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Water splitting

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Water splitting is the endergonicchemical reaction in which water is broken down into oxygen and hydrogen: 2 H2O → 2 H2 + O2Efficient and economical water splitting would be a technological breakthrough that could underpin a hydrogen economy. A version of water splitting occurs in photosynthesis, but hydrogen is not released but rather used ionically to drive the Calvin cycle. The reverse of water splitting is the basis of the hydrogen fuel cell. Water splitting using solar radiation has not been commercialized.

Electrolysis of waterElectrolysis of waterWater electrolysis is a term for processes that use electricity to convert liquid water (H2O) into gaseous hydrogen (H2) and oxygen (O2). The hydrogen produced by electrolysis can be used as fuel or as an industrial feedstock, most notably for the production of fertilizers.High-temperature electrolysisHigh-temperature electrolysisHigh-temperature electrolysis (also HTE or steam electrolysis, or HTSE) is a technology for producing hydrogen from water at high temperatures or other products, such as iron or carbon nanomaterials, as higher energy lowers needed electricity to split molecules and opens up new, potentially better electrolytes like molten salts or hydroxides. Unlike electrolysis at room temperature, HTE operates at elevated temperature ranges depending on the thermal capacity of the material.HydrogenHydrogenChemical element with atomic number 1 (H)–↑H↓Li(none) ← hydrogen → heliumPhotosynthesisPhotosynthesisPhotosynthesis is a system of biological processes by which photopigment-bearing autotrophic organisms, such as most plants, algae and cyanobacteria, convert light energy—typically from sunlight—into the chemical energy necessary to fuel their metabolism. The term photosynthesis usually refers to oxygenic photosynthesis, a process that releases oxygen as a byproduct of water splitting.OxygenOxygenChemical element with atomic number 8 (O)–↑O↓Snitrogen ← oxygen → fluorineHydrogen economyHydrogen economyUsing hydrogen to decarbonize more sectorsHydrogen has the most potential to reduce greenhouse gas emissions when used in chemical production, refineries, international shipping, and steelmakingThe hydrogen economy is a term for the role hydrogen as an energy carrier to complement electricity as part of a long-term option to reduce emissions of greenhouse gases. The aim is to reduce emissions where cheaper and more energy-efficient clean solutions are not available.Chemical reactionChemical reactionProcess that leads to chemical changesA thermite reaction using iron(III) oxide. The sparks flying outwards are globules of molten iron trailing smoke in their wake.A chemical reaction is a process that leads to the chemical transformation of one set of chemical substances to another. When chemical reactions occur, the atoms are rearranged and the reaction is accompanied by an energy change as new products are generated.WaterWaterNames Preferred IUPAC nameWaterSystematic IUPAC nameOxidane (not in common use)Other names Hydrogen oxideHydrogen hydroxide (H2O or HOH)Hydroxylic acidDihydrogen monoxide (DHMO) (parody name)Dihydrogen oxideHydric acidHydrohydroxic acidHydroxic acidHydroxoic acidHydrolμ-Oxidodihydrogenκ-Hydroxylhydrogen(0)AquaNeutral liquidOxygen dihydride (may be considered incorrect)Identifiers CAS Number7732-18-53D model (JSmol)Interactive imageBeilstein Reference3587155 ChEBICHEBI:15377ChEMBLChEMBL1098659ChemSpider937DrugBankDB09145ECHA InfoCard100.028.902EC Number231-791-2Gmelin Reference117 KEGGC00001PubChemCID962RTECS numberZC0110000UNII059QF0KO0RCompTox Dashboard(EPA)DTXSID6026296InChIInChI=1S/H2O/h1H2Key: XLYOFNOQVPJJNP-UHFFFAOYSA-NSMILESOProperties Chemical formulaH2OMolar mass18.015 g·mol Appearance Almost colorless or white crystalline solid, almost colorless liquid, with a hint of blue, colorless gas OdorOdorless DensityLiquid (1 atm, VSMOW):0.99984283(84) g/mL at 0 °C0.99997495(84) g/mL at 3.983035(670) °C (temperature of maximum density, often 4 °C)0.99704702(83) g/mL at 25 °C0.96188791(96) g/mL at 95 °CSolid:0.9167 g/mL at 0 °CMelting point0.00 °C (32.00 °F; 273.15 K) Boiling point99.98 °C (211.96 °F; 373.13 K) SolubilityPoorly soluble in haloalkanes, aliphatic and aromatic hydrocarbons, ethers.Calvin cycleCalvin cycleThe Calvin cycle, bio synthetic phase, dark reactions, or photosynthetic carbon reduction (PCR) cycle of photosynthesis is a series of chemical reactions that convert carbon dioxide and hydrogen-carrier compounds into glucose. The Calvin cycle is present in all photosynthetic eukaryotes and also many photosynthetic bacteria. In plants, these reactions occur in the stroma, the fluid-filled region of a chloroplast outside the thylakoid membranes.IonIonAn ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convention. The net charge of an ion is not zero because its total number of electrons is unequal to its total number of protons.Fuel cellFuel cellDevice that converts the chemical energy from a fuel into electricityDemonstration model of a direct methanol fuel cell (black layered cube) in its enclosureScheme of a proton-conducting fuel cellA fuel cell is an electrochemical cell that converts the chemical energy of a fuel (often hydrogen) and an oxidizing agent (often oxygen) into electricity through a pair of redox reactions.Endergonic reactionEndergonic reactionIn chemical thermodynamics, an endergonic reaction (from Greekἔνδον (endon)'within' and ἔργον (ergon)'work'; also called a heat absorbing nonspontaneous reaction or an unfavorable reaction) is a chemical reaction in which the standard change in free energy is positive, and an additional driving force is needed to perform this reaction.

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