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Arnold M. Collins
Arnold Miller Collins (1899-1982) was a chemist at DuPont who, working under Elmer Bolton and Wallace Carothers, first isolated polychloroprene and 2-chloro-1, 3-butadiene in 1930. Personal Born 1899. Married Helen Clark Collins. Died October 8, 1982. Education Collins attended Columbia College, graduating in 1921 with the AB degree. Doctoral degree. Columbia College 1924. His dissertation was entitled "Electrolytic introduction of alkyl groups", Columbia University, New York, New York. Career At Dupont, Collins worked under Wallace Carothers. Carothers assigned Collins to produce a sample of divinylacetylene. In March 1930, while distilling the products of the acetylene reaction, Collins obtained a small quantity of an unknown liquid, which he put aside in stoppered test tubes. He later found that the liquid had congealed into a clear homogeneous mass. When Collins removed the mass from the test tube, it bounced. Further analysis showed that the mass was a polymer of ...
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DuPont
DuPont de Nemours, Inc., commonly shortened to DuPont, is an American multinational chemical company first formed in 1802 by French-American chemist and industrialist Éleuthère Irénée du Pont de Nemours. The company played a major role in the development of Delaware and first arose as a major supplier of gunpowder. DuPont developed many polymers such as Vespel, neoprene, nylon, Corian, Teflon, Mylar, Kapton, Kevlar, Zemdrain, M5 fiber, Nomex, Tyvek, Sorona, Corfam and Lycra in the 20th century, and its scientists developed many chemicals, most notably Freon (chlorofluorocarbons), for the refrigerant industry. It also developed synthetic pigments and paints including ChromaFlair. In 2015, DuPont and the Dow Chemical Company agreed to a reorganization plan in which the two companies would merge and split into three. As a merged entity, DuPont simultaneously acquired Dow and renamed itself to DowDuPont on August 31, 2017, and after 18 months spin off the merged en ...
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Elmer Bolton
Elmer Keiser Bolton (June 23, 1886 – July 30, 1968) was an American chemist and research director for DuPont, notable for his role in developing neoprene and directing the research that led to the discovery of nylon. Personal life Bolton was born in Frankford, Philadelphia, Pennsylvania, the oldest of two brothers. His father ran the furniture store on Main Street, and both he and his brother attended public school in Frankford and went on to college. Bolton went to Bucknell University in Lewisburg, Pennsylvania, and took the ''Classical Course'', receiving a B.A. degree in 1908. From there he went to Harvard University, receiving his A.M. degree in 1910 and his Ph.D. in organic chemistry in 1913. His thesis advisor was Charles Loring Jackson, and his dissertation concerned the chemistry of periodoquinones. Several other prominent contemporaries of Bolton's at Harvard Graduate School were Roger Adams, Farrington Daniels, Frank C. Whitmore, James B. Sumner and James B ...
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Wallace Carothers
Wallace Hume Carothers (; April 27, 1896 – April 29, 1937) was an American chemist, inventor and the leader of organic chemistry at DuPont, who was credited with the invention of nylon. Carothers was a group leader at the DuPont Experimental Station laboratory, near Wilmington, Delaware, where most polymer research was done. Carothers was an organic chemist who, in addition to first developing nylon, also helped lay the groundwork for neoprene. After receiving his Ph.D., he taught at several universities before he was hired by DuPont to work on fundamental research. He married Helen Sweetman on February 21, 1936. Carothers had been troubled by periods of depression since his youth. Despite his success with nylon, he felt that he had not accomplished much and had run out of ideas. His unhappiness was exacerbated by the death of his sister, and on April 28, 1937, he committed suicide by drinking potassium cyanide. His daughter, Jane, was born on November 27, 1937. Educatio ...
