β-cubebene
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β-cubebene
Cubebenes are a pair of chemical compounds, classified as sesquiterpenes, first isolated from ''Piper cubeba'' berries, known as cubebs. The volatile oil from the distillation of cubebs is a pale green or blue-yellow viscous liquid with a warm woody, slightly camphoraceous odor consisting of cubebene which comes in two forms, α- and β-cubebene, both with the molecular formula C15H24. They differ only in the position of a double bond which is endocyclic (part of the five-membered ring) in α-cubebene, but exocyclic in β-cubeαbene. Additional plant sources A 2022 study detected α-cubebene in samples of oleoresin from three pine species (Pinus elliottii, Pinus pinaster, Pinus tropicalis) via mass spectrometry. α-cubebene was detected in Vitis vinifera ''Vitis vinifera'', the common grape vine, is a species of flowering plant, native to the Mediterranean Basin, Mediterranean region, Central Europe, and southwestern Asia, from Morocco and Portugal north to southern ...
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Piper Cubeba
''Piper cubeba'', cubeb or tailed pepper is a plant in genus '' Piper'', cultivated for its fruit and essential oil. It is mostly grown in Java and Sumatra, hence sometimes called Java pepper. The fruits are gathered before they are ripe, and carefully dried. Commercial cubeb consists of the dried berries, similar in appearance to black pepper, but with stalks attached – the "tails" in "tailed pepper". The dried pericarp is wrinkled, and its color ranges from grayish brown to black. The seed is hard, white and oily. The odor of cubeb is described as agreeable and aromatic and the taste as pungent, acrid, slightly bitter and persistent. It has been described as tasting like allspice, or like a cross between allspice and black pepper. Cubeb came to Europe via India through the trade with the Arabs. The name ''cubeb'' comes from Arabic ' () by way of Old French ''quibibes''. Cubeb is mentioned in alchemical writings by its Arabic name. In his ''Theatrum Botanicum'', John P ...
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Sesquiterpene
Sesquiterpenes are a class of terpenes that consist of three isoprene units and often have the molecular formula C15H24. Like monoterpenes, sesquiterpenes may be cyclic or contain rings, including many combinations. Biochemical modifications such as oxidation or rearrangement produce the related sesquiterpenoids. It is estimated (2006) that 3000 sesquiterpenes have been identified. Biosynthesis and examples The reaction of geranyl pyrophosphate with isopentenyl pyrophosphate results in the 15-carbon farnesyl pyrophosphate (FPP), which is an intermediate in the biosynthesis of sesquiterpenes such as farnesene. Cyclic sesquiterpenes are more common than cyclic monoterpenes because of the increased chain length and additional double bond in the sesquiterpene precursors. In addition to common six-membered ring systems such as the ones found in zingiberene and bisacurone, cyclization of one end of the chain to the other end can lead to macrocyclic rings such as humulene. ...
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Volatile Oil
An essential oil is a concentrated hydrophobic liquid containing volatile (easily evaporated at normal temperatures) chemical compounds from plants. Essential oils are also known as volatile oils, ethereal oils, aetheroleum, or simply as the oil of the plant from which they were extracted, such as oil of clove. An essential oil is essential in the sense that it contains the essence of the plant's fragrance—the characteristic fragrance of the plant from which it is derived. The term "essential" used here does ''not'' mean required or usable by the human body, as with the terms essential amino acid or essential fatty acid, which are so called because they are nutritionally required by a living organism. Essential oils are generally extracted by distillation, often by using steam. Other processes include expression, solvent extraction, '' sfumatura'', absolute oil extraction, resin tapping, wax embedding, and cold pressing. They are used in perfumes, cosmetics, soaps, ...
