Acoustic Paramagnetic Resonance
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Acoustic Paramagnetic Resonance
Acoustic paramagnetic resonance (APR) is a phenomenon of resonant absorption of sound by a system of magnetic particles placed in an external magnetic field. It occurs when the energy of the sound wave quantum becomes equal to the splitting of the energy levels of the particles, the splitting being induced by the magnetic field. APR is a variation of electron paramagnetic resonance (EPR) where the acoustic rather than electromagnetic waves are absorbed by the studied sample. APR was theoretically predicted in 1952, independently by Semen Altshuler and Alfred Kastler, and was experimentally observed by W. G. Proctor and W. H. Tanttila in 1955. History After discovery of EPR in 1944, Evgeny Zavoisky predicted that the resonance phenomenon should not be restricted to radio or microwave absorption but could be extended to the sound waves. This idea was theoretically developed by his collaborator Semen Altshuler in 1952 and independently by Alfred Kastler; whereas Altshuler reported the ...
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Magnetic Field
A magnetic field is a vector field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular to its own velocity and to the magnetic field. A permanent magnet's magnetic field pulls on ferromagnetic materials such as iron, and attracts or repels other magnets. In addition, a nonuniform magnetic field exerts minuscule forces on "nonmagnetic" materials by three other magnetic effects: paramagnetism, diamagnetism, and antiferromagnetism, although these forces are usually so small they can only be detected by laboratory equipment. Magnetic fields surround magnetized materials, and are created by electric currents such as those used in electromagnets, and by electric fields varying in time. Since both strength and direction of a magnetic field may vary with location, it is described mathematically by a function assigning a vector to each point of space, cal ...
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Quantum
In physics, a quantum (plural quanta) is the minimum amount of any physical entity (physical property) involved in an interaction. The fundamental notion that a physical property can be "quantized" is referred to as "the hypothesis of quantization". This means that the magnitude of the physical property can take on only discrete values consisting of integer multiples of one quantum. For example, a photon is a single quantum of light (or of any other form of electromagnetic radiation). Similarly, the energy of an electron bound within an atom is quantized and can exist only in certain discrete values. (Atoms and matter in general are stable because electrons can exist only at discrete energy levels within an atom.) Quantization is one of the foundations of the much broader physics of quantum mechanics. Quantization of energy and its influence on how energy and matter interact (quantum electrodynamics) is part of the fundamental framework for understanding and describing nature. E ...
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Electron Paramagnetic Resonance
Electron paramagnetic resonance (EPR) or electron spin resonance (ESR) spectroscopy is a method for studying materials that have unpaired electrons. The basic concepts of EPR are analogous to those of nuclear magnetic resonance (NMR), but the spins excited are those of the electrons instead of the atomic nuclei. EPR spectroscopy is particularly useful for studying metal complexes and organic radicals. EPR was first observed in Kazan State University by Soviet physicist Yevgeny Zavoisky in 1944, and was developed independently at the same time by Brebis Bleaney at the University of Oxford. Theory Origin of an EPR signal Every electron has a magnetic moment and spin quantum number s = \tfrac , with magnetic components m_\mathrm = + \tfrac or m_\mathrm = - \tfrac . In the presence of an external magnetic field with strength B_\mathrm , the electron's magnetic moment aligns itself either antiparallel ( m_\mathrm = - \tfrac ) or parallel ( m_\mathrm = + \tfrac ) to the fie ...
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Semen Altshuler
Semen Alexandrovich Altshuler (also Altshuller, Al'tshuler or Al'shuller; german: Altschuler; russian: Семён Александрович Альтшулер; September 24, 1911 – January 24, 1983) was a Soviet physicist known for his work in resonance spectroscopy and in particular for theoretical prediction of acoustic paramagnetic resonance in 1952.Kochelaev p.100 Early years Altshuler was born in 1911 in Vitebsk, now a city in Belarus, near the border with Russia. He finished school in Nizhny Novgorod and later moved to Kazan, where he spent most of his life. In 1928, he entered the physics faculty of the Kazan University aiming to study theoretical physics. He graduated in 1932 and obtained a post-graduate scholarship, but had to change university due to the scholarship rules. He moved to Moscow to study with Igor Tamm whom he admired for his books on electricity and magnetism. In 1934, Altshuler and Tamm published a famous article which predicted the existence of the magn ...
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Alfred Kastler
Alfred Kastler (; 3 May 1902 – 7 January 1984) was a French physicist, and Nobel Prize laureate. Biography Kastler was born in Guebwiller (Alsace, German Empire) and later attended the Lycée Bartholdi in Colmar, Alsace, and École Normale Supérieure in Paris in 1921. After his studies, in 1926 he began teaching physics at the Lycée of Mulhouse, and then taught at the University of Bordeaux, where he was a university professor until 1941. Georges Bruhat asked him to come back to the École Normale Supérieure, where he finally obtained a chair in 1952. Collaborating with Jean Brossel, he researched quantum mechanics, the interaction between light and atoms, and spectroscopy. Kastler, working on combination of optical resonance and magnetic resonance, developed the technique of "optical pumping". Those works led to the completion of the theory of lasers and masers. He won the Nobel Prize in Physics in 1966 "for the discovery and development of optical methods for studying He ...
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World Scientific
World Scientific Publishing is an academic publisher of scientific, technical, and medical books and journals headquartered in Singapore. The company was founded in 1981. It publishes about 600 books annually, along with 135 journals in various fields. In 1995, World Scientific co-founded the London-based Imperial College Press together with the Imperial College of Science, Technology and Medicine. Company structure The company head office is in Singapore. The Chairman and Editor-in-Chief is Dr Phua Kok Khoo, while the Managing Director is Doreen Liu. The company was co-founded by them in 1981. Imperial College Press In 1995 the company co-founded Imperial College Press, specializing in engineering, medicine and information technology, with Imperial College London. In 2006, World Scientific assumed full ownership of Imperial College Press, under a license granted by the university. Finally, in August 2016, ICP was fully incorporated into World Scientific under the new imprint ...
