Aerogel
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Aerogel
Aerogels are a class of synthetic porous ultralight material derived from a gel, in which the liquid component for the gel has been replaced with a gas, without significant collapse of the gel structure. The result is a solid with extremely low density and extremely low thermal conductivity. Aerogels can be made from a variety of chemical compounds. Silica aerogels feel like fragile expanded polystyrene to the touch, while some polymer-based aerogels feel like rigid foams. The first documented example of an aerogel was created by Samuel Stephens Kistler in 1931, as a result of a bet with Charles Learned over who could replace the liquid in "jellies" with gas without causing shrinkage. Aerogels are produced by extracting the liquid component of a gel through supercritical drying or freeze-drying. This allows the liquid to be slowly dried off without causing the solid matrix in the gel to collapse from capillary action, as would happen with conventional evaporation. The f ...
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Samuel Stephens Kistler
Samuel Stephens Kistler (March 26, 1900 November 6, 1975) was an American scientist and chemical engineer, best known as the inventor of aerogels, one of the lightest known solid materials. Biography Kistler, the son of a shopkeeper, was born in the small town of Cedarville in the far northeastern corner of California. The family moved to the larger Santa Rosa when Kistler was 12, where he first became interested in chemistry. When he entered the College of the Pacific in 1917, however, his plan was to learn to play the cello, then pursue a degree in agriculture. Instead, he ended up taking every science course available, and after three years he moved to Stanford University and obtained a B.A. in chemistry, followed by a chemical engineering degree. He never did learn to play the cello. After a brief spell working for the Standard Oil Company of California, he returned to academia, teaching chemistry at the College of the Pacific until 1931, when he transferred to the Univer ...
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Ultralight Material
Ultralight materials are solids with a density of less than 10 mg/cm3, including silica aerogels, carbon nanotube aerogels, aerographite, metallic foams, polymeric foams, and metallic microlattices. The density of air is about 1.275 mg/cm3, which means that the air in the pores contributes significantly to the density of these materials in atmospheric conditions. They can be classified by production method as aerogels, stochastic foams, and structured cellular materials. Properties Ultralight materials are solids with a density of less than 10 mg/cm3. Ultralight material is defined by its cellular arrangement and its stiffness and strength that make up its solid constituent. They include silica aerogels, carbon nanotube aerogels, aero graphite, metallic foams, polymeric foams, and metallic micro lattices. Ultralight materials are produced to have the strength of bulk-scaled properties at a micro-size. Also, they are designed to not compress even under extreme pre ...
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Thermal Insulation
Thermal insulation is the reduction of heat transfer (i.e., the transfer of thermal energy between objects of differing temperature) between objects in thermal contact or in range of radiative influence. Thermal insulation can be achieved with specially engineered methods or processes, as well as with suitable object shapes and materials. Heat flow is an inevitable consequence of contact between objects of different temperature. Thermal insulation provides a region of insulation in which thermal conduction is reduced, creating a thermal break or thermal barrier, or thermal radiation is reflected rather than absorbed by the lower-temperature body. The insulating capability of a material is measured as the inverse of thermal conductivity, thermal conductivity (k). Low thermal conductivity is equivalent to high insulating capability (R-value (insulation), resistance value). In thermal engineering, other important properties of insulating materials are product density, density (ρ ...
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Silica
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and most abundant families of materials, existing as a compound of several minerals and as a synthetic product. Notable examples include fused quartz, fumed silica, silica gel, opal and aerogels. It is used in structural materials, microelectronics (as an electrical insulator), and as components in the food and pharmaceutical industries. Structure In the majority of silicates, the silicon atom shows tetrahedral coordination, with four oxygen atoms surrounding a central Si atomsee 3-D Unit Cell. Thus, SiO2 forms 3-dimensional network solids in which each silicon atom is covalently bonded in a tetrahedral manner to 4 oxygen atoms. In contrast, CO2 is a linear molecule. The starkly different structures of th ...
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Thermal Conductivity
The thermal conductivity of a material is a measure of its ability to conduct heat. It is commonly denoted by k, \lambda, or \kappa. Heat transfer occurs at a lower rate in materials of low thermal conductivity than in materials of high thermal conductivity. For instance, metals typically have high thermal conductivity and are very efficient at conducting heat, while the opposite is true for insulating materials like Rockwool or Styrofoam. Correspondingly, materials of high thermal conductivity are widely used in heat sink applications, and materials of low thermal conductivity are used as thermal insulation. The reciprocal of thermal conductivity is called thermal resistivity. The defining equation for thermal conductivity is \mathbf = - k \nabla T, where \mathbf is the heat flux, k is the thermal conductivity, and \nabla T is the temperature gradient. This is known as Fourier's Law for heat conduction. Although commonly expressed as a scalar, the most general form of ...
