Δ15N
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Δ15N
In geochemistry, hydrology, paleoclimatology and paleoceanography, ''δ''15N (pronounced "delta fifteen n") or delta-N-15 is a measure of the ratio of the two stable isotopes of nitrogen, 15N: 14N. Formulas Two very similar expressions for are in wide use in hydrology. Both have the form 1000\fraca ‰ (‰ = permil or parts per thousand) where ''s'' and ''a'' are the relative abundances of 15N in respectively the sample and the atmosphere. The difference is whether the relative abundance is with respect to all the nitrogen, i.e. 14N plus 15N, or just to 14N. Since the atmosphere is 99.6337% 14N and 0.3663% 15N, ''a'' is 0.003663 in the former case and 0.003663/0.996337 = 0.003676 in the latter. However ''s'' varies similarly; for example if in the sample 15N is 0.385% and 14N is 99.615%, ''s'' is 0.003850 in the former case and 0.00385/0.99615 = 0.003865 in the latter. The value of 1000\fraca is then 51.05‰ in the former case and 51.38‰ in the latter, an insignifican ...
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Geochemistry
Geochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth, encompassing the entire Solar System, and has made important contributions to the understanding of a number of processes including mantle convection, the formation of planets and the origins of granite and basalt. It is an integrated field of chemistry and geology. History The term ''geochemistry'' was first used by the Swiss-German chemist Christian Friedrich Schönbein in 1838: "a comparative geochemistry ought to be launched, before geognosy can become geology, and before the mystery of the genesis of our planets and their inorganic matter may be revealed." However, for the rest of the century the more common term was "chemical geology", and there was little contact between geologists and chemists. Geochemistry emerged as a separate discipline after ...
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