Azurite
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Azurite
Azurite is a soft, deep-blue copper mineral produced by weathering of copper ore deposits. During the early 19th century, it was also known as chessylite, after the type locality at Chessy-les-Mines near Lyon, France. The mineral, a basic carbonate with the chemical formula Cu3(CO3)2(OH)2, has been known since ancient times, and was mentioned in Pliny the Elder's '' Natural History'' under the Greek name (κυανός: "deep blue," root of English ''cyan'') and the Latin name ''caeruleum''. Since antiquity, azurite's exceptionally deep and clear blue has been associated with low-humidity desert and winter skies. The modern English name of the mineral reflects this association, since both ''azurite'' and ''azure'' are derived via Arabic from the Persian (لاژورد), an area known for its deposits of another deep-blue stone, lapis lazuli ("stone of azure"). Mineralogy Azurite has the formula Cu3(CO3)2(OH)2, with the copper(II) cations linked to two different anions, ca ...
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Azurite Crystal Structure
Azurite is a soft, deep-blue copper mineral produced by weathering of copper ore deposits. During the early 19th century, it was also known as chessylite, after the type locality at Chessy-les-Mines near Lyon, France. The mineral, a basic carbonate with the chemical formula Cu3(CO3)2(OH)2, has been known since ancient times, and was mentioned in Pliny the Elder's '' Natural History'' under the Greek name (κυανός: "deep blue," root of English ''cyan'') and the Latin name ''caeruleum''. Since antiquity, azurite's exceptionally deep and clear blue has been associated with low-humidity desert and winter skies. The modern English name of the mineral reflects this association, since both ''azurite'' and ''azure'' are derived via Arabic from the Persian (لاژورد), an area known for its deposits of another deep-blue stone, lapis lazuli ("stone of azure"). Mineralogy Azurite has the formula Cu3(CO3)2(OH)2, with the copper(II) cations linked to two different anions, carbona ...
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Lapis Lazuli
Lapis lazuli (; ), or lapis for short, is a deep-blue metamorphic rock used as a semi-precious stone that has been prized since antiquity for its intense color. As early as the 7th millennium BC, lapis lazuli was mined in the Sar-i Sang mines,David Bomford and Ashok Roy, ''A Closer Look- Colour'' (2009), National Gallery Company, London, () in Shortugai, and in other mines in Badakhshan province in northeast Afghanistan. Lapis lazuli artifacts, dated to 7570 BC, have been found at Bhirrana, which is the oldest site of Indus Valley civilisation. Lapis was highly valued by the Indus Valley Civilisation (7570–1900 BC). Lapis beads have been found at Neolithic burials in Mehrgarh, the Caucasus, and as far away as Mauritania. It was used in the funeral mask of Tutankhamun (1341–1323 BC). By the end of the Middle Ages, lapis lazuli began to be exported to Europe, where it was ground into powder and made into ultramarine, the finest and most expensive of all blue pigments ...
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Chessy, Rhône
Chessy (), also known as Chessy-les-Mines (), is a commune in the Rhône department in eastern France. Chessy-les-Mines is the type locality of the mineral azurite, also known as "chessylite." The species was redescribed and renamed in 1824 by François-Sulpice Beudant (1787–1850), French mineralogist and geologist.Muséum national d'histoire naturelle


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Malachite
Malachite is a copper carbonate hydroxide mineral, with the formula Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses, in fractures and deep, underground spaces, where the water table and hydrothermal fluids provide the means for chemical precipitation. Individual crystals are rare, but occur as slender to acicular prisms. Pseudomorphs after more tabular or blocky azurite crystals also occur. Etymology and history The stone's name derives (via la, molochītis, frm, melochite, and Middle English ''melochites'') from Greek Μολοχίτης λίθος ''molochites lithos'', "mallow-green stone", from μολόχη ''molochē'', variant of μαλάχη ''malāchē'', "mallow". The mineral was given this name due to its resemblance to the leaves of the mallow plant. Malachite was mined from deposits near the Isthmus of Suez and the Sinai as early as 4000 BCE. ...
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Azure (color)
Azure ( , ) is the color between cyan and blue on the spectrum of visible light. It is often described as the color of the sky on a clear day. On the RGB color wheel, "azure" (hexadecimal #0080FF) is defined as the color at 210 degrees, i.e., the hue halfway between blue and cyan. In the RGB color model, used to create all the colors on a television or computer screen, azure is created by adding a 50% of green light to a 100% of blue light. In the X11 color system, which became a model for early web colors, azure is depicted as a pale cyan or white cyan. Etymology and history The color azure ultimately takes its name from the intense blue mineral lapis lazuli. ' is the Latin word for "stone" and ' is the genitive form of the Medieval Latin ', which is taken from the Arabic ''lāzaward'', itself from the Persian ''lāžaward'', which is the name of the stone in Persian and also of a place where lapis lazuli was mined. The name of the stone came to be associated ...