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Supercritical Drying
Supercritical drying, also known as critical point drying, is a process to remove liquid in a precise and controlled way. It is useful in the production of microelectromechanical systems (MEMS), the drying of spices, the production of aerogel, the decaffeination of coffee and in the preparation of biological specimens. Phase diagram As the substance in a liquid body crosses the boundary from liquid to gas (see green arrow in phase diagram), the liquid changes into gas at a finite rate, while the amount of liquid decreases. When this happens within a heterogeneous environment, surface tension in the liquid body pulls against any solid structures the liquid might be in contact with. Delicate structures such as cell walls, the dendrites in silica gel, and the tiny machinery of microelectromechanical devices, tend to be broken apart by this surface tension as the liquid–gas–solid junction moves by. To avoid this, the sample can be brought via two possible alternate paths f ...
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Heat Transfer
Heat transfer is a discipline of thermal engineering that concerns the generation, use, conversion, and exchange of thermal energy (heat) between physical systems. Heat transfer is classified into various mechanisms, such as thermal conduction, thermal convection, thermal radiation, and transfer of energy by phase changes. Engineers also consider the transfer of mass of differing chemical species (mass transfer in the form of advection), either cold or hot, to achieve heat transfer. While these mechanisms have distinct characteristics, they often occur simultaneously in the same system. Heat conduction, also called diffusion, is the direct microscopic exchanges of kinetic energy of particles (such as molecules) or quasiparticles (such as lattice waves) through the boundary between two systems. When an object is at a different temperature from another body or its surroundings, heat flows so that the body and the surroundings reach the same temperature, at which point they are ...
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Fractal
In mathematics, a fractal is a geometric shape containing detailed structure at arbitrarily small scales, usually having a fractal dimension strictly exceeding the topological dimension. Many fractals appear similar at various scales, as illustrated in successive magnifications of the Mandelbrot set. This exhibition of similar patterns at increasingly smaller scales is called self-similarity, also known as expanding symmetry or unfolding symmetry; if this replication is exactly the same at every scale, as in the Menger sponge, the shape is called affine self-similar. Fractal geometry lies within the mathematical branch of measure theory. One way that fractals are different from finite geometric figures is how they scale. Doubling the edge lengths of a filled polygon multiplies its area by four, which is two (the ratio of the new to the old side length) raised to the power of two (the conventional dimension of the filled polygon). Likewise, if the radius of a filled s ...
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Porosity
Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure the "accessible void", the total amount of void space accessible from the surface (cf. closed-cell foam). There are many ways to test porosity in a substance or part, such as industrial CT scanning. The term porosity is used in multiple fields including pharmaceutics, ceramics, metallurgy, materials, manufacturing, petrophysics, hydrology, earth sciences, soil mechanics, and engineering. Void fraction in two-phase flow In gas-liquid two-phase flow, the void fraction is defined as the fraction of the flow-channel volume that is occupied by the gas phase or, alternatively, as the fraction of the cross-sectional area of the channel that is occupied by the gas phase. Void fraction usually varies from location to location in the fl ...
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Chromium(III) Oxide
Chromium(III) oxide (or chromia) is an inorganic compound with the formula . It is one of the principal oxides of chromium and is used as a pigment. In nature, it occurs as the rare mineral eskolaite. Structure and properties has the corundum structure, consisting of a hexagonal close packed array of oxide anions with of the octahedral holes occupied by chromium. Similar to corundum, is a hard, brittle material ( Mohs hardness 8 to 8.5). It is antiferromagnetic up to 307 K, the Néel temperature. It is not readily attacked by acids. Occurrence occurs naturally as the mineral eskolaite, which is found in chromium-rich tremolite skarns, metaquartzites, and chlorite veins. Eskolaite is also a rare component of chondrite meteorites. The mineral is named after Finnish geologist Pentti Eskola. Production The Parisians Pannetier and Binet first prepared the transparent hydrated form of in 1838 via a secret process, sold as a pigment. It is derived from the mineral chrom ...
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Nanometre
330px, Different lengths as in respect to the Molecule">molecular scale. The nanometre (international spelling as used by the International Bureau of Weights and Measures; SI symbol: nm) or nanometer ( American spelling) is a unit of length in the International System of Units (SI), equal to one billionth ( short scale) of a metre () and to 1000 picometres. One nanometre can be expressed in scientific notation as , and as  metres. History The nanometre was formerly known as the millimicrometre – or, more commonly, the millimicron for short – since it is of a micron (micrometre), and was often denoted by the symbol mμ or (more rarely and confusingly, since it logically should refer to a ''millionth'' of a micron) as μμ. Etymology The name combines the SI prefix '' nano-'' (from the Ancient Greek , ', "dwarf") with the parent unit name ''metre'' (from Greek , ', "unit of measurement"). Usage Nanotechnologies are based on phenomena typically occurr ...
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