Topic summary

Diazo transfer

Diazo transfer

Extracted from the Wikipedia article Diazo.

By diazo transfer

In diazo transfer, sometimes called Regitz diazo transfer, certain carbon acids react with sulfonyl azides and a weak base like triethylamine or DBU, with corresponding sulfonamide byproduct. The mechanism involves enolate attack at the terminal nitrogen, proton transfer, and sulfonamide anion expulsion.