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Polychloroprene
Neoprene (also polychloroprene) is a family of synthetic rubbers that are produced by polymerization of chloroprene.Werner Obrecht, Jean-Pierre Lambert, Michael Happ, Christiane Oppenheimer-Stix, John Dunn and Ralf Krüger "Rubber, 4. Emulsion Rubbers" in Ullmann's Encyclopedia of Industrial Chemistry, 2012, Wiley-VCH, Weinheim. Neoprene exhibits good chemical stability and maintains flexibility over a wide temperature range. Neoprene is sold either as solid rubber or in latex form and is used in a wide variety of commercial applications, such as laptop sleeves, orthopaedic braces (wrist, knee, etc.), electrical insulation, liquid and sheet-applied elastomeric membranes or flashings, and automotive fan belts. Production Neoprene is produced by free-radical polymerization of chloroprene. In commercial production, this polymer is prepared by free radical emulsion polymerization. Polymerization is initiated using potassium persulfate. Bifunctional nucleophiles, metal oxides (e.g ...
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Vinylacetylene
Vinylacetylene is the organic compound with the formula C4H4. The colourless gas was once used in the polymer industry. It is composed of both alkyne and alkene groups and is the simplest enyne. Vinylacetylene is extremely dangerous because in high enough concentrations (typically > 30 mole percent, but pressure dependent) it can auto-detonate (explode without air being present) especially at elevated pressures, such as those seen in chemical plants processing C4 hydrocarbons. An example of such an explosion occurred at a Union Carbide plant in Texas City in 1969. Synthesis Vinylacetylene was first synthesized by Hofmann elimination of the related quaternary ammonium salt: : CH3)3NCH2CH=CHCH2N(CH3)32 → 2 CH3)3NH + HC≡C-CH=CH2 It is usually synthesized by dehydrohalogenation of 1,3-dichloro-2-butene. It also arises via the dimerization of acetylene or dehydrogenation of 1,3-butadiene. Application At one time, chloroprene (2-chloro-1,3-butadiene), an industrially im ...
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Wallace H
Wallace may refer to: People * Clan Wallace in Scotland * Wallace (given name) * Wallace (surname) * Wallace (footballer, born 1986), full name Wallace Fernando Pereira, Brazilian football left-back * Wallace (footballer, born 1987), full name Wallace Reis da Silva, Brazilian football centre-back * Wallace (footballer, born May 1994), full name Wallace Oliveira dos Santos, Brazilian football full-back * Wallace (footballer, born October 1994), full name Wallace Fortuna dos Santos, Brazilian football centre-back * Wallace (footballer, born 1998), full name Wallace Menezes dos Santos, Brazilian football midfielder Fictional characters * Wallace, from '' Wallace and Gromit'' * Wallace (''Pokémon'') * Wallace (''Sin City'') * Wallace (''The Wire'') * Wallace Breen, from ''Half-Life 2'' * Wallace Fennel, from ''Veronica Mars'' * Wallace Footrot, from ''Footrot Flats'' * Eli Wallace, from ''Stargate Universe'' * Wallace, from " The Hangover Part III" * Wallace the Brave, from ...
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Ira Williams
Ira Williams (1894–1977) was an American chemist at DuPont's Jackson Laboratory in New Jersey, who in 1930 made commercial Neoprene possible by producing a soft, plastic form of chloroprene that could be processed by the rubber industry. He won the 1946 Charles Goodyear Medal The Charles Goodyear Medal is the highest honor conferred by the American Chemical Society, Rubber Division. Established in 1941, the award is named after Charles Goodyear, the discoverer of vulcanization, and consists of a gold medal, a framed .... References 20th-century American chemists Polymer scientists and engineers 1894 births 1977 deaths {{US-chemist-stub ...