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Copper
Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orange color. Copper is used as a conductor of heat and electricity, as a building material, and as a constituent of various metal alloys, such as sterling silver used in jewelry, cupronickel used to make marine hardware and coins, and constantan used in strain gauges and thermocouples for temperature measurement. Copper is one of the few metals that can occur in nature in a directly usable metallic form (native metals). This led to very early human use in several regions, from circa 8000 BC. Thousands of years later, it was the first metal to be smelted from sulfide ores, circa 5000 BC; the first metal to be cast into a shape in a mold, c. 4000 BC; and the first metal to be purposely alloyed with another metal, tin, to create br ...
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Copper(II) Carbonate
Copper(II) carbonate or cupric carbonate is a chemical compound with formula . At ambient temperatures, it is an ionic solid (a salt) consisting of copper(II) cations and carbonate anions . This compound is rarely encountered because it is difficult to prepare and readily reacts with water moisture from the air. The terms "copper carbonate", "copper(II) carbonate", and "cupric carbonate" almost always refer (even in chemistry texts) to a basic copper carbonate (or copper(II) carbonate hydroxide), such as ()2 (which occurs naturally as the mineral malachite) or ()2()2 (azurite). For this reason, the qualifier neutral may be used instead of "basic" to refer specifically to . Preparation Reactions that may be expected to yield , such as mixing solutions of copper(II) sulfate and sodium carbonate in ambient conditions, yield instead a basic carbonate and , due to the great affinity of the ion for the hydroxide anion . Thermal decomposition of the basic carbonate at atmosph ...
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Mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Minerals'; p. 1. In the series ''Geology: Landforms, Minerals, and Rocks''. Rosen Publishing Group. The geological definition of mineral normally excludes compounds that occur only in living organisms. However, some minerals are often biogenic (such as calcite) or are organic compounds in the sense of chemistry (such as mellite). Moreover, living organisms often synthesize inorganic minerals (such as hydroxylapatite) that also occur in rocks. The concept of mineral is distinct from rock, which is any bulk solid geologic material that is relatively homogeneous at a large enough scale. A rock may consist of one type of mineral, or may be an aggregate of two or more different types of minerals, spacially segregated into disti ...
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Aurichalcite
Aurichalcite is a carbonate mineral, usually found as a secondary mineral in copper and zinc deposits. Its chemical formula is . The zinc to copper ratio is about 5:4. Occurrence Aurichalcite typically occurs in the oxidized zone of copper and zinc deposits. Associated minerals include: rosasite, smithsonite, hemimorphite, hydrozincite, malachite and azurite. It was first described in 1839 by Bottger who named the mineral for its zinc and copper content after the Greek ''όρειχαλκος'', for "mountain brass" or "mountain copper", the name of '' orichalcum'', a fabulous metal, mentioned in the legend of the mythic lost continent Atlantis. The type locality is the Loktevskoye Mine, Upper Loktevka River, Rudnyi Altai, Altaiskii Krai, Western Siberia, Russia. Crystallography Aurichalcite displays prismatic An optical prism is a transparent optical element with flat, polished surfaces that are designed to refract light. At least one surface must be angled — e ...
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Crystal Field Theory
Crystal field theory (CFT) describes the breaking of degeneracies of electron orbital states, usually ''d'' or ''f'' orbitals, due to a static electric field produced by a surrounding charge distribution (anion neighbors). This theory has been used to describe various spectroscopies of transition metal coordination complexes, in particular optical spectra (colors). CFT successfully accounts for some magnetic properties, colors, hydration enthalpies, and spinel structures of transition metal complexes, but it does not attempt to describe bonding. CFT was developed by physicists Hans Bethe and John Hasbrouck van Vleck in the 1930s. CFT was subsequently combined with molecular orbital theory to form the more realistic and complex ligand field theory (LFT), which delivers insight into the process of chemical bonding in transition metal complexes. Overview of crystal field theory According to crystal field theory, the interaction between a transition metal and ligands arises from th ...
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Coordination Complex
A coordination complex consists of a central atom or ion, which is usually metallic and is called the ''coordination centre'', and a surrounding array of bound molecules or ions, that are in turn known as ''ligands'' or complexing agents. Many metal-containing compounds, especially those that include transition metals (elements like titanium that belong to the Periodic Table's d-block), are coordination complexes. Nomenclature and terminology Coordination complexes are so pervasive that their structures and reactions are described in many ways, sometimes confusingly. The atom within a ligand that is bonded to the central metal atom or ion is called the donor atom. In a typical complex, a metal ion is bonded to several donor atoms, which can be the same or different. A polydentate (multiple bonded) ligand is a molecule or ion that bonds to the central atom through several of the ligand's atoms; ligands with 2, 3, 4 or even 6 bonds to the central atom are common. These compl ...
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Specific Gravity
Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water (molecule), water at its densest (at ); for gases, the reference is air at room temperature (). The term "relative density" (often abbreviated r.d. or RD) is often preferred in scientific usage, whereas the term "specific gravity" is deprecation, deprecated. If a substance's relative density is less than 1 then it is less dense than the reference; if greater than 1 then it is denser than the reference. If the relative density is exactly 1 then the densities are equal; that is, equal volumes of the two substances have the same mass. If the reference material is water, then a substance with a relative density (or specific gravity) less than 1 will float in water. For example, an ice cube, with a relative density of about 0.91, will float. A substance wi ...
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