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Evgeny Zavoisky
Yevgeny Konstantinovich Zavoisky (russian: Евгений Константинович Завойский; September 28, 1907 – October 9, 1976) was a Soviet physicist known for discovery of electron paramagnetic resonance in 1944. He likely observed nuclear magnetic resonance in 1941, well before Felix Bloch and Edward Mills Purcell, but dismissed the results as not reproducible. Zavoisky is also credited with design of luminescence camera for detection of nuclear processes in 1952 and discovery of magneto-acoustic resonance in plasma in 1958. Early years Zavoisky was born in 1907 in Mohyliv-Podilskyi, a town in the south of Russian Empire (now in Vinnytsia Oblast, Ukraine). His father Konstantin Ivanovich was a military doctor and mother Elizaveta Nikolaevna was trained as a teacher. In 1910, Zavoisky family moved to Kazan – a major Russian university city – for the sake of better education and well-being of their five children. There, Konstantin Ivanovich obtained a respect ...
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Sodium Chlorate
Sodium chlorate is an inorganic compound with the chemical formula Na ClO3. It is a white crystalline powder that is readily soluble in water. It is hygroscopic. It decomposes above 300 °C to release oxygen and leaves sodium chloride. Several hundred million tons are produced annually, mainly for applications in bleaching pulp to produce high brightness paper. Synthesis Industrially, sodium chlorate is produced by the electrolysis of concentrated sodium chloride solutions. All other processes are obsolete. The sodium chlorate process is not to be confused with the chloralkali process, which is an industrial process for the electrolytic production of sodium hydroxide and chlorine gas. The overall reaction can be simplified to the equation: First, chloride is oxidised to form intermediate hypochlorite, ClO−, which undergoes further oxidisation to chlorate along two competing reaction paths: (1) Anodic chlorate formation at the boundary layer between the electrolyte and t ...
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Dynamic Nuclear Polarisation
Dynamic nuclear polarization (DNP) results from transferring spin polarization from electrons to nuclei, thereby aligning the nuclear spins to the extent that electron spins are aligned. Note that the alignment of electron spins at a given magnetic field and temperature is described by the Boltzmann distribution under the thermal equilibrium. It is also possible that those electrons are aligned to a higher degree of order by other preparations of electron spin order such as: chemical reactions (leading to Chemical-Induced DNP, CIDNP), optical pumping and spin injection. DNP is considered one of several techniques for hyperpolarization. DNP can also be induced using unpaired electrons produced by radiation damage in solids. When electron spin polarization deviates from its thermal equilibrium value, polarization transfers between electrons and nuclei can occur spontaneously through electron-nuclear cross relaxation and/or spin-state mixing among electrons and nuclei. For example, the ...
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Maser
A maser (, an acronym for microwave amplification by stimulated emission of radiation) is a device that produces coherent electromagnetic waves through amplification by stimulated emission. The first maser was built by Charles H. Townes, James P. Gordon, and Herbert J. Zeiger at Columbia University in 1953. Townes, Nikolay Basov and Alexander Prokhorov were awarded the 1964 Nobel Prize in Physics for theoretical work leading to the maser. Masers are also used as the timekeeping device in atomic clocks, and as extremely low-noise microwave amplifiers in radio telescopes and deep-space spacecraft communication ground stations. Modern masers can be designed to generate electromagnetic waves at not only microwave frequencies but also radio and infrared frequencies. For this reason, Townes suggested replacing ''microwave'' with the word ''molecular'' as the first word in the acronym ''maser''. The laser works by the same principle as the maser but produces higher frequency ...
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Charles Hard Townes
Charles Hard Townes (July 28, 1915 – January 27, 2015) was an American physicist. Townes worked on the theory and application of the maser, for which he obtained the fundamental patent, and other work in quantum electronics associated with both maser and laser devices. He shared the 1964 Nobel Prize in Physics with Nikolay Basov and Alexander Prokhorov. Townes was an adviser to the United States Government, meeting every US president from Harry S. Truman (1945) to Bill Clinton (1999). He directed the US government's Science and Technology Advisory Committee for the Apollo lunar landing program. After becoming a professor of the University of California, Berkeley in 1967, he began an astrophysical program that produced several important discoveries, for example, the black hole at the center of the Milky Way galaxy. Townes was religious and believed that science and religion are converging to provide a greater understanding of the nature and purpose of the universe. Earl ...
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EPR Splitting
EPR may refer to: Science and technology * EPR (nuclear reactor), European Pressurised-Water Reactor * EPR paradox (Einstein–Podolsky–Rosen paradox), in physics * Earth potential rise, in electrical engineering * East Pacific Rise, a mid-oceanic ridge * Electron paramagnetic resonance * Engine pressure ratio,of a jet engine * Ethylene propylene rubber * Yevpatoria RT-70 radio telescope (Evpatoria planetary radar) * Bernays–Schönfinkel class or effectively propositional, in mathematical logic * Endpoint references in Web addressing * Ethnic Power Relations, dataset of ethnic groups * ePrivacy Regulation (ePR), proposal for the regulation of various privacy-related topics, mostly in relation to electronic communications within the European Union Medicine * Enhanced permeability and retention effect, a controversial concept in cancer research * Emergency Preservation and Resuscitation, a medical procedure * Electronic patient record Environment * UNECE Environmental Perform ...
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