Antisymmetric Exchange
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Antisymmetric Exchange
In Physics, antisymmetric exchange, also known as the Dzyaloshinskii–Moriya interaction (DMI), is a contribution to the total magnetic exchange interaction between two neighboring magnetic spins, \mathbf_i and \mathbf_j . Quantitatively, it is a term in the Hamiltonian which can be written as : H^_=\mathbf_ \cdot ( \mathbf_i \times \mathbf_j ). In magnetically ordered systems, it favors a spin canting of otherwise parallel or antiparallel aligned magnetic moments and thus, is a source of weak ferromagnetic behavior in an antiferromagnet. The interaction is fundamental to the production of magnetic skyrmions and explains the magnetoelectric effects in a class of materials termed multiferroics. History The discovery of antisymmetric exchange originated in the early 20th century from the controversial observation of weak ferromagnetism in typically antiferromagnetic -FeO crystals. In 1958, Igor Dzyaloshinskii provided evidence that the interaction was due to the relativistic ...
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Neutron Scattering
Neutron scattering, the irregular dispersal of free neutrons by matter, can refer to either the naturally occurring physical process itself or to the man-made experimental techniques that use the natural process for investigating materials. The natural/physical phenomenon is of elemental importance in nuclear engineering and the nuclear sciences. Regarding the experimental technique, understanding and manipulating neutron scattering is fundamental to the applications used in crystallography, physics, physical chemistry, biophysics, and materials research. Neutron scattering is practiced at research reactors and spallation neutron sources that provide neutron radiation of varying intensities. Neutron diffraction (elastic scattering) techniques are used for analyzing structures; where inelastic neutron scattering is used in studying atomic vibrations and other excitations. Scattering of fast neutrons "Fast neutrons" (see neutron temperature) have a kinetic energy above ...
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Exchange Interaction
In chemistry and physics, the exchange interaction (with an exchange energy and exchange term) is a quantum mechanical effect that only occurs between identical particles. Despite sometimes being called an exchange force in an analogy to classical force, it is not a true force as it lacks a force carrier. The effect is due to the wave function of indistinguishable particles being subject to exchange symmetry, that is, either remaining unchanged (symmetric) or changing sign (antisymmetric) when two particles are exchanged. Both bosons and fermions can experience the exchange interaction. For fermions, this interaction is sometimes called Pauli repulsion and is related to the Pauli exclusion principle. For bosons, the exchange interaction takes the form of an effective attraction that causes identical particles to be found closer together, as in Bose–Einstein condensation. The exchange interaction alters the expectation value of the distance when the wave functions of two or more ...
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Copper(II) Oxide
Copper(II) oxide or cupric oxide is an inorganic compound with the formula CuO. A black solid, it is one of the two stable oxides of copper, the other being Cu2O or copper(I) oxide (cuprous oxide). As a mineral, it is known as tenorite. It is a product of copper mining and the precursor to many other copper-containing products and chemical compounds. Production It is produced on a large scale by pyrometallurgy, as one stage in extracting copper from its ores. The ores are treated with an aqueous mixture of ammonium carbonate, ammonia, and oxygen to give copper(I) and copper(II) ammine complexes, which are extracted from the solids. These complexes are decomposed with steam to give CuO. It can be formed by heating copper in air at around 300–800°C: : 2 Cu + O2 → 2 CuO For laboratory uses, pure copper(II) oxide is better prepared by heating copper(II) nitrate, copper(II) hydroxide, or basic copper(II) carbonate: : 2 Cu(NO3)2(s) → 2 CuO(s) + 4 NO2(g) + O2(g) (180° ...
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Bismuth Ferrite
Bismuth ferrite (BiFeO3, also commonly referred to as BFO in materials science) is an inorganic chemical compound with perovskite structure and one of the most promising multiferroic materials. The room-temperature phase of BiFeO3 is classed as rhombohedral belonging to the space group R3c. It is synthesized in bulk and thin film form and both its antiferromagnetic (G type ordering) Néel temperature (approximately 653 K) and ferroelectric Curie temperature are well above room temperature (approximately 1100K). Ferroelectric polarization occurs along the pseudocubic direction (\langle 111\rangle_c) with a magnitude of 90–95 μC/cm2. Sample Preparation Bismuth ferrite is not a naturally occurring mineral and several synthesis routes to obtain the compound have been developed. Solid state synthesis In the solid state reaction method bismuth oxide (Bi2O3) and iron oxide (Fe2O3) in a 1:1 mole ratio are mixed with a mortar or by ball milling and then fired at elevated te ...
