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Arsenic Sulfide
Arsenic sulfide may refer to: *Arsenic trisulfide, As2S3, the mineral orpiment * Arsenic pentasulfide, As2S5, similar structure to phosphorus pentasulfide (β-P2S5) *Tetraarsenic tetrasulfide Realgar ( ), also known as "ruby sulphur" or "ruby of arsenic", is an arsenic sulfide mineral with the chemical formula α-. It is a soft, sectile mineral occurring in monoclinic crystals, or in granular, compact, or powdery form, often in assoc ..., As4S4, the mineral realgar * Tetraarsenic trisulfide, As4S3, the mineral α- or β- dimorphite {{chemistry index ...
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Arsenic Trisulfide
Arsenic trisulfide is the inorganic compound with the formula . It is a dark yellow solid that is insoluble in water. It also occurs as the mineral orpiment (Latin: auripigmentum), which has been used as a pigment called King's yellow. It is produced in the analysis of arsenic compounds. It is a group V/VI, intrinsic p-type semiconductor and exhibits photo-induced phase-change properties. Structure occurs both in crystalline and amorphous forms. Both forms feature polymeric structures consisting of trigonal pyramidal As(III) centres linked by sulfide centres. The sulfide centres are two-fold coordinated to two arsenic atoms. In the crystalline form, the compound adopts a ruffled sheet structure. The bonding between the sheets consists of van der Waals forces. The crystalline form is usually found in geological samples. Amorphous does not possess a layered structure but is more highly cross-linked. Like other glasses, there is no medium or long-range order, but the first co-ordin ...
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Phosphorus Pentasulfide
Phosphorus pentasulfide is the inorganic compound with the formula (monomer) or (dimer). This yellow solid is the one of two phosphorus sulfides of commercial value. Samples often appear greenish-gray due to impurities. It is soluble in carbon disulfide but reacts with many other solvents such as alcohols, DMSO, and DMF. Structure and synthesis Its tetrahedral molecular structure is similar to that of adamantane and almost identical to the structure of phosphorus pentoxide. Phosphorus pentasulfide is obtained by the reaction of liquid white phosphorus () with sulfur above 300 °C. The first synthesis of by Berzelius in 1843 was by this method. Alternatively, can be formed by reacting elemental sulfur or pyrite, , with ferrophosphorus, a crude form of (a byproduct of white phosphorus () production from phosphate rock): : : Applications Approximately 150,000 tons of are produced annually. The compound is mainly converted to other derivatives for use as lubrication ad ...
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Tetraarsenic Tetrasulfide
Realgar ( ), also known as "ruby sulphur" or "ruby of arsenic", is an arsenic sulfide mineral with the chemical formula α-. It is a soft, sectile mineral occurring in monoclinic crystals, or in granular, compact, or powdery form, often in association with the related mineral, orpiment (). It is orange-red in color, melts at 320 °C, and burns with a bluish flame releasing fumes of arsenic and sulfur. Realgar is soft with a Mohs hardness of 1.5 to 2 and has a specific gravity of 3.5. Its streak is orange colored. It is trimorphous with pararealgar and bonazziite. Its name comes from the Arabic ''rahj al-ġār'' (, "powder of the mine"), via Medieval Latin, and its earliest record in English is in the 1390s. Uses Realgar is a minor ore of arsenic extracted in China, Peru, and the Philippines. Historical uses Realgar was used by firework manufacturers to create the color white in fireworks prior to the availability of powdered metals such as aluminium, magnesium and titani ...
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