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Neoprene
Neoprene (also polychloroprene) is a family of synthetic rubbers that are produced by polymerization of chloroprene.Werner Obrecht, Jean-Pierre Lambert, Michael Happ, Christiane Oppenheimer-Stix, John Dunn and Ralf Krüger "Rubber, 4. Emulsion Rubbers" in Ullmann's Encyclopedia of Industrial Chemistry, 2012, Wiley-VCH, Weinheim. Neoprene exhibits good chemical stability and maintains flexibility over a wide temperature range. Neoprene is sold either as solid rubber or in latex form and is used in a wide variety of commercial applications, such as laptop sleeves, orthopaedic braces (wrist, knee, etc.), electrical insulation, liquid and sheet-applied elastomeric membranes or flashings, and automotive fan belts. Production Neoprene is produced by free-radical polymerization of chloroprene. In commercial production, this polymer is prepared by free radical emulsion polymerization. Polymerization is initiated using potassium persulfate. Bifunctional nucleophiles, metal oxides ( ...
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Charles Goodyear Medal
The Charles Goodyear Medal is the highest honor conferred by the American Chemical Society, Rubber Division. Established in 1941, the award is named after Charles Goodyear, the discoverer of vulcanization, and consists of a gold medal, a framed certificate and prize money. The medal honors individuals for "outstanding invention, innovation, or development which has resulted in a significant change or contribution to the nature of the rubber industry". Awardees give a lecture at an ACS Rubber Division meeting, and publish a review of their work in the society's scientific journal '' Rubber Chemistry and Technology''. Recipients Source: * 1941 David Spence – Diamond Rubber Co. researcher noted for synthesizing isoprene for use in synthetic rubber * 1942 Lorin B. Sebrell – Goodyear Research Director noted for his work on organic accelerators for vulcanization * 1944 Waldo L. Semon – early developer of synthetic rubber, in particular Ameripol for B. F. Goodrich * 1946 ...
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ACS Rubber Division
ACS or Acs may refer to: Organizations and societies * American Cancer Society, an American voluntary health organization dedicated to eliminating cancer * American Ceramic Society, an American professional organization * American Cheese Society, a professional organization of the American cheese industry * American Chemical Society, an American professional association * American College of Surgeons, a fellowship of American surgeons * American Colonization Society, an organization that helped in founding Liberia as a colony for freed slaves * American Constitution Society for Law and Policy, an organization of lawyers and law students in the US * American Cryonics Society, non-profit corporation that supports and promotes research and education into cryonics * American CueSports Alliance, a US-based pool league * Association of Caribbean States, an advisory, consultative body of Caribbean countries * Association of Cricket Statisticians and Historians, an association found ...
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Polymer Scientists And Engineers
A polymer (; Greek '' poly-'', "many" + ''-mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic and natural polymers play essential and ubiquitous roles in everyday life. Polymers range from familiar synthetic plastics such as polystyrene to natural biopolymers such as DNA and proteins that are fundamental to biological structure and function. Polymers, both natural and synthetic, are created via polymerization of many small molecules, known as monomers. Their consequently large molecular mass, relative to small molecule compounds, produces unique physical properties including toughness, high elasticity, viscoelasticity, and a tendency to form amorphous and semicrystalline structures rather than crystals. The term "polymer" derives from the Greek word πολύς (''polus'', meaning "many, much") and μέρος (''meros'', meani ...
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1899 Births
Events January 1899 * January 1 ** Spanish rule ends in Cuba, concluding 400 years of the Spanish Empire in the Americas. ** Queens and Staten Island become administratively part of New York City. * January 2 – ** Bolivia sets up a customs office in Puerto Alonso, leading to the Brazilian settlers there to declare the Republic of Acre in a revolt against Bolivian authorities. **The first part of the Jakarta Kota–Anyer Kidul railway on the island of Java is opened between Batavia Zuid ( Jakarta Kota) and Tangerang. * January 3 – Hungarian Prime Minister Dezső Bánffy fights an inconclusive duel with his bitter enemy in parliament, Horánszky Nándor. * January 4 – **U.S. President William McKinley's declaration of December 21, 1898, proclaiming a policy of benevolent assimilation of the Philippines as a United States territory, is announced in Manila by the U.S. commander, General Elwell Otis, and angers independence activists who had fought ag ...
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