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Double Bond
In chemistry, a double bond is a covalent bond between two atoms involving four bonding electrons as opposed to two in a single bond. Double bonds occur most commonly between two carbon atoms, for example in alkenes. Many double bonds exist between two different elements: for example, in a carbonyl group between a carbon atom and an oxygen atom. Other common double bonds are found in azo compounds (N=N), imines (C=N), and sulfoxides (S=O). In a skeletal formula, a double bond is drawn as two parallel lines (=) between the two connected atoms; typographically, the equals sign is used for this. Double bonds were introduced in chemical notation by Russian chemist Alexander Butlerov. Double bonds involving carbon are stronger and shorter than single bonds. The bond order is two. Double bonds are also electron-rich, which makes them potentially more reactive in the presence of a strong electron acceptor (as in addition reactions of the halogens). File:Ethene structural.svg, ...
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Exocyclic
In organic chemistry, an alicyclic compound contains one or more all-carbon rings which may be either saturated or unsaturated, but do not have aromatic character. Alicyclic compounds may have one or more aliphatic side chains attached. Cycloalkanes The simplest alicyclic compounds are the monocyclic cycloalkanes: cyclopropane, cyclobutane, cyclopentane, cyclohexane, cycloheptane, cyclooctane, and so on. Bicyclic alkanes include decalin, housane, and norbornane. Polycyclic alkanes include cubane, basketane, and tetrahedrane. Spiro compounds have two or more rings that are connected through only one carbon atom. The mode of ring-closing in the formation of many alicyclic compounds can be predicted by Baldwin's rules. Otto Wallach, a German chemist, received the 1910 Nobel Prize in Chemistry for his work on alicyclic compounds. Cycloalkenes Monocyclic cycloalkenes are cyclopropene, cyclobutene, cyclopentene, cyclohexene, cycloheptene, cyclooctene, a ...
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Oleoresin
Oleoresins are semi-solid extracts composed of resin and essential or fatty oil, obtained by evaporation of the solvents used for their production. The oleoresin of conifers is known as crude turpentine or gum turpentine, which consists of oil of turpentine and rosin. Properties In contrast to essential oils obtained by steam distillation, oleoresins abound in heavier, less volatile and lipophilic compounds, such as resins, waxes, fats and fatty oils. Gummo-oleoresins (oleo-gum resins, gum resins) occur mostly as crude balsams and contain also water-soluble gums. Processing of oleoresins is conducted on a large scale, especially in China (400,000 tons per year in the 1990s), but the technology is too labor-intensive to be viable in countries with high labor costs, such as the US. Oleoresins are prepared from spices, such as basil, capsicum (paprika), cardamom, celery seed, cinnamon bark, clove bud, fenugreek, fir balsam, ginger, jambu, labdanum, mace, marjoram, nutm ...
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Pinus Elliottii
''Pinus elliottii'', commonly known as slash pine,Family, P. P. (1990). Pinus elliottii Engelm. slash pine. ''Silvics of North America: Conifers'', (654), 338. is a conifer tree native to the Southeastern United States. Slash pine is named after the "slashes" – swampy ground overgrown with trees and bushes – that constitute its habitat. Other common names include swamp pine, yellow slash pine, and southern Florida pine. Slash pine has two different varieties: ''P. e.'' var. ''elliottii'' and ''P. e.'' var. ''densa''. Historically, slash pine has been an important economic timber for naval stores, turpentine, and resin. The wood of slash pine is known for its unusually high strength, especially for a pine. It exceeds many hardwoods and is even comparable to very dense woods such as black ironwood. Description and taxonomy This tree is fast-growing, but not very long-lived by pine standards (to 200 years). It reaches heights of with a trunk diameter of . The leaves are need ...
