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Azaborane
Azaborane usually refers a boranes, borane Cluster chemistry, cluster where BH vertices are replaced by N or NR (R = H, organic substituent). Like many of the related boranes, these clusters are polyhedra and can be classified as ''closo-'', ''nido-'', ''arachno-'', etc. Within the context of Polyhedral skeletal electron pair theory, Wade's rules, NR is a 4-electron vertex, and N is a 3-electron vertex. Prominent examples are the charge-neutral ''nido''-NB10H13 (i.e. (NH)(BH)10) and ''closo''-NB11H12 (i.e. (NH)(BH)11).{{cite journal, author=P. Paetzold, title=New Perspectives in Boron-Nitrogen Chemistry-I, year=1991, pages=345–350, volume=63, journal=Pure Appl. Chem., issue=3, doi=10.1351/pac199163030345, s2cid=53659373, url=https://www.iupac.org/publications/pac/pdf/1991/pdf/6303x0345.pdf Azaboranes can also refer to simpler compounds including iminoboranes (formula = RN=NR') and borazines. See also * Carborane References [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carborane
Carboranes are electron-delocalized (non-classically bonded) clusters composed of boron, carbon and hydrogen atoms.Grimes, R. N., ''Carboranes 3rd Ed.'', Elsevier, Amsterdam and New York (2016), . Like many of the related boron hydrides, these clusters are polyhedra or fragments of polyhedra. Carboranes are one class of heteroboranes. In terms of scope, carboranes can have as few as 5 and as many as 14 atoms in the cage framework. The majority have two cage carbon atoms. The corresponding C-alkyl and B-alkyl analogues are also known in a few cases. Structure and bonding Carboranes and boranes adopt 3-dimensional cage (cluster) geometries in sharp contrast to typical organic compounds. Cages are compatible with sigma—delocalized bonding, whereas hydrocarbons are typically chains or rings. Like for other electron-delocalized polyhedral clusters, the electronic structure of these cluster compounds can be described by the Wade–Mingos rules. Like the related boron hydrides, th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Boranes
Boranes is the name given to compounds with the formula BxHy and related anions. Many such boranes are known. Most common are those with 1 to 12 boron atoms. Although they have few practical applications, the boranes exhibit structures and bonding that differs strongly from the patterns seen in hydrocarbons. Hybrids of boranes and hydrocarbons, the carboranes are also well developed. History The development of the chemistry of boranes led to innovations in synthetic methods as well as structure and bonding. First, new synthetic techniques were required to handle diborane and many of its derivatives, which are both pyrophoric and volatile. Alfred Stock invented the glass vacuum line for this purpose. The structure of diborane was correctly predicted in 1943 many years after its discovery. The structures of the boron hydride clusters were determined beginning in 1948 with the characterization of decaborane. William Lipscomb was awarded the Nobel prize in Chemistry in 1976 for th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cluster Chemistry
In chemistry, an atom cluster (or simply cluster) is an ensemble of bound atoms or molecules that is intermediate in size between a simple molecule and a nanoparticle; that is, up to a few nanometers (nm) in diameter. The term ''microcluster'' may be used for ensembles with up to couple dozen atoms. Clusters with a definite number and type of atoms in a specific arrangement are often considered a specific chemical compound and are studied as such. For example, fullerene is a cluster of 60 carbon atoms arranged as the vertices of a truncated icosahedron, and decaborane is a cluster of 10 boron atoms forming an incomplete icosahedron, surrounded by 14 hydrogen atoms. The term is most commonly used for ensembles consisting of several atoms of the same element, or of a few different elements, bonded in a three-dimensional arrangement. Transition metals and main group elements form especially robust clusters. Indeed, in some contexts, the term may refer specifically to a metal cl ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polyhedra
In geometry, a polyhedron (plural polyhedra or polyhedrons; ) is a three-dimensional shape with flat polygonal faces, straight edges and sharp corners or vertices. A convex polyhedron is the convex hull of finitely many points, not all on the same plane. Cubes and pyramids are examples of convex polyhedra. A polyhedron is a 3-dimensional example of a polytope, a more general concept in any number of dimensions. Definition Convex polyhedra are well-defined, with several equivalent standard definitions. However, the formal mathematical definition of polyhedra that are not required to be convex has been problematic. Many definitions of "polyhedron" have been given within particular contexts,. some more rigorous than others, and there is not universal agreement over which of these to choose. Some of these definitions exclude shapes that have often been counted as polyhedra (such as the self-crossing polyhedra) or include shapes that are often not considered as valid polyhed ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polyhedral Skeletal Electron Pair Theory
In chemistry the polyhedral skeletal electron pair theory (PSEPT) provides electron counting rules useful for predicting the structures of clusters such as borane and carborane clusters. The electron counting rules were originally formulated by Kenneth Wade, and were further developed by others including Michael Mingos; they are sometimes known as Wade's rules or the Wade–Mingos rules. The rules are based on a molecular orbital treatment of the bonding. These notes contained original material that served as the basis of the sections on the 4''n'', 5''n'', and 6''n'' rules. These rules have been extended and unified in the form of the Jemmis ''mno'' rules. Predicting structures of cluster compounds Different rules (4''n'', 5''n'', or 6''n'') are invoked depending on the number of electrons per vertex. The 4''n'' rules are reasonably accurate in predicting the structures of clusters having about 4 electrons per vertex, as is the case for many boranes and carboranes. For such ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iminoborane
Iminoboranes comprise a group of organoboron compounds with the formula RB=NR'. They are electronically related to acetylenes but are usually more reactive due to the polarity. Structure and bonding The parent iminoborane, HB=NH, is produced by the photolysis of H3BNH3. Bonding in iminoboranes can be described by two resonance structures In chemistry, resonance, also called mesomerism, is a way of describing bonding in certain molecules or polyatomic ions by the combination of several contributing structures (or ''forms'', also variously known as ''resonance structures'' or '' ...: :R-\overset\overset-R R-B=\ddot-R The stability is dramatically affected by bulky substituents. One isolable iminoborane is (''tert''-Bu)B=N(''tert''-Bu). Synthesis Elimination of fluoro- or chlorosilanes provides a well-tested route. Bulky substituents such as (Me3Si)3Si stabilize the iminoborane with respect to oligomerization: :(Me3Si)3SiB(F)-N(SiMe3)2 → (Me3Si)3Si-B=N-SiMe3 + F ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Borazine
Borazine, also known as borazole, is a non-polar inorganic compound with the chemical formula B3H6N3. In this cyclic compound, the three BH units and three NH units alternate. The compound is isoelectronic and isostructural with benzene. For this reason borazine is sometimes referred to as “inorganic benzene”. Like benzene, borazine is a colourless liquid with an aromatic smell. Synthesis The compound was reported in 1926 by the chemists Alfred Stock and Erich Pohland by a reaction of diborane with ammonia. Borazine can be synthesized by treating diborane and ammonia in a 1:2 ratio at 250–300 °C with a conversion of 50%. :3 B2H6 + 6 NH3 → 2 B3H6N3 + 12 H2 An alternative more efficient route begins with sodium borohydride and ammonium sulfate: :6 NaBH4 + 3 (NH4)2SO4 → 2 B3N3H6 + 3 Na2SO4 + 18 H2 In a two-step process to borazine, boron trichloride is first converted to trichloroborazine: :3 BCl3 + 3 NH4Cl → Cl3B3H3N3 + 9 HCl The B-Cl bonds are subsequently c ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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