PuO2. In the corresponding anti-structure, called the antifluorite structure, anions and cations are swapped, such as Be2C. Gas phase The gas phase is noteworthy for failing the predictions of VSEPR theory; the molecule is no ...
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Locality (India)
Locality may refer to: * Locality (association), an association of community regeneration organizations in England * Locality (linguistics) * Locality (settlement) * Suburbs and localities (Australia), in which a locality is a geographic subdivision in rural areas of Australia Science * Locality (astronomy) * Locality of reference, in computer science * Locality (statistics) * Principle of locality, in physics See also * Local (other) * Type locality (other) Type locality may refer to: * Type locality (biology) * Type locality (geology) See also * Local (other) * Locality (other) {{disambiguation ...
{{disambiguation ...
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United States
The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country primarily located in North America. It consists of 50 states, a federal district, five major unincorporated territories, nine Minor Outlying Islands, and 326 Indian reservations. The United States is also in free association with three Pacific Island sovereign states: the Federated States of Micronesia, the Marshall Islands, and the Republic of Palau. It is the world's third-largest country by both land and total area. It shares land borders with Canada to its north and with Mexico to its south and has maritime borders with the Bahamas, Cuba, Russia, and other nations. With a population of over 333 million, it is the most populous country in the Americas and the third most populous in the world. The national capital of the United States is Washington, D.C. and its most populous city and principal financial center is New York City. Paleo-Americ ...
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Coal Mining In India
Coal in India has been mined since 1774, and India is the second largest producer and consumer of coal after China, mining in FY 2022. Around 30% of coal is imported. Due to high demand and poor average quality, India imports coking coal to meet the requirements of its steel plants. Dhanbad, the largest coal producing city, has been called the coal capital of India. State-owned Coal India had a monopoly on coal mining between its nationalisation in 1973 and 2018. Most of the coal is burned to generate electricity and most electricity is generated by coal, but coal-fired power plants have been criticised for breaking environmental laws. The health and environmental impact of the coal industry is serious, and phasing out coal would have short-term health and environmental benefits greatly exceeding the costs. Electricity from new solar farms in India is cheaper than that generated by the country's existing coal plants. History The Indira Gandhi administration nationalized ...
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Ammonia
Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous waste, particularly among aquatic organisms, and it contributes significantly to the nutritional needs of terrestrial organisms by serving as a precursor to 45% of the world's food and fertilizers. Around 70% of ammonia is used to make fertilisers in various forms and composition, such as urea and Diammonium phosphate. Ammonia in pure form is also applied directly into the soil. Ammonia, either directly or indirectly, is also a building block for the synthesis of many pharmaceutical products and is used in many commercial cleaning products. It is mainly collected by downward displacement of both air and water. Although common in nature—both terrestrially and in the outer planets of the Solar System—and in wide use, ammonia is both caust ...
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Sodium Hydroxide
Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations and hydroxide anions . Sodium hydroxide is a highly caustic base and alkali that decomposes proteins at ordinary ambient temperatures and may cause severe chemical burns. It is highly soluble in water, and readily absorbs moisture and carbon dioxide from the air. It forms a series of hydrates . The monohydrate crystallizes from water solutions between 12.3 and 61.8 °C. The commercially available "sodium hydroxide" is often this monohydrate, and published data may refer to it instead of the anhydrous compound. As one of the simplest hydroxides, sodium hydroxide is frequently used alongside neutral water and acidic hydrochloric acid to demonstrate the pH scale to chemistry students. Sodium hydroxide is used in many industries: in the manufacture of pulp and paper, textiles, drinking water, soaps and deterge ...
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