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Methylidyne group

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In organic chemistry, a methylidyne group or just methylidyne is a neutral part of a molecule (a substituent or functional group) with formula ≡CH, consisting of a carbonatom bonded to a hydrogen atom by one single bond and to the rest of the molecule by one triple bond. For example, a methylidyne group is present in , H3C−(CH2)5−N≡CH. The name "methylidyne" is also used for the methylidyne radical (carbyne) ⫶CH, the same two atoms not bound to any other atom.

Methylidyne radicalMethylidyne radicalNames Preferred IUPAC nameMethylidyneSystematic IUPAC nameHydridocarbonhydridocarbon(•),Hydridocarbon(3•)Identifiers CAS Number3315-37-53D model (JSmol)Interactive imageBeilstein Reference7801830 ChEBICHEBI:51382CHEBI:51383Gmelin Reference24689 CompTox Dashboard(EPA)DTXSID701027113InChIInChI=1S/CH/h1HKey: VRLIPUYDFBXWCH-UHFFFAOYSA-NSMILES[CH]Properties Chemical formulaCH, CH, CHMolar mass13.0186 g mol Appearance Colourless gas Solubility in waterReacts Thermochemistry Std molarentropy(S298)183.04 J K mol Std enthalpy offormation(ΔfH298)594.13 kJ mol Related compounds Related compoundsMethyl (CH3)Methylene (CH2)Carbide (C)Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).Methylidyne, or (unsubstituted) carbyne, is an organic compound whose molecule consists of a single hydrogen atom bonded to a carbon atom.Functional groupFunctional groupIn organic chemistry, a functional group is any substituent or moiety in a molecule that causes the molecule's characteristic chemical reactions. The same functional group will undergo the same or similar chemical reactions regardless of the rest of the molecule's composition. This enables systematic prediction of chemical reactions and behavior of chemical compounds and the design of chemical synthesis.SubstituentIn organic chemistry, a substituent is one or a group of atoms that replaces (one or more) atoms, thereby becoming a moiety in the resultant (new) molecule. The suffix -yl is used when naming organic compounds that contain a single bond replacing one hydrogen; -ylidene and -ylidyne are used with double bonds and triple bonds, respectively.Organic chemistryOrganic chemistryOrganic chemistry is a subdiscipline within chemistry involving the scientific study of the structure, properties, and reactions of organic compounds and organic materials (i.e. matter in its various forms that contain carbonatoms). It involves studying the structure of organic material to determine the structural formula, analyzing physical and chemical properties, and evaluating chemical reactivity to understand the behavior of organic compounds.MoleculeMoleculeA molecule is a group of two or more atoms that are held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions that satisfy this criterion. In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and molecule is often used when referring to polyatomic ions.CarbonCarbonChemical element with atomic number 6 (C)–↑C↓Siboron ← carbon → nitrogenAtomAtomSmallest unit of a chemical elementAtoms are the basic particles of the chemical elements and the fundamental building blocks of matter. An atom consists of a nucleus of protons and generally neutrons, surrounded by an electromagnetically bound swarm of electrons. The chemical elements are distinguished from each other by the number of protons that are in their atoms. For example, any atom that contains 11 protons is sodium, and any atom that contains 29 protons is copper.HydrogenHydrogenChemical element with atomic number 1 (H)–↑H↓Li(none) ← hydrogen → heliumElectric chargeElectric chargeElectric charge (symbol q, sometimes Q) is a physical property of matter that causes it to experience a force when placed in an electromagnetic field. Electric charge can be positive or negative. Like charges repel each other and unlike charges attract each other. An object with no net charge is referred to as electrically neutral.

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