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Pinus Pinaster
''Pinus pinaster'', the maritime pine or cluster pine, is a pine native to the south Atlantic Europe region and parts of the western Mediterranean. It is a hard, fast growing pine bearing small seeds with large wings. Description ''Pinus pinaster'' is a medium-size tree, reaching tall with a Trunk (botany), trunk diameter of up to , exceptionally . The Bark (botany), bark is orange-red, thick, and deeply fissured at the base of the trunk, somewhat thinner in the upper Crown (botany), crown. The leaves ('needles') are in pairs, very stout ( broad), up to long, and bluish-green to distinctly yellowish-green. The maritime pine features the longest and most robust needles of all European pine species. The conifer cone, cones are conic, long and broad at the base when closed, green at first, ripening glossy red-brown when 24 months old. They open slowly over the next few years, or after being heated by a wildfire, forest fire, to release the seeds, opening to broad. The seeds ...
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Pinus Tropicalis
''Pinus tropicalis'', the tropical pine, is a pine tree endemic to the western highlands of the island of Cuba Cuba, officially the Republic of Cuba, is an island country, comprising the island of Cuba (largest island), Isla de la Juventud, and List of islands of Cuba, 4,195 islands, islets and cays surrounding the main island. It is located where the .... See also * Cuban pine forests References * Endemic flora of Cuba Least concern plants tropicalis Trees of Cuba {{conifer-stub ...
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Mass Spectrometry
Mass spectrometry (MS) is an analytical technique that is used to measure the mass-to-charge ratio of ions. The results are presented as a ''mass spectrum'', a plot of intensity as a function of the mass-to-charge ratio. Mass spectrometry is used in many different fields and is applied to pure samples as well as complex mixtures. A mass spectrum is a type of plot of the ion signal as a function of the mass-to-charge ratio. These spectra are used to determine the elemental or isotopic signature of a sample, the masses of particles and of molecules, and to elucidate the chemical identity or structure of molecules and other chemical compounds. In a typical MS procedure, a sample, which may be solid, liquid, or gaseous, is ionization, ionized, for example by bombarding it with a Electron ionization, beam of electrons. This may cause some of the sample's molecules to break up into positively charged fragments or simply become positively charged without fragmenting. These ions (fragmen ...
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Vitis Vinifera
''Vitis vinifera'', the common grape vine, is a species of flowering plant, native to the Mediterranean Basin, Mediterranean region, Central Europe, and southwestern Asia, from Morocco and Portugal north to southern Germany and east to northern Iran. , there were between List of grape varieties, 5,000 and 10,000 varieties of ''Vitis vinifera'' grapes though only a few are of commercial significance for wine and table grape production. The wild grape is often classified as ''Vitis vinifera'' ''sylvestris'' (in some classifications considered ''Vitis sylvestris''), with ''Vitis vinifera'' ''vinifera'' restricted to cultivated forms. Domesticated vines have hermaphrodite#Plants, hermaphrodite flowers, but ''sylvestris'' is plant sexuality, dioecious (male and female flowers on separate plants) and pollination is required for fruit to develop. Grapes can be eaten fresh or dried to produce raisins, Sultana (grape)#Raisins, sultanas, and Zante currant, currants. Grape leaves are used ...
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Lemberger (grape)
Lemberger is a surname of German origin demonym for a person from the Polish city Lwów (German: ''Lemberg''), now Lviv, Ukraine. Notable people with the surname include: * Georg Lemberger (c.1490–1500 – c.1540–1545), German painter and woodcut artist * , Polish Jewish actor * Hans Leinberger sometimes given as Lemberger (c.1475/1480 – after 1531), Late Gothic sculptor from Altbayern * Jean Lemberger (1924-1993), Polish Jew born French FTP-MOI from Des terroristes à la retraite * Ken Lemberger (born 1946), American film producer * LeAnn Lemberger, American writer published as "Leigh Michaels" * Leopold Lemberger, Austrian-Swiss film director known as "Leopold Lindtberg" * Shimon Lemberger, Makova Rebbe in Kiryat Ata See also * Blaufränkisch, a grape variety also known as ''Lemberger'', or ''Blauer Limberger'' * Lemberg (other) Lemberg is the German name for the city of Lviv in Ukraine. It may also refer to: Places Settlements *Lemberg, Saskatchewan, a m ...
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