Akaganeite
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Akaganeite
Akaganeite, also written as the deprecated Akaganéite,Ernst A.J. Burke (2008):Tidying up Mineral Names: an IMA-CNMNC Scheme for Suffixes, Hyphens and Diacritical marks. ''Mineralogical Record'', volume 39, issue 2. is a chloride-containing iron(III) oxide-hydroxide mineral, formed by the weathering of pyrrhotite (Fe1−''x''S). Akaganeite is often described as the β phase of anhydrous ferric oxyhydroxide , but some chloride (or fluoride) ions are normally included in the structure,Jongsik Kim and Clare P. Grey (2010), "Li Solid-State MAS NMR Study of Local Environments and Lithium Adsorption on the Iron(III) Oxyhydroxide, Akaganeite (β-FeOOH)". ''Chemistry of Materials'', volume 22, pages 5453–5462. so a more accurate formula is .C. Rémazeilles and Ph. Refait (2007):On the formation of β-FeOOH (akaganéite) in chloride-containing environments. ''Corrosion Science'', volume 49, issue 2, pages 844-857. Nickel may substitute for iron, yielding the more general formula
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Iron(III) Oxide-hydroxide
Iron(III) oxide-hydroxide or ferric oxyhydroxideA. L. Mackay (1960): "β-Ferric Oxyhydroxide". ''Mineralogical Magazine'' (''Journal of the Mineralogical Society''), volume 32, issue 250, pages 545-557. is the chemical compound of iron, oxygen, and hydrogen with formula . The compound is often encountered as one of its hydrates, ·''n'' ust The monohydrate · is often referred to as iron(III) hydroxide ,CAS , C.I. 77492 hydrated iron oxide, yellow iron oxide, or Pigment Yellow 42. Natural occurrences Minerals Anhydrous ferric hydroxide occurs in the nature as the exceedingly rare mineral bernalite, Fe(OH)3·''n''H2O (n=0.0-0.25). Iron oxyhydroxides, , are much more common and occur naturally as structurally different minerals (polymorphs) denoted by the Greek letters α, β, γ and δ. * Goethite, α-FeO(OH), has been used as an ochre pigment since prehistoric times. * Akaganeite is the β polymorph,A. L. Mackay (1962): "β-Ferric oxyhydroxide—akaganéite", ''Miner ...
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