Aluminium Alloy Inclusions
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Aluminium Alloy Inclusions
An inclusion is a solid particle in liquid aluminium alloy. It is usually non-metallic and can be of different nature depending on its source. Problems related to inclusions Inclusions can create problems in the casting when they are large and in too high concentration. Here are examples of problems related to inclusions: * Pinholes in light gauge foil * Flange cracks in beverage containers * Surface streaks in bright automotive trim and lithographic material * Breakage in wire drawing operation * Increased tool wear and tear * Increased porosity * Loss of pressure tightness of engine blocks * Poor machinability * Cosmetic defect in apparent surfaces * Diminished mechanical properties (e.g. Ultimate Tensile Strength, Yield Strength, Elongation) Inclusion types Oxide films In contact with ambient air, liquid aluminium reacts with the oxygen and form an oxide film layer (gamma-Al2O3). This layer becomes thicker with time. When molten aluminium is disturbed, this oxide film gets m ...
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Particle
In the Outline of physical science, physical sciences, a particle (or corpuscule in older texts) is a small wikt:local, localized physical body, object which can be described by several physical property, physical or chemical property, chemical properties, such as volume, density, or mass. They vary greatly in size or quantity, from subatomic particles like the electron, to microscopic scale, microscopic particles like atoms and molecules, to macroscopic scale, macroscopic particles like powder (substance), powders and other granular materials. Particles can also be used to create scientific models of even larger objects depending on their density, such as humans moving in a crowd or celestial bodies in motion (physics), motion. The term ''particle'' is rather general in meaning, and is refined as needed by various scientific fields. Anything that is composed of particles may be referred to as being particulate. However, the noun ''particulates, particulate'' is most frequently ...
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Cathode
A cathode is the electrode from which a conventional current leaves a polarized electrical device. This definition can be recalled by using the mnemonic ''CCD'' for ''Cathode Current Departs''. A conventional current describes the direction in which positive charges move. Electrons have a negative electrical charge, so the movement of electrons is opposite to that of the conventional current flow. Consequently, the mnemonic ''cathode current departs'' also means that electrons flow ''into'' the device's cathode from the external circuit. For example, the end of a household battery marked with a + (plus) is the cathode. The electrode through which conventional current flows the other way, into the device, is termed an anode. Charge flow Conventional current flows from cathode to anode outside of the cell or device (with electrons moving in the opposite direction), regardless of the cell or device type and operating mode. Cathode polarity with respect to the anode can be positive ...
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Silicon
Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic table: carbon is above it; and germanium, tin, lead, and flerovium are below it. It is relatively unreactive. Because of its high chemical affinity for oxygen, it was not until 1823 that Jöns Jakob Berzelius was first able to prepare it and characterize it in pure form. Its oxides form a family of anions known as silicates. Its melting and boiling points of 1414 Â°C and 3265 Â°C, respectively, are the second highest among all the metalloids and nonmetals, being surpassed only by boron. Silicon is the eighth most common element in the universe by mass, but very rarely occurs as the pure element in the Earth's crust. It is widely distributed in space in cosmic dusts, planetoids, and planets as various forms of silicon dioxide ( ...
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Hypereutectic
A eutectic system or eutectic mixture ( ) is a homogeneous mixture that has a melting point lower than those of the constituents. The lowest possible melting point over all of the mixing ratios of the constituents is called the ''eutectic temperature''. On a phase diagram, the eutectic temperature is seen as the eutectic point (see plot on the right). Non-eutectic mixture ratios would have different melting temperatures for their different constituents, since one component's lattice will melt at a lower temperature than the other's. Conversely, as a non-eutectic mixture cools down, each of its components would solidify (form a lattice) at a different temperature, until the entire mass is solid. Not all binary alloys have eutectic points, since the valence electrons of the component species are not always compatible, in any mixing ratio, to form a new type of joint crystal lattice. For example, in the silver-gold system the melt temperature (liquidus) and freeze temperature (so ...
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Phosphorus
Phosphorus is a chemical element with the symbol P and atomic number 15. Elemental phosphorus exists in two major forms, white phosphorus and red phosphorus, but because it is highly reactive, phosphorus is never found as a free element on Earth. It has a concentration in the Earth's crust of about one gram per kilogram (compare copper at about 0.06 grams). In minerals, phosphorus generally occurs as phosphate. Elemental phosphorus was first isolated as white phosphorus in 1669. White phosphorus emits a faint glow when exposed to oxygen – hence the name, taken from Greek mythology, meaning 'light-bearer' (Latin ), referring to the " Morning Star", the planet Venus. The term '' phosphorescence'', meaning glow after illumination, derives from this property of phosphorus, although the word has since been used for a different physical process that produces a glow. The glow of phosphorus is caused by oxidation of the white (but not red) phosphorus — a process now called chem ...
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Titanium Boride
Titanium diboride (TiB2) is an extremely hard ceramic which has excellent heat conductivity, oxidation stability and wear resistance. TiB2 is also a reasonable electrical conductor,J. Schmidt et al. "Preparation of titanium diboride TiB2 by spark plasma sintering at slow heating rate" Sci. Technol. Adv. Mater. 8 (2007) 37free download/ref> so it can be used as a cathode material in aluminium smelting and can be shaped by electrical discharge machining. Physical properties TiB2 shares some properties with boron carbide and titanium carbide, but many of its properties are superior to those of B4C & TiC: Exceptional hardness at extreme temperature *2nd hardest material at 3000°C (# diamond) *3rd hardest material at 2800°C (# cBN) *4th hardest material at 2100°C (# B4C) *5th hardest material at 1000°C (# B6O) Advantages over other borides *Highest boride elastic modulus *Highest boride fracture toughness *Highest boride compressive strength *2nd highest boride melting point (32 ...