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Nature Materials
''Nature Materials'', is a peer-reviewed scientific journal published by Nature Publishing Group. It was launched in September 2002. Vincent Dusastre is the launching and current chief editor. Aims and scope ''Nature Materials'' is focused on all topics within the combined disciplines of '' materials science'' and ''engineering''. Topics published in the journal are presented from the view of the impact that materials research has on other scientific disciplines such as (for example) physics, chemistry, and biology. Coverage in this journal encompasses fundamental research and applications from synthesis to processing, and from structure to composition. Coverage also includes basic research and applications of properties and performance of materials. Materials are specifically described as "substances in the condensed states (liquid, solid, colloidal)", and which are "designed or manipulated for technological ends." Furthermore, ''Nature Materials'' functions as a forum for the ...
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Tunnel Magnetoresistance
Tunnel magnetoresistance (TMR) is a magnetoresistive effect that occurs in a magnetic tunnel junction (MTJ), which is a component consisting of two ferromagnets separated by a thin insulator. If the insulating layer is thin enough (typically a few nanometres), electrons can tunnel from one ferromagnet into the other. Since this process is forbidden in classical physics, the tunnel magnetoresistance is a strictly quantum mechanical phenomenon. Magnetic tunnel junctions are manufactured in thin film technology. On an industrial scale the film deposition is done by magnetron sputter deposition; on a laboratory scale molecular beam epitaxy, pulsed laser deposition and electron beam physical vapor deposition are also utilized. The junctions are prepared by photolithography. Phenomenological description The direction of the two magnetizations of the ferromagnetic films can be switched individually by an external magnetic field. If the magnetizations are in a parallel orientation it ...
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Magnetic Ordering
Magnetism is the class of physical attributes that are mediated by a magnetic field, which refers to the capacity to induce attractive and repulsive phenomena in other entities. Electric currents and the magnetic moments of elementary particles give rise to a magnetic field, which acts on other currents and magnetic moments. Magnetism is one aspect of the combined phenomena of electromagnetism. The most familiar effects occur in ferromagnetic materials, which are strongly attracted by magnetic fields and can be magnetized to become permanent magnets, producing magnetic fields themselves. Demagnetizing a magnet is also possible. Only a few substances are ferromagnetic; the most common ones are iron, cobalt, and nickel and their alloys. The rare-earth metals neodymium and samarium are less common examples. The prefix ' refers to iron because permanent magnetism was first observed in lodestone, a form of natural iron ore called magnetite, Fe3O4. All substances exhibit some type of ...
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Spintronic
Spintronics (a portmanteau meaning spin transport electronics), also known as spin electronics, is the study of the intrinsic spin of the electron and its associated magnetic moment, in addition to its fundamental electronic charge, in solid-state devices. The field of spintronics concerns spin-charge coupling in metallic systems; the analogous effects in insulators fall into the field of multiferroics. Spintronics fundamentally differs from traditional electronics in that, in addition to charge state, electron spins are exploited as a further degree of freedom, with implications in the efficiency of data storage and transfer. Spintronic systems are most often realised in dilute magnetic semiconductors (DMS) and Heusler alloys and are of particular interest in the field of quantum computing and neuromorphic computing. History Spintronics emerged from discoveries in the 1980s concerning spin-dependent electron transport phenomena in solid-state devices. This includes the observ ...
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Magnetic Skyrmion
In physics, magnetic skyrmions (occasionally described as 'vortices,' or 'vortex-like' configurations) are statically stable solitons which have been predicted theoretically and observed experimentally in condensed matter systems. Skyrmions can be formed in magnetic materials in their 'bulk' such as in MnSi, or in magnetic thin films. They can be achiral, or chiral (Fig. 1 a and b are both chiral skyrmions) in nature, and may exist both as dynamic excitations or stable or metastable states. Although the broad lines defining magnetic skyrmions have been established de facto, there exist a variety of interpretations with subtle differences. Most descriptions include the notion of topology – a categorization of shapes and the way in which an object is laid out in space – using a continuous-field approximation as defined in micromagnetics. Descriptions generally specify a non-zero, integer value of the topological index, (not to be confused with the chemistry meaning of 'topologi ...
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Trigonal Crystal System
In crystallography, the hexagonal crystal family is one of the six crystal families, which includes two crystal systems (hexagonal and trigonal) and two lattice systems (hexagonal and rhombohedral). While commonly confused, the trigonal crystal system and the rhombohedral lattice system are not equivalent (see section crystal systems below). In particular, there are crystals that have trigonal symmetry but belong to the hexagonal lattice (such as α-quartz). The hexagonal crystal family consists of the 12 point groups such that at least one of their space groups has the hexagonal lattice as underlying lattice, and is the union of the hexagonal crystal system and the trigonal crystal system. There are 52 space groups associated with it, which are exactly those whose Bravais lattice is either hexagonal or rhombohedral. __TOC__ Lattice systems The hexagonal crystal family consists of two lattice systems: hexagonal and rhombohedral. Each lattice system consists of one Bravais la ...
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