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Flux (metallurgy)
In metallurgy, a flux () is a chemical cleaning agent, flowing agent, or purifying agent. Fluxes may have more than one function at a time. They are used in both extractive metallurgy and metal joining. Some of the earliest known fluxes were sodium carbonate, potash, charcoal, coke, borax, lime, lead sulfide and certain minerals containing phosphorus. Iron ore was also used as a flux in the smelting of copper. These agents served various functions, the simplest being a reducing agent, which prevented oxides from forming on the surface of the molten metal, while others absorbed impurities into the slag, which could be scraped off the molten metal. Fluxes are also used in foundries for removing impurities from molten nonferrous metals such as aluminium, or for adding desirable trace elements such as titanium. As cleaning agents, fluxes facilitate soldering, brazing, and welding by removing oxidation from the metals to be joined. In some applications molten flux also serve ...
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Hydrogen Gas Porosity
Hydrogen gas porosity is an aluminium casting defect in the form of a porosity or void in an aluminium casting caused by a high level of hydrogen gas (H2) dissolved in the aluminium at liquid phase. The solubility of hydrogen in solid aluminium is much smaller than in liquid aluminium. As the aluminium freezes, some of the hydrogen comes out of solution and forms bubbles, creating porosity in the solid aluminium. Aluminium foundries want to produce high-quality aluminum castings with minimum porosity. Hydrogen porosity can be reduced by reducing the amount of hydrogen in the liquid aluminium alloy, by degassing or sparging. (Sometimes a small hydrogen concentration is intentionally maintained; some very fine hydrogen porosity can be preferable to internal voids caused by shrinkage.) Directional solidification can drive impurities to one end of the casting. The hydrogen problem Hydrogen forms whenever molten aluminium comes into contact with water vapor, and easily dissolves into ...
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Chloride
The chloride ion is the anion (negatively charged ion) Cl−. It is formed when the element chlorine (a halogen) gains an electron or when a compound such as hydrogen chloride is dissolved in water or other polar solvents. Chloride salts such as sodium chloride are often very soluble in water.Green, John, and Sadru Damji. "Chapter 3." ''Chemistry''. Camberwell, Vic.: IBID, 2001. Print. It is an essential electrolyte located in all body fluids responsible for maintaining acid/base balance, transmitting nerve impulses and regulating liquid flow in and out of cells. Less frequently, the word ''chloride'' may also form part of the "common" name of chemical compounds in which one or more chlorine atoms are covalently bonded. For example, methyl chloride, with the standard name chloromethane (see IUPAC books) is an organic compound with a covalent C−Cl bond in which the chlorine is not an anion. Electronic properties A chloride ion (diameter 167  pm) is much larger tha ...
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Aluminum Carbide
Aluminum carbide, chemical formula Al4 C3, is a carbide of aluminum. It has the appearance of pale yellow to brown crystals. It is stable up to 1400 Â°C. It decomposes in water with the production of methane. Structure Aluminum carbide has an unusual crystal structure that consists of alternating layers of Al2C and Al2C2. Each aluminum atom is coordinated to 4 carbon atoms to give a tetrahedral arrangement. Carbon atoms exist in 2 different binding environments; one is a deformed octahedron of 6 Al atoms at a distance of 217 pm. The other is a distorted trigonal bipyramidal structure of 4 Al atoms at 190–194 pm and a fifth Al atom at 221 pm. Other carbides (IUPAC nomenclature: methides) also exhibit complex structures. Reactions Aluminum carbide hydrolyses with evolution of methane. The reaction proceeds at room temperature but is rapidly accelerated by heating. : Al4C3 + 12 H2O → 4 Al(OH)3 + 3 CH4 Similar reactions occur with other protic reagents: : Al4C3 + 12 HCl â ...
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Graphite
Graphite () is a crystalline form of the element carbon. It consists of stacked layers of graphene. Graphite occurs naturally and is the most stable form of carbon under standard conditions. Synthetic and natural graphite are consumed on large scale (300 kton/year, in 1989) for uses in pencils, lubricants, and electrodes. Under high pressures and temperatures it converts to diamond. It is a weak conductor of heat and electricity. Types and varieties Natural graphite The principal types of natural graphite, each occurring in different types of ore deposits, are * Crystalline small flakes of graphite (or flake graphite) occurs as isolated, flat, plate-like particles with hexagonal edges if unbroken. When broken the edges can be irregular or angular; * Amorphous graphite: very fine flake graphite is sometimes called amorphous; * Lump graphite (or vein graphite) occurs in fissure veins or fractures and appears as massive platy intergrowths of fibrous or acicular crystalline ...
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Refractory
In materials science, a refractory material or refractory is a material that is resistant to decomposition by heat, pressure, or chemical attack, and retains strength and form at high temperatures. Refractories are polycrystalline, polyphase, inorganic, non-metallic, porous, and heterogeneous. They are typically composed of oxides or carbides, nitrides etc. of the following materials: silicon, aluminium, magnesium, calcium, boron, chromium and zirconium. ASTM C71 defines refractories as "...non-metallic materials having those chemical and physical properties that make them applicable for structures, or as components of systems, that are exposed to environments above ." Refractory materials are used in furnaces, kilns, incinerators, and reactors. Refractories are also used to make crucibles and moulds for casting glass and metals and for surfacing flame deflector systems for rocket launch structures. Today, the iron- and steel-industry and metal casting sectors use appr ...
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